Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Mannitol Hexanitrate

Mannitol Hexanitrate is colorless crystals.

CAS 15825-70-4 C6H8N6O18 452.16 g/mol Danger

01 · Identification

What Mannitol Hexanitrate is

Mannitol Hexanitrate is colorless crystals. Its molecular formula is C6H8N6O18 and its molecular weight is 452.16 g/mol. It melts at 107 °C, is soluble in water.

Under the GHS it carries the signal word Danger.

02 · Identifiers

Mannitol Hexanitrate identifiers and molecular data

Mannitol Hexanitrate CAS number and EC number

CAS number15825-70-4
EC number239-924-6
Index number (CLP Annex VI)603-036-00-0

Mannitol Hexanitrate molecular formula and molecular weight

Molecular formulaC6H8N6O18
Molecular weight452.16 g/mol

Other names for Mannitol Hexanitrate

  • nitromannite

03 · GHS classification

Mannitol Hexanitrate hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Mannitol Hexanitrate pictograms and signal word

Signal wordDanger

Mannitol Hexanitrate hazard class and category

GHS hazard classes Mannitol Hexanitrate falls into
Hazard class Category From code Pictogram
Explosives GHS chapter 2.1 Category Unstable explosive H200 GHS01

Mannitol Hexanitrate hazard statements (H-codes)

Hazard statements assigned to Mannitol Hexanitrate
CodeHazard statement
H200 Unstable explosives.

This page lists only the codes assigned to Mannitol Hexanitrate. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for Mannitol Hexanitrate

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of Mannitol Hexanitrate issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

Mannitol Hexanitrate precautionary statements

CLP Annex VI assigns 1 precautionary statement to Mannitol Hexanitrate. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Prevention

What to do before and during handling so the hazard never happens.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

Mannitol Hexanitrate name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български манитолхексанитрат нитроманит
Spanish español Hexanitrato de manitol nitromanita
Czech čeština manitol-hexanitrát nitromannit
Danish dansk mannitolhexanitrat nitromannit
German Deutsch Mannithexanitrat Nitromannit
Estonian eesti mannitoolheksanitraat nitromanniit
Greek ελληνικά εξανιτρική μαννιτόλη νιτρομαννίτης
English English mannitol hexanitrate nitromannite
French français hexanitrate de mannitol nitromannite
Croatian hrvatski manitol-heksanitrat nitromanit
Italian italiano mannitol-esanitrato nitromannite
Latvian latviešu mannīta heksanitrāts nitromannīts
Lithuanian lietuvių manitolio heksanitratas nitromanitas
Hungarian magyar mannitol-hexanitrát nitromannit
Maltese Malti eżanitrat tal-mannitol nitromannit
Dutch Nederlands mannitolhexanitraat nitromanniet
Polish polski heksaazotan(V) heksano-1,2,3,4,5,6-heksaolu nitromannitheksaazotan(V) mannitu
Portuguese português hexanitrato de manitol nitromanite
Romanian română hexanitrat de manitol nitromanită
Slovak slovenčina hexanitrát manitolu nitromanit
Slovenian slovenščina manitol heksanitrat nitromanit
Finnish suomi mannitoliheksanitraatti nitromanniitti
Swedish svenska mannitolhexanitrat nitromannit

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

Mannitol Hexanitrate GHS label elements

Everything CLP Annex VI fixes for Mannitol Hexanitrate, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS01 Exploding bomb pictogram

Danger

Mannitol Hexanitrate

  • Unstable explosives.
  • Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open Mannitol Hexanitrate in the GHS label constructor →

07 · Physical and chemical properties

Mannitol Hexanitrate properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

Mannitol Hexanitrate boiling point

Property Value Conditions Source
Boiling point Explodes HSDB

Mannitol Hexanitrate melting point

Property Value Conditions Source
Melting point 107 °C (224.6 °F) HSDB

Mannitol Hexanitrate density

Property Value Conditions Source
Density 1.8 g/cm³ at 20 °C HSDB

Mannitol Hexanitrate solubility

Property Value Conditions Source
Solubility Soluble in alcohol, acetone, ether HSDB
Very soluble in benzene HSDB
Insoluble in water HSDB

Mannitol Hexanitrate lower explosive limit (LEL)

Property Value Conditions Source
Lower explosive limit (LEL) A powerful explosive sensitive to shock or heat. HSDB
Explodes at 120 °F at 48.89 °C HSDB

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

08 · Fire and explosion

Mannitol Hexanitrate fire and explosion behaviour

These are descriptions rather than measured values, so they are kept out of the table above and quoted here with the source that reported them.

Mannitol Hexanitrate fire potential

Dangerous fire and explosion risk

Source: Hazardous Substances Data Bank (HSDB)

Fire and explosion

If it should dry out it can explode due to shock, heat, flame, or friction ... Under prolonged exposure to fire or heat they can explode. /Mannitol hexanitrate, wetted/

Source: HSDB

09 · Handling and storage

Mannitol Hexanitrate storage and handling

Mannitol Hexanitrate reactivity

Nitroalkanes, such as MANITOL HEXANITRATE, range from slight to strong oxidizing agents. If mixed with reducing agents, including hydrides, sulfides and nitrides, they may begin a vigorous reaction that culminates in a detonation. Nitroalkanes are milder oxidizing agents, but still react violently with reducing agents at higher temperature and pressures. Nitroalkanes react with inorganic bases to form explosive salts. The presence of metal oxides increases the thermal sensitivity of nitroalkanes. Nitroalkanes with more than one nitro group are generally explosive. Nitroalkanes are insoluble in water.

Source: CAMEO Chemicals

Planning storage for a mix of chemicals? Check Mannitol Hexanitrate in the storage compatibility matrix →

10 · Transport

Mannitol Hexanitrate UN number and transport classification

Transport classification is a separate system from the GHS classification above. It decides how a package is marked and how a load may be carried; it does not follow from the workplace label, and the workplace label does not follow from it. The entries below are linked by CAS number, never by name.

Mannitol Hexanitrate under UN 0133 — shipping name, class and packing group

Europe · ADR 2025, Table A

Proper shipping name (3.1.2) Class Classification code PG Labels (column 5)
MANNITOL HEXANITRATE (NITROMANNITE), WETTED with not less than 40 % water, or mixture of alcohol and water, by mass 1 1.1D
  • ADR label model 1 — Explosive, division 1.1, compatibility group D
1

Source: ADR 2025, Table A of Chapter 3.2 · ECE/TRANS/352 Vol. I (UNECE). Class 1 is “Explosive substances and articles” (ADR 2.1.1.1).

Proper shipping name (column 2) Class or division PG Labels (column 6)
Mannitol hexanitrate, wetted or Nitromannite, wetted with not less than 40 percent water, or mixture of alcohol and water, by mass 1.1D
  • US DOT EXPLOSIVE 1.1 label (§172.411), compatibility group D
1.1D

Source: 49 CFR 172.101 Hazardous Materials Table · eCFR, revision 2026-08-03. Class 1.1D is “Explosives (with a mass explosion hazard)” (49 CFR 173.2).

Full UN 0133 entry — special provisions, packing instructions, quantity limits and the orange plate →

11 · Questions

Mannitol Hexanitrate — frequently asked questions

What is the CAS number of Mannitol Hexanitrate?

The CAS number of Mannitol Hexanitrate is 15825-70-4. Its EC number is 239-924-6.

What is the chemical formula of Mannitol Hexanitrate?

The molecular formula of Mannitol Hexanitrate is C6H8N6O18 and its molecular weight is 452.16 g/mol.

What does a Mannitol Hexanitrate label have to show?

Under CLP Annex VI the label for Mannitol Hexanitrate carries the pictogram Exploding bomb and the signal word is Danger.

Is Mannitol Hexanitrate flammable?

CLP Annex VI assigns Mannitol Hexanitrate no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it.

Is Mannitol Hexanitrate a carcinogen?

CLP Annex VI records no harmonised carcinogenicity classification for Mannitol Hexanitrate. Annex VI is a list of agreed classifications, not a list of substances found safe, so this is an absence of a classification rather than a clean bill of health.

What is the boiling point of Mannitol Hexanitrate?

The boiling point reported for Mannitol Hexanitrate is Explodes (HSDB).

What is the melting point of Mannitol Hexanitrate?

The melting point reported for Mannitol Hexanitrate is 107 °C (224.6 °F) (HSDB).

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