Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Imazapyr

Imazapyr is a clear, slightly viscous, pale yellow to dark green aqueous liquid with a slight ammonical odor.

CAS 81334-34-1 C13H15N3O3 261.28 g/mol Warning

01 · Identification

What Imazapyr is

Imazapyr is a clear, slightly viscous, pale yellow to dark green aqueous liquid with a slight ammonical odor. Its molecular formula is C13H15N3O3 and its molecular weight is 261.28 g/mol. It melts at 171 °C.

Under the GHS it carries the signal word Warning.

02 · Identifiers

Imazapyr identifiers and molecular data

Imazapyr CAS number and EC number

CAS number81334-34-1
Index number (CLP Annex VI)613-126-00-1

Imazapyr molecular formula and molecular weight

Molecular formulaC13H15N3O3
Molecular weight261.28 g/mol

Other names for Imazapyr

  • imazapyr (ISO)
  • 2-[4,5-dihydro-4-methyl-4-(1-methylethyl)-5-oxo-1H-imidazol-2-yl]-3-pyridine carboxylate

03 · GHS classification

Imazapyr hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Imazapyr pictograms and signal word

Signal wordWarning

Imazapyr hazard class and category

GHS hazard classes Imazapyr falls into
Hazard class Category From code Pictogram
Serious eye damage/eye irritation GHS chapter 3.3 Category 2A H319 GHS07
Hazardous to the aquatic environment - chronic GHS chapter 4.1 Category 3 H412

Imazapyr hazard statements (H-codes)

Hazard statements assigned to Imazapyr
CodeHazard statement
H319 Causes serious eye irritation.
H412 Harmful to aquatic life with long lasting effects.

This page lists only the codes assigned to Imazapyr. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for Imazapyr

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of Imazapyr issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

Imazapyr precautionary statements

CLP Annex VI assigns 8 precautionary statements to Imazapyr. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Disposal

What has to happen to the contents and the empty container.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

Imazapyr name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български имазапир (ISO) 2-[4,5-дихидро-4-метил-4-(1-метилетил)-5-оксо-1 H -имидазол-2-ил]-3-пиридинкарбоксилат
Spanish español Imazapir (ISO) ácido 2-[4,5-dihidro-4-metil-4-(1-metiletil)-5-oxo-1 H - imidazol-2-il]-3-piridina-carboxílico
Czech čeština imazapyr (ISO) 2-(4-isopropyl-4-methyl-5-oxo-4,5-dihydro-1 H -imidazol-2-yl)pyridin-3-karboxylová kyselina
Danish dansk imazapyr (ISO) 2-[4,5-dihydro-4-methyl-4-(1-methylethyl)-5-oxo-1 H -imidazol-2-yl]-3-pyridincarboxylat
German Deutsch Imazapyr (ISO) 2-[4,5-Dihydro-4-methyl-4-(1-methylethyl)-5-oxo-1 H - imidazol-2-yl]-3-pyridincarboxylat
Estonian eesti imasapüür (ISO) 2-[4,5-dihüdro-4-metüül-4-(1-metüületüül)-5-okso-1 H -imidasool-2-üül]-3-püridiinkarboksülaat
Greek ελληνικά imazapyr (ιμαζαπύρ) (ISO) 2-[4,5-διυδρο-4-μεθυλο-4-(1-μεθυλαιθυλ)-5-οξο-1 H -ιμιδαζολ-2-υλο]-3-πυριδινοκαρβοξυλικό οξύ
English English imazapyr (ISO) 2-[4,5-dihydro-4-methyl-4-(1- methylethyl)-5-oxo-1 H - imidazol-2-yl]-3-pyridine carboxylate
French français imazapyr (ISO) carboxylate de 2-[4,5-dihydro-4-méthyl-4-(1- méthyléthyl)-5-oxo-1 H -imidazol-2-yl]-3-pyridine
Croatian hrvatski imazapir (ISO) 2-[4,5-dihidro-4-metil-4-(1-metiletil)-5-okso-1 H -imidazol-2-il]-3-piridin karboksilat
Italian italiano imazapir (ISO) acido 2-[4,5-diidro-4-metil-4-(1- metiletil)-5-osso-1 H -imidazol-2-il]- 3-piridincarbossilico
Latvian latviešu imazapīrs (ISO) 2-[4,5-dihidro-4-metil-4-(1-metiletil)-5-okso-1 H -imidazol-2-il]-3-piridīna karboksilāts
Lithuanian lietuvių imazapiras (ISO) 2-[4,5-dihidro-4-metil-4-(1-metiletil)-5-okso-1 H -imidazol-2-il]-3-piridinkarboksilatas
Hungarian magyar imazapir (ISO) 2-[4,5-dihidro-4-metil-4-(1-metiletil)-5-oxo-1 H -imidazol-2-il]-3-piridin-karboxilát
Maltese Malti imażapir (ISO) karbossilat ta’ 2-[4,5-diidro-4-metil-4-(1-metiletil)-5-osso-1 H -imidażol-2-il]-3-piridina
Dutch Nederlands imazapyr (ISO) 2-[4,5-dihydro-4-methyl-4-(1-methylethyl)-5-oxo-1 H -imidazool-2-yl]-3-pyridinecarboxylaat
Polish polski imazapyr (ISO) kwas ( RS )-2-[4-izopropylo-4-metylo-5-okso-4,5-dihydro-1 H -imidazol-2-ilo]nikotynowykwas ( RS )-2-[4-metylo-4-(1-metyloetylo)-5-okso-4,5-dihydro-1 H -imidazol-2-ilo]-3-pirydynokarboksylowy
Portuguese português imazapir (ISO) ácido 2-[4,5-di-hidro-4-metil-4-(1-metiletil)-5-oxo-1 H -imidazol-2-il]-3-piridinacarboxílico
Romanian română imazapir (ISO) 2-[4,5-dihidro-4-metil-4-(1-metiletil)-5-oxo-1 H -imidazol-2-il]-3-piridin-carboxilat
Slovak slovenčina imazapyr (ISO) 2-[4-izopropyl-4-metyl-5-oxo-4,5-dihydro-1 H -imidazol-2-yl]pyridín-3-karboxylát
Slovenian slovenščina imazapir (ISO) 2-[4,5-dihidro-4-metil-4-(1-metiletil)-5-okso-1 H -imidazol-2-il]-3-piridinkarboksilna kislina
Finnish suomi imatsapyyri (ISO) 2-[4,5-dihydro-4-metyyli-4-(1-metyylietyyli)-5-okso-1 H -imidatsoli-2-yyli]-3-pyridiinikarboksylaatti
Swedish svenska imazapyr (ISO) 2-[4,5-dihydro-4-metyl-4-(1-metyletyl)-5-oxo-1 H -imidazol-2-yl]-3-pyridinkarboxylat

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

Imazapyr GHS label elements

Everything CLP Annex VI fixes for Imazapyr, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS07 Exclamation mark pictogram

Warning

Imazapyr

  • Causes serious eye irritation.
  • Harmful to aquatic life with long lasting effects.
  • Wash thoroughly after handling.
  • Avoid release to the environment.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • IF IN EYES:
  • Get medical advice/attention.
  • If eye irritation persists:
  • Remove contact lenses, if present and easy to do. Continue rinsing.
  • Dispose of contents/container to

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open Imazapyr in the GHS label constructor →

07 · Health hazards

Imazapyr health hazards and exposure limits

Imazapyr hazard summary

The imidazolinones are not reproductive or developmental toxins and lack genotoxic and carcinogenic potential; They are relatively nontoxic in acute toxicity testing; [Krieger, p. 1853-63] An eye irritant; [MSDSonline] See Imazapyr isopropylamine salt.

Source: Haz-Map, Information on Hazardous Chemicals and Occupational Diseases

Imazapyr carcinogenicity classification

Cancer Classification: Group E Evidence of Non-carcinogenicity for Humans

Source: Hazardous Substances Data Bank (HSDB)

An IARC group and a CLP classification answer different questions. IARC judges whether the evidence for cancer in humans is strong enough; CLP Annex VI is the legally binding EU classification. A substance can carry one and not the other.

08 · Physical and chemical properties

Imazapyr properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

Imazapyr melting point

Property Value Conditions Source
Melting point 171 °C (339.8 °F) HSDB
MP: 160-180 (decomposes) decomposes, Imazapyr isopropylamine salt HSDB

Imazapyr density

Property Value Conditions Source
Density 0.34 g/cm³ HSDB

Imazapyr solubility

Property Value Conditions Source
Solubility In acetone 3.39, dimethyl sulfoxide 47.1, hexane 0.00095, methanol 10.5, dichloromethane 8.72, toluene 0.180 (25 °C, all in g/100 mL) HSDB
In water, 1.13X10+4 mg/L at 25 °C; 9.74 g/L at 15 °C at 25 °C HSDB

Imazapyr vapor pressure

Property Value Conditions Source
Vapor pressure 97.508 mmHg below this value, at 60 °C HSDB

Imazapyr corrosivity

Property Value Conditions Source
Corrosivity Corrosive to iron, mild steel, and brass, but not to #304 stainless steel HSDB

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

09 · Questions

Imazapyr — frequently asked questions

What is the CAS number of Imazapyr?

The CAS number of Imazapyr is 81334-34-1.

What is the chemical formula of Imazapyr?

The molecular formula of Imazapyr is C13H15N3O3 and its molecular weight is 261.28 g/mol.

What does a Imazapyr label have to show?

Under CLP Annex VI the label for Imazapyr carries the pictogram Exclamation mark and the signal word is Warning.

Is Imazapyr flammable?

CLP Annex VI assigns Imazapyr no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it.

Is Imazapyr a carcinogen?

CLP Annex VI records no harmonised carcinogenicity classification for Imazapyr. Annex VI is a list of agreed classifications, not a list of substances found safe, so this is an absence of a classification rather than a clean bill of health.

What is the melting point of Imazapyr?

The melting point reported for Imazapyr is 171 °C (339.8 °F) (HSDB).

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