Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Benzyl Salicylate

Benzyl Salicylate is a thick liquid with a faint sweet odor.

CAS 118-58-1 C14H12O3 228.24 g/mol Warning

01 · Identification

What Benzyl Salicylate is

Benzyl Salicylate is a thick liquid with a faint sweet odor. Its molecular formula is C14H12O3 and its molecular weight is 228.24 g/mol. It boils at 320 °C, melts at 24 °C, is slightly soluble in water.

Under the GHS it carries the signal word Warning.

02 · Identifiers

Benzyl Salicylate identifiers and molecular data

Benzyl Salicylate CAS number and EC number

CAS number118-58-1
EC number204-262-9
Index number (CLP Annex VI)607-754-00-5

Benzyl Salicylate molecular formula and molecular weight

Molecular formulaC14H12O3
Molecular weight228.24 g/mol

03 · GHS classification

Benzyl Salicylate hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Benzyl Salicylate pictograms and signal word

Signal wordWarning

Benzyl Salicylate hazard class and category

GHS hazard classes Benzyl Salicylate falls into
Hazard class Category From code Pictogram
Skin sensitisation GHS chapter 3.4 Category 1 or 1A or 1B H317 GHS07

Where two values are shown with “or”, the hazard statement is shared by more than one category or by more than one class, and the code alone does not say which. H272, for example, belongs to oxidising liquids and to oxidising solids — the physical state decides. The binding answer for a specific entry is in the CLP Annex VI table itself.

Benzyl Salicylate hazard statements (H-codes)

Hazard statements assigned to Benzyl Salicylate
CodeHazard statement
H317 May cause an allergic skin reaction.

This page lists only the codes assigned to Benzyl Salicylate. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for Benzyl Salicylate

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of Benzyl Salicylate issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

Benzyl Salicylate precautionary statements

CLP Annex VI assigns 5 precautionary statements to Benzyl Salicylate. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Response

What to do once exposure, spillage or fire has already happened.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

Benzyl Salicylate name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български бензилов салицилат
Spanish español Salicilato de bencilo
Czech čeština benzyl-salicylát
Danish dansk benzylsalicylat
German Deutsch Benzylsalicylat
Estonian eesti bensüülsalitsülaat
Greek ελληνικά σαλικυλικό βένζυλο
English English benzyl salicylate
French français Salicylate de benzyle
Croatian hrvatski benzilsalicilat
Italian italiano salicilato di benzile
Latvian latviešu benzilsalicilāts
Lithuanian lietuvių benzilsalicilatas
Hungarian magyar benzil-szalicilát
Maltese Malti benzil saliċilat
Dutch Nederlands benzylsalicylaat
Polish polski salicylan benzylu
Portuguese português salicilato de benzilo
Romanian română salicilat de benzil
Slovak slovenčina benzyl-2-hydroxybenzoát
Slovenian slovenščina benzilsalicilat
Finnish suomi bentsyylisalisylaatti
Swedish svenska bensylsalicylat

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

Benzyl Salicylate GHS label elements

Everything CLP Annex VI fixes for Benzyl Salicylate, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS07 Exclamation mark pictogram

Warning

Benzyl Salicylate

  • May cause an allergic skin reaction.
  • Avoid breathing dust/fume/gas/mist/vapours/spray.
  • Contaminated work clothing should not be allowed out of the workplace.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • Get medical advice/attention.
  • If skin irritation or rash occurs:

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open Benzyl Salicylate in the GHS label constructor →

07 · Physical and chemical properties

Benzyl Salicylate properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

Benzyl Salicylate boiling point

Property Value Conditions Source
Boiling point 320 °C (608 °F) HSDB
300 °C (572 °F) JECFA
211 °C (411.8 °F) at 20.0266 mmHg (reduced pressure) HSDB

Benzyl Salicylate melting point

Property Value Conditions Source
Melting point 24 °C (75.2 °F) HSDB
23.89 °C (75 °F) CAMEO
23.4 °C (74.1 °F) HMDB

Benzyl Salicylate density

Property Value Conditions Source
Density 1.175 g/cm³ at 20 °C HSDB
1.178 g/cm³ range, midpoint shown JECFA

Benzyl Salicylate solubility

Property Value Conditions Source
Solubility Slightly soluble in water HSDB
Miscible with alcohol or ether HSDB
In water, 8.8 mg/L at 20 °C, pH 6.8-7.1 at 20 °C HSDB

Benzyl Salicylate vapor pressure

Property Value Conditions Source
Vapor pressure 0.000078 mmHg at 25 °C HSDB

Benzyl Salicylate flash point

Property Value Conditions Source
Flash point 180 °C (356 °F) HSDB
100 °C (212 °F) above this value HSDB

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

08 · Fire and explosion

Benzyl Salicylate fire and explosion behaviour

These are descriptions rather than measured values, so they are kept out of the table above and quoted here with the source that reported them.

Benzyl Salicylate fire potential

Combustible when exposed to heat or flame.

Source: Hazardous Substances Data Bank (HSDB)

09 · Handling and storage

Benzyl Salicylate storage and handling

Benzyl Salicylate storage conditions

Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage.

Source: Hazardous Substances Data Bank (HSDB)

Benzyl Salicylate incompatible materials

Incompatible materials: Strong oxidizing agents.

Source: Hazardous Substances Data Bank (HSDB)

Benzyl Salicylate reactivity

BENZYL SALICYLATE may hydrolyze in aqueous acid or basic solutions. It can react with oxidizing materials. (NTP, 1992)

Source: CAMEO Chemicals

Planning storage for a mix of chemicals? Check Benzyl Salicylate in the storage compatibility matrix →

10 · Questions

Benzyl Salicylate — frequently asked questions

What is the CAS number of Benzyl Salicylate?

The CAS number of Benzyl Salicylate is 118-58-1. Its EC number is 204-262-9.

What is the chemical formula of Benzyl Salicylate?

The molecular formula of Benzyl Salicylate is C14H12O3 and its molecular weight is 228.24 g/mol.

What does a Benzyl Salicylate label have to show?

Under CLP Annex VI the label for Benzyl Salicylate carries the pictogram Exclamation mark and the signal word is Warning.

Is Benzyl Salicylate flammable?

CLP Annex VI assigns Benzyl Salicylate no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it. The flash point reported for it is 180 °C (356 °F) (HSDB).

Is Benzyl Salicylate a carcinogen?

CLP Annex VI records no harmonised carcinogenicity classification for Benzyl Salicylate. Annex VI is a list of agreed classifications, not a list of substances found safe, so this is an absence of a classification rather than a clean bill of health.

What is the boiling point of Benzyl Salicylate?

The boiling point reported for Benzyl Salicylate is 320 °C (608 °F) (HSDB).

What is the melting point of Benzyl Salicylate?

The melting point reported for Benzyl Salicylate is 24 °C (75.2 °F) (HSDB).

How should Benzyl Salicylate be stored?

Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. (Hazardous Substances Data Bank (HSDB))

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