Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Ethoxyquin

Ethoxyquin is a yellow liquid.

CAS 91-53-2 C14H19NO 217.31 g/mol Warning

01 · Identification

What Ethoxyquin is

Ethoxyquin is a yellow liquid. Its molecular formula is C14H19NO and its molecular weight is 217.31 g/mol. It melts at 0 °C.

Under the GHS it carries the signal word Warning.

02 · Identifiers

Ethoxyquin identifiers and molecular data

Ethoxyquin CAS number and EC number

CAS number91-53-2
EC number202-075-7
Index number (CLP Annex VI)613-014-00-2

Ethoxyquin molecular formula and molecular weight

Molecular formulaC14H19NO
Molecular weight217.31 g/mol

Other names for Ethoxyquin

  • ethoxyquin (ISO)
  • 6-ethoxy-1,2-dihydro-2,2,4-trimethylquinoline

03 · GHS classification

Ethoxyquin hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Ethoxyquin pictograms and signal word

Signal wordWarning

Ethoxyquin hazard class and category

GHS hazard classes Ethoxyquin falls into
Hazard class Category From code Pictogram
Acute toxicity - oral GHS chapter 3.1 Category 4 H302 GHS07

Ethoxyquin hazard statements (H-codes)

Hazard statements assigned to Ethoxyquin
CodeHazard statement
H302 Harmful if swallowed.

This page lists only the codes assigned to Ethoxyquin. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for Ethoxyquin

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of Ethoxyquin issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

Ethoxyquin precautionary statements

CLP Annex VI assigns 4 precautionary statements to Ethoxyquin. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Prevention

What to do before and during handling so the hazard never happens.

Response

What to do once exposure, spillage or fire has already happened.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

Ethoxyquin name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български етоксихин (ISO) 6-етокси-2,2,4-триметил-1,2-дихидрохинолин
Spanish español Etoxiquina (ISO) 6-etoxi-1,2-dihidro-2,2,4-trimetilquinolina
Czech čeština ethoxychin 6-ethoxy-2,2,4-trimethyl-1,2-dihydrochinolin
Danish dansk ethoxyquin (ISO) 6-ethoxy-1,2-dihydro-2,2,4-trimethylquinolin
German Deutsch Ethoxyquin (ISO) 6-Ethoxy-1,2-dihydro-2,2,4-trimethylinolin
Estonian eesti etoksükiin (ISO) 6-etoksü-1,2-dihüdro-2,2,4-trimetüülkinoliin
Greek ελληνικά ethoxyquin (αιθοξυκίνη) (ISO) 6-αιθοξυ-1,2-διυδρο-2,2,4-τριμεθυλοκινολίνη
English English ethoxyquin (ISO) 6-ethoxy-1,2-dihydro-2,2,4-trimethylquinoline
French français éthoxyquine (ISO) 6-éthoxy-1,2-dihydro-2,2,4-triméthylquinoline
Croatian hrvatski etoksikvin (ISO) 6-etoksi-1,2-dihidro-2,2,4-trimetilkinolin
Italian italiano ethoxyquin (ISO) 6-etossi-2,2,4-trimetil-1,2-diidrochinolina
Latvian latviešu etoksikvīns (ISO) 6-etoksi-1,2-dihidro-2,2,4-trimetilhinolīns
Lithuanian lietuvių etoksichinas (ISO) 6-etoksi-1,2-dihidro-2,2,4-trimetilchinolinas
Hungarian magyar etoxikvin (ISO) 6-etoxi-1,2-dihidro-2,2,4-trimetilkinolin
Maltese Malti etossiquin (ISO) 6-etossi-1,2-diidro-2,2,4-trimetilquinoline
Dutch Nederlands ethoxyquine (ISO) 6-ethoxy-2,2,4-trimethyl-1,2-dihydrochinoline
Polish polski etoksychina (ISO) 6-etoksy-2,2,4-trimetylo-1,2-dihydrochinolina
Portuguese português etoxiquina (ISO) 6-etoxi-1,2-di-hidro-2,2,4-trimetilquinolina
Romanian română etoxiquin (ISO) 6-etoxi-2,2,4-trimetil-1,2-dihidrochinolină
Slovak slovenčina etoxychín (ISO) 6-etoxy-2,2,4-trimetyl-1,2-dihydrochinolín
Slovenian slovenščina etoksikin (ISO) 6-etoksi-1,2-dihidro-2,2,4-trimetilkinolin
Finnish suomi etoksikvini (ISO) 6-etoksi-1,2-dihydro-2,2,4-trimetyylikinoliini
Swedish svenska etoxikin (ISO) 6-etoxi-1,2-dihydro-2,2,4-trimetylkinolin

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

Ethoxyquin GHS label elements

Everything CLP Annex VI fixes for Ethoxyquin, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS07 Exclamation mark pictogram

Warning

Ethoxyquin

  • Harmful if swallowed.
  • Do not eat, drink or smoke when using this product.
  • IF SWALLOWED:
  • Call a POISON CENTER/doctor/ if you feel unwell.
  • Rinse mouth.

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open Ethoxyquin in the GHS label constructor →

07 · Health hazards

Ethoxyquin health hazards and exposure limits

Ethoxyquin hazard summary

Allergic contact dermatitis reported in a feed mill worker; [Kanerva, p. 1793] A skin irritant; May cause reversible changes to the liver; Reports of contact dermatitis in animal feed employees; [HSDB] May polymerize on exposure to light and air; A skin and eye irritant; May cause skin sensitization; [CAMEO] Strongly associated with cases of occupational contact dermatitis; Causes increased liver enzymes in animal experiments; [Reference #2]

Source: Haz-Map, Information on Hazardous Chemicals and Occupational Diseases

08 · Physical and chemical properties

Ethoxyquin properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

Ethoxyquin boiling point

Property Value Conditions Source
Boiling point 124 °C (255.2 °F) range, midpoint shown, at 2 mmHg (reduced pressure) HSDB
123.89 °C (255 °F) range, midpoint shown, at 2 mmHg (reduced pressure) CAMEO

Ethoxyquin melting point

Property Value Conditions Source
Melting point 0 °C (32 °F) approximate HSDB
0 °C (32 °F) below this value CAMEO

Ethoxyquin density

Property Value Conditions Source
Density 1.03 g/cm³ range, midpoint shown, at 25 °C HSDB

Ethoxyquin solubility

Property Value Conditions Source
Solubility less than 1 mg/mL at 68 °F (NTP, 1992) at 20 °C CAMEO

Ethoxyquin vapor pressure

Property Value Conditions Source
Vapor pressure 0.0000182 mmHg at 0 °C CAMEO
0.000132 mmHg Haz-Map

Ethoxyquin flash point

Property Value Conditions Source
Flash point 107.22 °C (225 °F) CAMEO

Ethoxyquin vapor density

Property Value Conditions Source
Vapor density 7.48 (air = 1) HSDB

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

09 · Fire and explosion

Ethoxyquin fire and explosion behaviour

These are descriptions rather than measured values, so they are kept out of the table above and quoted here with the source that reported them.

Ethoxyquin fire potential

FIRE HAZARD /IS/ SLIGHT

Source: Hazardous Substances Data Bank (HSDB)

10 · Handling and storage

Ethoxyquin storage and handling

Ethoxyquin incompatible materials

Can react with oxidizing materials.

Source: Hazardous Substances Data Bank (HSDB)

Ethoxyquin reactivity

ETHOXYQUIN may undergo a hazardous polymerization at temperatures above 320 °F. Tends to polymerize and darken in color on exposure to light and air. Not compatible with oxidizing agents and with strong acids (NTP, 1992).

Source: CAMEO Chemicals

Planning storage for a mix of chemicals? Check Ethoxyquin in the storage compatibility matrix →

11 · Questions

Ethoxyquin — frequently asked questions

What is the CAS number of Ethoxyquin?

The CAS number of Ethoxyquin is 91-53-2. Its EC number is 202-075-7.

What is the chemical formula of Ethoxyquin?

The molecular formula of Ethoxyquin is C14H19NO and its molecular weight is 217.31 g/mol.

What does a Ethoxyquin label have to show?

Under CLP Annex VI the label for Ethoxyquin carries the pictogram Exclamation mark and the signal word is Warning.

Is Ethoxyquin flammable?

CLP Annex VI assigns Ethoxyquin no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it. The flash point reported for it is 107.22 °C (225 °F) (CAMEO).

Is Ethoxyquin a carcinogen?

CLP Annex VI records no harmonised carcinogenicity classification for Ethoxyquin. Annex VI is a list of agreed classifications, not a list of substances found safe, so this is an absence of a classification rather than a clean bill of health.

What is the boiling point of Ethoxyquin?

The boiling point reported for Ethoxyquin is 124 °C (255.2 °F), range, midpoint shown, at 2 mmHg (reduced pressure) (HSDB).

What is the melting point of Ethoxyquin?

The melting point reported for Ethoxyquin is 0 °C (32 °F), approximate (HSDB).

Nearby

Substances next to Ethoxyquin

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