Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Octanoic Acid

Octanoic Acid is solidifies to leafy crystals when cold with a faint, fruity-acid odor.

CAS 124-07-2 Danger

01 · Identification

What Octanoic Acid is

Octanoic Acid is solidifies to leafy crystals when cold with a faint, fruity-acid odor. It boils at 239 °C, melts at 16.5 °C, is miscible with water.

Under the GHS it carries the signal word Danger.

02 · Identifiers

Octanoic Acid identifiers and molecular data

Octanoic Acid CAS number and EC number

CAS number124-07-2
EC number204-677-5
Index number (CLP Annex VI)607-708-00-4

03 · GHS classification

Octanoic Acid hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Octanoic Acid pictograms and signal word

Signal wordDanger

Octanoic Acid hazard class and category

GHS hazard classes Octanoic Acid falls into
Hazard class Category From code Pictogram
Skin corrosion/irritation GHS chapter 3.2 Category 1A or 1B or 1C H314 GHS05
Hazardous to the aquatic environment - chronic GHS chapter 4.1 Category 3 H412

Where two values are shown with “or”, the hazard statement is shared by more than one category or by more than one class, and the code alone does not say which. H272, for example, belongs to oxidising liquids and to oxidising solids — the physical state decides. The binding answer for a specific entry is in the CLP Annex VI table itself.

Octanoic Acid hazard statements (H-codes)

Hazard statements assigned to Octanoic Acid
CodeHazard statement
H314 Causes severe skin burns and eye damage.
H412 Harmful to aquatic life with long lasting effects.

This page lists only the codes assigned to Octanoic Acid. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for Octanoic Acid

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of Octanoic Acid issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

Octanoic Acid precautionary statements

CLP Annex VI assigns 7 precautionary statements to Octanoic Acid. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Response

What to do once exposure, spillage or fire has already happened.

Disposal

What has to happen to the contents and the empty container.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

Octanoic Acid name in 22 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български октанова киселина
Spanish español ácido octanoico
Czech čeština oktanová kyselina
Danish dansk octansyre
German Deutsch Octansäure
Estonian eesti oktaanhape
Greek ελληνικά οκτανοϊκό οξύ
English English octanoic acid
French français acide octanoïque
Italian italiano acido ottanoico
Latvian latviešu oktānskābe
Lithuanian lietuvių oktano rūgštis
Hungarian magyar oktánsav kálisó-kaprilsav
Maltese Malti aċidu oktanojku
Dutch Nederlands octaanzuur
Polish polski kwas oktanowy
Portuguese português ácido octanoico
Romanian română acid octanoic
Slovak slovenčina kyselina oktánová
Slovenian slovenščina oktanojska kislina
Finnish suomi Oktaanihappo
Swedish svenska oktansyra

22 of the 23 language editions carry this entry; it is absent from Croatian. That is a property of the regulation, not a gap in this table — editions do occasionally differ in which entries they print. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

Octanoic Acid GHS label elements

Everything CLP Annex VI fixes for Octanoic Acid, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS05 Corrosion pictogram

Danger

Octanoic Acid

  • Causes severe skin burns and eye damage.
  • Harmful to aquatic life with long lasting effects.
  • Do not breathe dust/fume/gas/mist/vapours/spray.
  • Avoid release to the environment.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • IF SWALLOWED:
  • Immediately call a POISON CENTER/doctor/
  • Do NOT induce vomiting.
  • Dispose of contents/container to

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open Octanoic Acid in the GHS label constructor →

07 · Health hazards

Octanoic Acid health hazards and exposure limits

Octanoic Acid hazard summary

Category of C7-C9 aliphatic aldehydes and carboxylic acids: Members and supporting chemicals demonstrate low acute toxicity by oral, dermal, and inhalation exposures; toxicity in repeated-dose studies only at relatively high levels; no evidence of reproductive toxicity, developmental toxicity, or mutagenicity; [EPA ChAMP: Hazard Characterization] Corrosive to skin; [Quick CPC] A skin, eye, and mucous membrane irritant; [HSDB] An irritant; [MSDSonline]

Source: Haz-Map, Information on Hazardous Chemicals and Occupational Diseases

08 · Physical and chemical properties

Octanoic Acid properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

Octanoic Acid boiling point

Property Value Conditions Source
Boiling point 239 °C (462.2 °F) HSDB
239.72 °C (463.5 °F) at 760 mmHg CAMEO
240 °C (464 °F) at 760 mmHg DOE PAC

Octanoic Acid melting point

Property Value Conditions Source
Melting point 16.5 °C (61.7 °F) HSDB
16.39 °C (61.5 °F) range, midpoint shown CAMEO

Octanoic Acid density

Property Value Conditions Source
Density 0.91 g/cm³ CAMEO
0.91 g/cm³ at 20 °C HSDB

Octanoic Acid solubility

Property Value Conditions Source
Solubility Miscible in ethanol, chloroform, acetonitrile HSDB
slightly soluble in water; soluble in most organic solvents JECFA
Very slightly sol in water (0.068 g/100 g at 20 °C); freely sol in alcohol, chloroform, ether, carbon disulfide, petroleum ether, glacial acetic acid at 20 °C HSDB

Octanoic Acid vapor pressure

Property Value Conditions Source
Vapor pressure 0.0037 mmHg at 25 °C HSDB
1 mmHg at 78 °C HSDB
1 mmHg at 92.28 °C CAMEO

Octanoic Acid flash point

Property Value Conditions Source
Flash point 130 °C (266 °F) open cup HSDB
132.22 °C (270 °F) HSDB
110 °C (230 °F) CAMEO

Octanoic Acid lower explosive limit (LEL)

Property Value Conditions Source
Lower explosive limit (LEL) Combustible HSDB

Octanoic Acid odor threshold

Property Value Conditions Source
Odor threshold IT CAN BE DETECTED @ 0.008 PPM. HSDB
Aroma threshold values: Detection: 910 ppb to 19 ppm. HSDB
Odor Threshold Low: 0.008 [ppm] Haz-Map

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

09 · Fire and explosion

Octanoic Acid fire and explosion behaviour

These are descriptions rather than measured values, so they are kept out of the table above and quoted here with the source that reported them.

Octanoic Acid fire potential

Combustible

Source: Hazardous Substances Data Bank (HSDB)

10 · Handling and storage

Octanoic Acid storage and handling

Octanoic Acid storage conditions

Containers less than 1 gallon: Store in original container in areas inaccessible to children and persons unfamiliar with its proper use. Containers greater than 1 gallon: Do not contaminate water, food, feed by storage or disposal. ... Store this product in a cool, dry area, away from direct sunlight and heat../65 Disinfecting Heavy Duty Acid Bathroom Cleaner/

Source: Hazardous Substances Data Bank (HSDB)

Planning storage for a mix of chemicals? Check Octanoic Acid in the storage compatibility matrix →

11 · Questions

Octanoic Acid — frequently asked questions

What is the CAS number of Octanoic Acid?

The CAS number of Octanoic Acid is 124-07-2. Its EC number is 204-677-5.

What does a Octanoic Acid label have to show?

Under CLP Annex VI the label for Octanoic Acid carries the pictogram Corrosion and the signal word is Danger.

Is Octanoic Acid flammable?

CLP Annex VI assigns Octanoic Acid no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it. The flash point reported for it is 130 °C (266 °F), open cup (HSDB).

Is Octanoic Acid a carcinogen?

CLP Annex VI records no harmonised carcinogenicity classification for Octanoic Acid. Annex VI is a list of agreed classifications, not a list of substances found safe, so this is an absence of a classification rather than a clean bill of health.

What is the boiling point of Octanoic Acid?

The boiling point reported for Octanoic Acid is 239 °C (462.2 °F) (HSDB).

What is the melting point of Octanoic Acid?

The melting point reported for Octanoic Acid is 16.5 °C (61.7 °F) (HSDB).

How should Octanoic Acid be stored?

Containers less than 1 gallon: Store in original container in areas inaccessible to children and persons unfamiliar with its proper use. Containers greater than 1 gallon: Do not contaminate water, food, feed by storage or disposal. ... Store this product in a cool, dry area, away from direct sunlight and heat../65 Disinfecting Heavy Duty Acid Bathroom Cleaner/ (Hazardous Substances Data Bank (HSDB))

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