Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Safety data sheet reference · CAS 7487-88-9

Magnesium sulfate SDS

also: magnesium sulfate MSDS · safety data sheet · MgSO4 · CAS 7487-88-9 · Epsom salt

Official PDF from supplier

This page is a reference, not the legal document.

CAS number

7487-88-9

Molecular formula

MgSO4

No harmonised EU classification

Magnesium sulfate has no entry in CLP Annex VI — there is no harmonised EU-wide classification for it. That is not evidence of safety. Suppliers remain obliged to self-classify it under CLP, and workplace hazards (dust, asphyxiation, thermal) can exist without a harmonised entry. Always obtain the supplier's SDS for the product you actually use.

§ 03 · Composition and identifiers

Magnesium sulfate structure

Magnesium sulfate is an ionic compound — there is no discrete MgSO4 molecule. The diagram shows the ions the crystal lattice is built from.

Ions of magnesium sulfate (MgSO4)

Ions of magnesium sulfate · MgSO4

SMILES [O-]S(=O)(=O)[O-].[Mg+2]
InChI InChI=1S/Mg.H2O4S/c;1-5(2,3)4/h;(H2,1,2,3,4)/q+2;/p-2
InChIKey CSNNHWWHGAXBCP-UHFFFAOYSA-L
PubChem CID 24083 →

Identifiers from PubChem (NIH, public domain). Structure diagram drawn with RDKit from the SMILES string.

MSDS vs SDS

Magnesium sulfate MSDS vs SDS: is there a difference?

MSDS (Material Safety Data Sheet) is the older name for the same document. In the US, OSHA's Hazard Communication Standard (2012) adopted the GHS-standardised 16-section Safety Data Sheet; in the EU the format is set by REACH Annex II. So a "magnesium sulfate MSDS" and a "magnesium sulfate SDS" refer to the same document — today it is issued as an SDS. Full breakdown of the differences →

Compliance hub

From classification to SDS

The classification above corresponds to Section 2 of a Safety Data Sheet. Learn how a compliant 16-section SDS is structured and authored →

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Build the label for magnesium sulfate

Pictograms, signal word and H-statements combined into a compliant label layout →

§ 16 · Sources

Reference aid only. This page summarises the harmonised EU classification and computed storage guidance — it is not a Safety Data Sheet and does not replace one. Always verify hazards, handling and storage against the supplier's SDS (sections 7 and 10) and local regulations before use. Page updated 2026-08-11.

Frequently asked questions about magnesium sulfate

Is an MSDS the same as an SDS?

In practice, yes. MSDS (Material Safety Data Sheet) is the older name for the same document. In the US, OSHA's Hazard Communication Standard (2012) adopted the GHS-standardised 16-section Safety Data Sheet; in the EU the SDS format is set by REACH Annex II. A document you find labelled "magnesium sulfate MSDS" is today issued as an SDS.

Where can I download an official magnesium sulfate SDS PDF?

From your own supplier — an SDS is issued per product and supplier, so the correct PDF for an inspection is the one matching the product you actually purchased. The supplier links on this page lead to the official SDS libraries of major distributors.

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