Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Triamiphos

Triamiphos is white crystals.

CAS 1031-47-6 Danger

01 · Identification

What Triamiphos is

Triamiphos is white crystals. It boils at 400 °C, melts at 168 °C.

Under the GHS it carries the signal word Danger.

02 · Identifiers

Triamiphos identifiers and molecular data

Triamiphos CAS number and EC number

CAS number1031-47-6
Index number (CLP Annex VI)015-024-00-7

Other names for Triamiphos

  • triamiphos (ISO)
  • 5-amino-3-phenyl-1,2,4-triazol-1-yl-N,N,N',N'-tetramethylphosphonic diamide

03 · GHS classification

Triamiphos hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Triamiphos pictograms and signal word

Signal wordDanger

Triamiphos hazard class and category

GHS hazard classes Triamiphos falls into
Hazard class Category From code Pictogram
Acute toxicity - oral GHS chapter 3.1 Category 1 or 2 H300 GHS06
Acute toxicity - dermal GHS chapter 3.1 Category 1 or 2 H310 GHS06

Where two values are shown with “or”, the hazard statement is shared by more than one category or by more than one class, and the code alone does not say which. H272, for example, belongs to oxidising liquids and to oxidising solids — the physical state decides. The binding answer for a specific entry is in the CLP Annex VI table itself.

Triamiphos hazard statements (H-codes)

Hazard statements assigned to Triamiphos
CodeHazard statement
H310 Fatal in contact with skin.
H300 Fatal if swallowed.

This page lists only the codes assigned to Triamiphos. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for Triamiphos

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of Triamiphos issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

Triamiphos precautionary statements

CLP Annex VI assigns 7 precautionary statements to Triamiphos. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

Triamiphos name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български триамифос (ISO) 5-амино-3-фенил-1,2,4-триазол-1-ил- N , N , N ′, N ′-тетраметилфосфонов диамид
Spanish español Triamifós (ISO) diamida del ácido 5-amino-3-fenil-1,2,4-triazol-1-il- N, N,N',N' -tetrametilfosfónico
Czech čeština triamifos (ISO) 2-[bis(dimethylamino)fosforyl]-5-fenyl-2 H -1,2,4-triazol-3-amin
Danish dansk triamiphos (ISO) 5-amino-3-phenyl-1,2,4-triazol-1-yl- N, N,N' , N' -tetramethylphosphondiamid
German Deutsch Triamiphos (ISO) 5-Amino-3-phenyl-1,2,4-triazol-1-yl- N, N,N',N' -tetramethylphosphonsäurediamid
Estonian eesti triamifoss (ISO) 5-amino-3-fenüül-1,2,4-triasool-1-üül- N , N , N ', N '-tetrametüülfosfoondiamiid
Greek ελληνικά triamiphos (τριαμιφός) (ISO) 5-αμινο-3-φαινυλο-1,2,4-τριαζολ-1-υλο- N, N,N′,N′ -τετραμεθυλοφωσφονικό διαμίδιο
English English triamiphos (ISO) 5-amino-3-phenyl-1,2,4-triazol-1-yl- N, N,N',N' -tetramethylphosphonic diamide
French français triamiphos (ISO) diamide 5-amino-3-phényl-1,2,4-triazol-1-yl- N, N,N',N' -tétraméthylphosphonique
Croatian hrvatski triamifos (ISO) 5-amino-3-fenil-1,2,4-triazol-1-il- N, N,N',N' -tetrametil-fosfonij-diamid
Italian italiano triamifos (ISO) diammide 5-ammino-3-fenil-1,2,4-triazol-1-il- N , N , N ', N '-tetrametilfosfonica
Latvian latviešu triamifoss (ISO) 5-amino-3-fenil-1,2,4-triazol-1-il- N, N,N',N' -tetrametilfosfondiamīds
Lithuanian lietuvių triamifosas (ISO) 5-amino-3-fenil-1,2,4-triazol-1-il- N, N,N',N' -tetrametilfosfondiamidas
Hungarian magyar triamfosz (ISO) 5-amino-3-fenil-1,2,4-triazol-1-il- N, N,N’,N’ -tetrametilfoszfonsav-diamid
Maltese Malti triamifos (ISO) diammid 5-ammino-3-fenul-1,2,4-triażol-1-il-N, N,N',N'-tetrametilfosfoniku
Dutch Nederlands triamifos (ISO) 5-amino-3-fenyl-1,2,4-triazool-1-yl- N , N , N' , N' -tetramethylfosfondiamide
Polish polski triamifos (ISO) bis(dimetyloamid) 5-amino-3-fenylo-1H-1,2,4-triazol-1-ilofosfonowy
Portuguese português triamifos (ISO) diamida 5-amino-3-fenil-1,2,4-triazol-1-il- N , N , N ', N '-tetrametilfosfónica
Romanian română triamifos (ISO) 5-amino-3-fenil-1,2,4- triazol-1-il- N, N,N',N' - tetrametilfosfondiamidă
Slovak slovenčina triamifos (ISO) 2-[bis(dimetylamino)fosforyl]-5-fenyl-2 H -1,2,4-triazol-3-amín
Slovenian slovenščina triamifos (ISO) 5-amino-3-fenil-1,2,4-triazol-1-il- N, N,N',N' -tetrametilfosfonski diamid
Finnish suomi triamifossi (ISO) 5-amino-3-fenyyli-1,2,4-triatsol-1-yyli- N, N,N',N' -tetrametyylifosfonidiamiini
Swedish svenska triamifos (ISO) 5-amino-3-fenyl-1,2,4-triazol-1-yl- N, N,N',N' -tetrametylfosfondiamid

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

Triamiphos GHS label elements

Everything CLP Annex VI fixes for Triamiphos, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS06 Skull and crossbones pictogram

Danger

Triamiphos

  • Fatal in contact with skin.
  • Fatal if swallowed.
  • Do not eat, drink or smoke when using this product.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • IF SWALLOWED:
  • IF ON SKIN:
  • Immediately call a POISON CENTER/doctor/
  • Rinse mouth.
  • Wash with plenty of water/

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open Triamiphos in the GHS label constructor →

07 · Health hazards

Triamiphos health hazards and exposure limits

Triamiphos hazard summary

Causes moderate to severe erythema and moderate edema to skin; [HSDB] A cholinesterase inhibitor; Can be absorbed through skin; [CAMEO] The average of two baseline respective cholinesterase activity determinations three days apart, with no exposures to enzyme inhibiting pesticides for at least 30 days, is recommended for each worker prior to exposure to cholinesterase inhibitors because of large inter-individual differences in published baseline values. To be established at least once a year. Removal from workplace exposures is recommended until the cholinesterase activity returns to within 20% of baseline. [TLVs and BEIs]

Source: Haz-Map, Information on Hazardous Chemicals and Occupational Diseases

08 · Physical and chemical properties

Triamiphos properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

Triamiphos boiling point

Property Value Conditions Source
Boiling point 400 °C (752 °F) at 760 mmHg DOE PAC
Decomposes on distillation decomposes HSDB

Triamiphos melting point

Property Value Conditions Source
Melting point 168 °C (334.4 °F) range, midpoint shown HSDB

Triamiphos solubility

Property Value Conditions Source
Solubility Moderately soluble in most common organic solvents except petroleum ether. HSDB
250 mg/l in water @ 20 °C at 20 °C HSDB
5 g/l in benzene @ 20 °C at 20 °C HSDB

Triamiphos vapor pressure

Property Value Conditions Source
Vapor pressure 1e-7 mmHg at 25 °C DOE PAC
Very low at room temperature HSDB

Triamiphos corrosivity

Property Value Conditions Source
Corrosivity Non-corrosive HSDB

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

09 · Handling and storage

Triamiphos storage and handling

Triamiphos reactivity

Organophosphates, such as TRIAMIPHOS, are susceptible to formation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrides. Partial oxidation by oxidizing agents may result in the release of toxic phosphorus oxides.

Source: CAMEO Chemicals

Planning storage for a mix of chemicals? Check Triamiphos in the storage compatibility matrix →

10 · Questions

Triamiphos — frequently asked questions

What is the CAS number of Triamiphos?

The CAS number of Triamiphos is 1031-47-6.

What does a Triamiphos label have to show?

Under CLP Annex VI the label for Triamiphos carries the pictogram Skull and crossbones and the signal word is Danger.

Is Triamiphos flammable?

CLP Annex VI assigns Triamiphos no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it.

Is Triamiphos a carcinogen?

CLP Annex VI records no harmonised carcinogenicity classification for Triamiphos. Annex VI is a list of agreed classifications, not a list of substances found safe, so this is an absence of a classification rather than a clean bill of health.

What is the boiling point of Triamiphos?

The boiling point reported for Triamiphos is 400 °C (752 °F), at 760 mmHg (DOE PAC).

What is the melting point of Triamiphos?

The melting point reported for Triamiphos is 168 °C (334.4 °F), range, midpoint shown (HSDB).

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