Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

Build a label

Substance profile

1,1-Dimethoxyethane

1,1-Dimethoxyethane is a colorless liq with a strongly aromatic odor.

CAS 534-15-6 C4H10O2 90.12 g/mol Danger

01 · Identification

What 1,1-Dimethoxyethane is

1,1-Dimethoxyethane is a colorless liq with a strongly aromatic odor. Its molecular formula is C4H10O2 and its molecular weight is 90.12 g/mol. It boils at 64.5 °C, melts at -113 °C, is miscible with water.

Under the GHS it carries the signal word Danger. It is classed as flammable agents - 3rd degree.

02 · Identifiers

1,1-Dimethoxyethane identifiers and molecular data

1,1-Dimethoxyethane CAS number and EC number

CAS number534-15-6
EC number208-589-8
Index number (CLP Annex VI)605-007-00-8

1,1-Dimethoxyethane molecular formula and molecular weight

Molecular formulaC4H10O2
Molecular weight90.12 g/mol
Chemical class Flammable agents - 3rd degree

Other names for 1,1-Dimethoxyethane

  • dimethyl acetal

03 · GHS classification

1,1-Dimethoxyethane hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

1,1-Dimethoxyethane pictograms and signal word

Signal wordDanger

1,1-Dimethoxyethane hazard class and category

GHS hazard classes 1,1-Dimethoxyethane falls into
Hazard class Category From code Pictogram
Flammable liquids GHS chapter 2.6 Category 2 H225 GHS02

1,1-Dimethoxyethane hazard statements (H-codes)

Hazard statements assigned to 1,1-Dimethoxyethane
CodeHazard statement
H225 Highly flammable liquid and vapour.

This page lists only the codes assigned to 1,1-Dimethoxyethane. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for 1,1-Dimethoxyethane

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of 1,1-Dimethoxyethane issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

1,1-Dimethoxyethane precautionary statements

CLP Annex VI assigns 5 precautionary statements to 1,1-Dimethoxyethane. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Storage

How the container has to be kept between uses.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

1,1-Dimethoxyethane name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български 1,1-диметоксиетан диметилацетал
Spanish español 1,1-Dimetoxietano dimetilacetal
Czech čeština 1,1-dimethoxyethan dimethylacetal
Danish dansk 1,1-dimethoxyethan dimethylacetal
German Deutsch 1,1-Dimethoxyethan Dimethylacetal
Estonian eesti 1,1-dimetoksüetaan dimetüülatsetaal
Greek ελληνικά 1,1-διμεθοξυαιθάνιο διμεθυλακετάλη
English English 1,1-dimethoxyethane dimethyl acetal
French français 1,1-diméthoxyéthane acétal diméthylique
Croatian hrvatski 1,1-dimetoksietan dimetil-acetal
Italian italiano 1,1-dimetossietano dimetilacetale
Latvian latviešu 1,1-dimetoksietāns dimetilacetāls
Lithuanian lietuvių 1,1-dimetoksietanas dimetilacetalis
Hungarian magyar 1,1-dimetoxietán dimetil-acetál
Maltese Malti 1,1-dimetossietan aċetal tad-dimetil
Dutch Nederlands 1,1-dimethoxyethaan dimethylacetaal
Polish polski 1,1-dimetoksyetan acetal dimetylowy acetaldehydu
Portuguese português 1,1-dimetoxietano dimetilacetal
Romanian română 1,1-dimetoxietan acetal metilic
Slovak slovenčina 1,1-dimetoxyetán acetaldehyd-dimetylacetál akrylaldehyd
Slovenian slovenščina 1,1-dimetoksietan dimetil acetal
Finnish suomi 1,1-dimetoksietaani dimetyyliasetaali
Swedish svenska 1,1-dimetoxietan dimetylacetal

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

1,1-Dimethoxyethane GHS label elements

Everything CLP Annex VI fixes for 1,1-Dimethoxyethane, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS02 Flame pictogram

Danger

1,1-Dimethoxyethane

  • Highly flammable liquid and vapour.
  • Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
  • Keep container tightly closed.
  • Use explosion-proof [electrical/ventilating/lighting/…] equipment.
  • Use only non-sparking tools.
  • Store in a well-ventilated place.

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open 1,1-Dimethoxyethane in the GHS label constructor →

07 · Health hazards

1,1-Dimethoxyethane health hazards and exposure limits

1,1-Dimethoxyethane hazard summary

A severe skin and eye irritant; [CAMEO] Acts as general anesthetic in lethal-dose inhalation studies of rats; [RTECS] Safe when used as a flavoring agent in food; [JECFA] A fire hazard; [Hawley] An irritant; [MSDSonline]

Source: Haz-Map, Information on Hazardous Chemicals and Occupational Diseases

08 · Physical and chemical properties

1,1-Dimethoxyethane properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

1,1-Dimethoxyethane boiling point

Property Value Conditions Source
Boiling point 64.5 °C (148.1 °F) HSDB
64 °C (147.2 °F) JECFA
64.5 °C (148.1 °F) range, midpoint shown, at 760 mmHg HMDB

1,1-Dimethoxyethane melting point

Property Value Conditions Source
Melting point -113.2 °C (-171.8 °F) HSDB

1,1-Dimethoxyethane density

Property Value Conditions Source
Density 0.8501 g/cm³ at 20 °C HSDB
0.855 g/cm³ range, midpoint shown JECFA

1,1-Dimethoxyethane solubility

Property Value Conditions Source
Solubility ETHER; VERY SOL IN ACETONE HSDB
Miscible with water, alcohol, chloroform, ether. HSDB
miscible with water, organic solvent, oils JECFA

1,1-Dimethoxyethane vapor pressure

Property Value Conditions Source
Vapor pressure 171.18 mmHg at 25 °C HSDB
171 mmHg Haz-Map

1,1-Dimethoxyethane flash point

Property Value Conditions Source
Flash point 26.67 °C (80 °F) below this value HSDB

1,1-Dimethoxyethane vapor density

Property Value Conditions Source
Vapor density 3.1 (air = 1) HSDB

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

09 · Fire and explosion

1,1-Dimethoxyethane fire and explosion behaviour

These are descriptions rather than measured values, so they are kept out of the table above and quoted here with the source that reported them.

1,1-Dimethoxyethane fire potential

FLAMMABLE, DANGEROUS FIRE RISK.

Source: Hazardous Substances Data Bank (HSDB)

10 · Handling and storage

1,1-Dimethoxyethane storage and handling

1,1-Dimethoxyethane peroxide formation

D: Other compounds that may form peroxides

Source: Lab and Research Safety, University of Minnesota

1,1-Dimethoxyethane reactivity

1,1-DIMETHOXYETHANE may react violently with strong oxidizing agents. Can act as a weak base to form salts with strong acids and addition complexes with Lewis acids. In other reactions, which typically involve the breaking of the carbon-oxygen bond, ethers are relatively inert.

Source: CAMEO Chemicals

Planning storage for a mix of chemicals? Check 1,1-Dimethoxyethane in the storage compatibility matrix →

11 · Questions

1,1-Dimethoxyethane — frequently asked questions

What is the CAS number of 1,1-Dimethoxyethane?

The CAS number of 1,1-Dimethoxyethane is 534-15-6. Its EC number is 208-589-8.

What is the chemical formula of 1,1-Dimethoxyethane?

The molecular formula of 1,1-Dimethoxyethane is C4H10O2 and its molecular weight is 90.12 g/mol.

What does a 1,1-Dimethoxyethane label have to show?

Under CLP Annex VI the label for 1,1-Dimethoxyethane carries the pictogram Flame and the signal word is Danger.

Is 1,1-Dimethoxyethane flammable?

Yes. CLP Annex VI assigns 1,1-Dimethoxyethane H225 — highly flammable liquid and vapour. The flash point reported for it is 26.67 °C (80 °F), below this value (HSDB).

Is 1,1-Dimethoxyethane a carcinogen?

CLP Annex VI records no harmonised carcinogenicity classification for 1,1-Dimethoxyethane. Annex VI is a list of agreed classifications, not a list of substances found safe, so this is an absence of a classification rather than a clean bill of health.

What is the boiling point of 1,1-Dimethoxyethane?

The boiling point reported for 1,1-Dimethoxyethane is 64.5 °C (148.1 °F) (HSDB).

What is the melting point of 1,1-Dimethoxyethane?

The melting point reported for 1,1-Dimethoxyethane is -113.2 °C (-171.8 °F) (HSDB).

How should 1,1-Dimethoxyethane be stored?

CLP Annex VI assigns 1,1-Dimethoxyethane the storage statement P403.

Get the free GHS / CLP / OSHA deadline calendar

Verified 2026–2029 compliance dates in one PDF — plus alerts when the rules change.