Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Aluminum isopropoxide

Aluminum isopropoxide is a white solid.

CAS 555-31-7 C9H21AlO3 204.24 g/mol Danger

01 · Identification

What Aluminum isopropoxide is

Aluminum isopropoxide is a white solid. Its molecular formula is C9H21AlO3 and its molecular weight is 204.24 g/mol. It melts at 119 °C.

Under the GHS it carries the signal word Danger.

02 · Identifiers

Aluminum isopropoxide identifiers and molecular data

Aluminum isopropoxide CAS number and EC number

CAS number555-31-7
EC number209-090-8
Index number (CLP Annex VI)603-042-00-3

Aluminum isopropoxide molecular formula and molecular weight

Molecular formulaC9H21AlO3
Molecular weight204.24 g/mol

Other names for Aluminum isopropoxide

  • aluminium-tri-isopropoxide

03 · GHS classification

Aluminum isopropoxide hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Aluminum isopropoxide pictograms and signal word

Signal wordDanger

Aluminum isopropoxide hazard class and category

GHS hazard classes Aluminum isopropoxide falls into
Hazard class Category From code Pictogram
Flammable solids GHS chapter 2.7 Category 1 or 2 H228 GHS02

Where two values are shown with “or”, the hazard statement is shared by more than one category or by more than one class, and the code alone does not say which. H272, for example, belongs to oxidising liquids and to oxidising solids — the physical state decides. The binding answer for a specific entry is in the CLP Annex VI table itself.

Aluminum isopropoxide hazard statements (H-codes)

Hazard statements assigned to Aluminum isopropoxide
CodeHazard statement
H228 Flammable solid.

This page lists only the codes assigned to Aluminum isopropoxide. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for Aluminum isopropoxide

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of Aluminum isopropoxide issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

Aluminum isopropoxide precautionary statements

CLP Annex VI assigns 4 precautionary statements to Aluminum isopropoxide. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Disposal

What has to happen to the contents and the empty container.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

Aluminum isopropoxide name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български алуминиев триизопропоксид
Spanish español Triisopropóxido de aluminio
Czech čeština isopropoxid hlinitý
Danish dansk aluminiumtriisopropylat aluminiumtriisopropoxid
German Deutsch Aluminiumtriisopropoxid
Estonian eesti alumiiniumtriisopropoksiid
Greek ελληνικά τριισοπροποξειδικό αργίλιο
English English aluminium-tri-isopropoxide
French français triisopropoxyde d'aluminium
Croatian hrvatski aluminijev triizopropoksid
Italian italiano isopropilato di alluminio
Latvian latviešu alumīnija triizopropoksīds
Lithuanian lietuvių aliuminio triizopropoksidas
Hungarian magyar alumínium-triizopropoxid
Maltese Malti aluminju-tri-isopropossidu
Dutch Nederlands aluminiumisopropylaat aluminiumtriisopropoxide
Polish polski triizopropanolan glinu triizopropoksylan glinu
Portuguese português triisopropóxido de alumínio
Romanian română triizopropoxid de aluminiu
Slovak slovenčina alumínium-tris(propán-2-olát)
Slovenian slovenščina aluminijev triizopropoksid
Finnish suomi alumiinitri-isopropoksidi
Swedish svenska aluminiumtriisopropoxid

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

Aluminum isopropoxide GHS label elements

Everything CLP Annex VI fixes for Aluminum isopropoxide, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS02 Flame pictogram

Danger

Aluminum isopropoxide

  • Flammable solid.
  • If medical advice is needed, have product container or label at hand.
  • Keep out of reach of children.
  • Read carefully and follow all instructions.
  • Dispose of contents/container to

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open Aluminum isopropoxide in the GHS label constructor →

07 · Health hazards

Aluminum isopropoxide health hazards and exposure limits

Aluminum isopropoxide hazard summary

May cause eye irritation; [HSDB] Reacts with water; A corrosive substance that can cause injury to the skin, eyes, and respiratory tract; [MSDSonline] See Aluminum.

Source: Haz-Map, Information on Hazardous Chemicals and Occupational Diseases

Aluminum isopropoxide occupational exposure limits

US occupational exposure limits reported for Aluminum isopropoxide. PEL is enforceable (OSHA), REL is a recommendation (NIOSH), IDLH is the concentration at which escape becomes impossible without injury.
Limit Value Source
PEL 15.0 [mg/m3] (total dust) Haz-Map, Information on Hazardous Chemicals and Occupational Diseases

These are United States values. The European Union sets its own indicative and binding limits, and the figure that applies at a given workplace is the one in the local regulation — not the one shown here.

08 · Physical and chemical properties

Aluminum isopropoxide properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

Aluminum isopropoxide boiling point

Property Value Conditions Source
Boiling point 135 °C (275 °F) at 10 mmHg (reduced pressure) HSDB

Aluminum isopropoxide melting point

Property Value Conditions Source
Melting point 119 °C (246.2 °F) DOE PAC

Aluminum isopropoxide density

Property Value Conditions Source
Density 1.025 g/cm³ at 20 °C HSDB
1.035 g/cm³ at 25 °C DOE PAC

Aluminum isopropoxide solubility

Property Value Conditions Source
Solubility Soluble in ethanol, isopropanol, benzene, toluene, chloroform, carbon tetrachloride, petroleum hydrocarbons. HSDB

Aluminum isopropoxide lower explosive limit (LEL)

Property Value Conditions Source
Lower explosive limit (LEL) ...Violently explosive when they come into contact with water. Aluminum alkyls HSDB

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

09 · Fire and explosion

Aluminum isopropoxide fire and explosion behaviour

These are descriptions rather than measured values, so they are kept out of the table above and quoted here with the source that reported them.

Aluminum isopropoxide fire potential

Certain polymerization catalysts, such as aluminum alkyls, react & burn violently on contact with water. /Aluminum alkyls/

Source: Hazardous Substances Data Bank (HSDB)

10 · Handling and storage

Aluminum isopropoxide storage and handling

Aluminum isopropoxide storage conditions

Extremely reactive with air, moisture and compounds containing active hydrogen and therefore must be kept under a blanket of inert gas. /Aluminum alkyls/

Source: Hazardous Substances Data Bank (HSDB)

Aluminum isopropoxide incompatible materials

Extremely reactive with air, moisture, and compounds containing active hydrogen... /Alkyl aluminum compounds/

Source: Hazardous Substances Data Bank (HSDB)

Planning storage for a mix of chemicals? Check Aluminum isopropoxide in the storage compatibility matrix →

11 · Questions

Aluminum isopropoxide — frequently asked questions

What is the CAS number of Aluminum isopropoxide?

The CAS number of Aluminum isopropoxide is 555-31-7. Its EC number is 209-090-8.

What is the chemical formula of Aluminum isopropoxide?

The molecular formula of Aluminum isopropoxide is C9H21AlO3 and its molecular weight is 204.24 g/mol.

What does a Aluminum isopropoxide label have to show?

Under CLP Annex VI the label for Aluminum isopropoxide carries the pictogram Flame and the signal word is Danger.

Is Aluminum isopropoxide flammable?

Yes. CLP Annex VI assigns Aluminum isopropoxide H228 — flammable solid.

Is Aluminum isopropoxide a carcinogen?

CLP Annex VI records no harmonised carcinogenicity classification for Aluminum isopropoxide. Annex VI is a list of agreed classifications, not a list of substances found safe, so this is an absence of a classification rather than a clean bill of health.

What is the exposure limit for Aluminum isopropoxide?

The US occupational exposure limit reported for Aluminum isopropoxide is 15.0 [mg/m3] (total dust) (Haz-Map, Information on Hazardous Chemicals and Occupational Diseases). Limits differ by country: the EU sets its own indicative and binding values, and the figure that applies at a given workplace is the one in the local regulation.

What is the boiling point of Aluminum isopropoxide?

The boiling point reported for Aluminum isopropoxide is 135 °C (275 °F), at 10 mmHg (reduced pressure) (HSDB).

What is the melting point of Aluminum isopropoxide?

The melting point reported for Aluminum isopropoxide is 119 °C (246.2 °F) (DOE PAC).

How should Aluminum isopropoxide be stored?

Extremely reactive with air, moisture and compounds containing active hydrogen and therefore must be kept under a blanket of inert gas. /Aluminum alkyls/ (Hazardous Substances Data Bank (HSDB))

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