Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

2,2-Dichloro-1,3-benzodioxole

2,2-Dichloro-1,3-benzodioxole is a chemical substance with the molecular formula C7H4Cl2O2.

CAS 2032-75-9 C7H4Cl2O2 191.01 g/mol Danger

01 · Identification

What 2,2-Dichloro-1,3-benzodioxole is

2,2-Dichloro-1,3-benzodioxole is a chemical substance with the molecular formula C7H4Cl2O2. Its molecular formula is C7H4Cl2O2 and its molecular weight is 191.01 g/mol.

Under the GHS it carries the signal word Danger.

02 · Identifiers

2,2-Dichloro-1,3-benzodioxole identifiers and molecular data

2,2-Dichloro-1,3-benzodioxole CAS number and EC number

CAS number2032-75-9
EC number426-850-6
Index number (CLP Annex VI)603-206-00-4

2,2-Dichloro-1,3-benzodioxole molecular formula and molecular weight

Molecular formulaC7H4Cl2O2
Molecular weight191.01 g/mol

Other names for 2,2-Dichloro-1,3-benzodioxole

  • 2,2-dichloro-1,3-benzodioxol

03 · GHS classification

2,2-Dichloro-1,3-benzodioxole hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

2,2-Dichloro-1,3-benzodioxole pictograms and signal word

Signal wordDanger

2,2-Dichloro-1,3-benzodioxole hazard class and category

GHS hazard classes 2,2-Dichloro-1,3-benzodiox… falls into
Hazard class Category From code Pictogram
Flammable liquids GHS chapter 2.6 Category 3 H226 GHS02
Acute toxicity - oral GHS chapter 3.1 Category 4 H302 GHS07
Skin corrosion/irritation GHS chapter 3.2 Category 1A or 1B or 1C H314 GHS05
Skin sensitisation GHS chapter 3.4 Category 1 or 1A or 1B H317 GHS07

Where two values are shown with “or”, the hazard statement is shared by more than one category or by more than one class, and the code alone does not say which. H272, for example, belongs to oxidising liquids and to oxidising solids — the physical state decides. The binding answer for a specific entry is in the CLP Annex VI table itself.

2,2-Dichloro-1,3-benzodioxole hazard statements (H-codes)

Hazard statements assigned to 2,2-Dichloro-1,3-benzodiox…
CodeHazard statement
H226 Flammable liquid and vapour.
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.

2,2-Dichloro-1,3-benzodioxole supplemental EU statements (EUH)

EU-specific statements assigned to 2,2-Dichloro-1,3-benzodiox…. They exist only in CLP and have no counterpart in UN GHS.
CodeStatement
EUH014 Reacts violently with water.

This page lists only the codes assigned to 2,2-Dichloro-1,3-benzodiox…. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for 2,2-Dichloro-1,3-benzodiox…

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of 2,2-Dichloro-1,3-benzo… issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

2,2-Dichloro-1,3-benzodioxole precautionary statements

CLP Annex VI assigns 17 precautionary statements to 2,2-Dichloro-1,3-benzodiox…. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Storage

How the container has to be kept between uses.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

2,2-Dichloro-1,3-benzodioxole name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български 2,2-дихлоро-1,3-бензодиоксол
Spanish español 2,2-Dicloro-1,3-benzodioxol
Czech čeština 2,2-dichlor-1,3-benzodioxol
Danish dansk 2,2-dichlor-1,3-benzodioxol
German Deutsch 2,2-Dichlor-1,3-benzodioxol
Estonian eesti 2,2-dikloro-1,3-bensodioksool
Greek ελληνικά 2,2-διχλωρo-1,3-βενζoδιoξόλη
English English 2,2-dichloro-1,3-benzodioxol
French français 2,2-dichloro-1,3-benzodioxol
Croatian hrvatski 2,2-diklor-1,3-benzodioksol
Italian italiano 2,2-dicloro-1,3-benzodiossolo
Latvian latviešu 2,2-dihlor-1,3-benzdioksols
Lithuanian lietuvių 2,2-dichlor-1,3-benzdioksolis
Hungarian magyar 2,2-diklór-1,3-benzodioxol
Maltese Malti 2,2-dikloro-1,3-benżodiossol
Dutch Nederlands 2,2-dichloor-1,3-benzodioxool
Polish polski 2,2-dichloro-1,3-benzodioksol
Portuguese português 2,2-dicloro-1,3-benzodioxol
Romanian română 2,2-diclor-1,3-benzodioxol
Slovak slovenčina 2,2-dichlór-1,3-benzodioxol
Slovenian slovenščina 2,2-dikloro-1,3-benzodioksol
Finnish suomi 2,2-dikloori-1,3-bentsodioksoli
Swedish svenska 2,2-diklor-1,3-bensodioxol

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

2,2-Dichloro-1,3-benzodioxole GHS label elements

Everything CLP Annex VI fixes for 2,2-Dichloro-1,3-benzodiox…, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS02 Flame pictogramGHS05 Corrosion pictogramGHS07 Exclamation mark pictogram

Danger

2,2-Dichloro-1,3-benzodioxole

  • Flammable liquid and vapour.
  • Harmful if swallowed.
  • Causes severe skin burns and eye damage.
  • May cause an allergic skin reaction.
  • Reacts violently with water.
  • Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
  • Keep container tightly closed.
  • Use explosion-proof [electrical/ventilating/lighting/…] equipment.
  • Use only non-sparking tools.
  • Do not breathe dust/fume/gas/mist/vapours/spray.
  • Avoid breathing dust/fume/gas/mist/vapours/spray.
  • Do not eat, drink or smoke when using this product.
  • Contaminated work clothing should not be allowed out of the workplace.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • IF SWALLOWED:
  • Immediately call a POISON CENTER/doctor/
  • Call a POISON CENTER/doctor/ if you feel unwell.
  • Get medical advice/attention.
  • Rinse mouth.
  • Do NOT induce vomiting.
  • If skin irritation or rash occurs:
  • Store in a well-ventilated place.

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open 2,2-Dichloro-1,3-benzodiox… in the GHS label constructor →

07 · Questions

2,2-Dichloro-1,3-benzodioxole — frequently asked questions

What is the CAS number of 2,2-Dichloro-1,3-benzodioxole?

The CAS number of 2,2-Dichloro-1,3-benzodioxole is 2032-75-9. Its EC number is 426-850-6.

What is the chemical formula of 2,2-Dichloro-1,3-benzodioxole?

The molecular formula of 2,2-Dichloro-1,3-benzodioxole is C7H4Cl2O2 and its molecular weight is 191.01 g/mol.

What does a 2,2-Dichloro-1,3-benzodioxole label have to show?

Under CLP Annex VI the label for 2,2-Dichloro-1,3-benzodioxole carries the pictograms Flame, Corrosion and Exclamation mark and the signal word is Danger.

Is 2,2-Dichloro-1,3-benzodioxole flammable?

Yes. CLP Annex VI assigns 2,2-Dichloro-1,3-benzodioxole H226 — flammable liquid and vapour.

Is 2,2-Dichloro-1,3-benzodioxole a carcinogen?

CLP Annex VI records no harmonised carcinogenicity classification for 2,2-Dichloro-1,3-benzodioxole. Annex VI is a list of agreed classifications, not a list of substances found safe, so this is an absence of a classification rather than a clean bill of health.

How should 2,2-Dichloro-1,3-benzodioxole be stored?

CLP Annex VI assigns 2,2-Dichloro-1,3-benzodioxole the storage statement P403.

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