Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Triethylene Glycol Dimethacrylate

Triethylene Glycol Dimethacrylate: liquid.

CAS 109-16-0 C14H22O6 286.32 g/mol Warning

01 · Identification

What Triethylene Glycol Dimethacryl… is

Triethylene Glycol Dimethacrylate: liquid. Its molecular formula is C14H22O6 and its molecular weight is 286.32 g/mol.

Under the GHS it carries the signal word Warning.

02 · Identifiers

Triethylene Glycol Dimethacryl… identifiers and molecular data

Triethylene Glycol Dimethacryl… CAS number and EC number

CAS number109-16-0
EC number203-652-6
Index number (CLP Annex VI)607-768-00-1

Triethylene Glycol Dimethacryl… molecular formula and molecular weight

Molecular formulaC14H22O6
Molecular weight286.32 g/mol

Other names for Triethylene Glycol Dimethacryl…

  • 2,2'-ethylenedioxydiethyl dimethacrylate

03 · GHS classification

Triethylene Glycol Dimethacryl… hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Triethylene Glycol Dimethacryl… pictograms and signal word

Signal wordWarning

Triethylene Glycol Dimethacryl… hazard class and category

GHS hazard classes Triethylene Glycol… falls into
Hazard class Category From code Pictogram
Skin sensitisation GHS chapter 3.4 Category 1 or 1A or 1B H317 GHS07

Where two values are shown with “or”, the hazard statement is shared by more than one category or by more than one class, and the code alone does not say which. H272, for example, belongs to oxidising liquids and to oxidising solids — the physical state decides. The binding answer for a specific entry is in the CLP Annex VI table itself.

Triethylene Glycol Dimethacryl… hazard statements (H-codes)

Hazard statements assigned to Triethylene Glycol…
CodeHazard statement
H317 May cause an allergic skin reaction.

This page lists only the codes assigned to Triethylene Glycol…. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for Triethylene Glycol…

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of Triethylene Glycol… issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

Triethylene Glycol Dimethacryl… precautionary statements

CLP Annex VI assigns 5 precautionary statements to Triethylene Glycol…. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Response

What to do once exposure, spillage or fire has already happened.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

Triethylene Glycol Dimethacryl… name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български 2,2’-етилендиоксидиетил диметакрилат
Spanish español Dimetacrilato de 2,2’-etilendioxidietilo
Czech čeština 2,2’-ethylendioxydiethyl-dimethakrylát
Danish dansk 2,2'-ethylendioxydiethyldimethacrylat
German Deutsch 2,2’-Ethylendioxydiethyldimethacrylat
Estonian eesti 2,2’-etüleenedioksüdietüüldimetakrülaat
Greek ελληνικά διμεθακρυλικό 2,2′-αιθυλενοδιοξυδιαιθύλιο διμεθακρυλικός 2,2′-αιθυλενοδιοξυδιαιθυλεστέρας
English English 2,2'-ethylenedioxydiethyl dimethacrylate
French français diméthacrylate de 2,2 ’-éthylènedioxydiéthyl
Croatian hrvatski 2,2′-etilendioksidietil dimetakrilat
Italian italiano dimetacrilato di 2,2’-etilendiossidietile
Latvian latviešu 2,2’-etilēndioksidietildimetakrilāts
Lithuanian lietuvių 2,2’-etilenodioksietildimetakrilatas
Hungarian magyar 2‚2’-(etiléndioxi)dietil-dimetakrilát
Maltese Malti 2,2’-etilendiossidietil dimetilakrilat
Dutch Nederlands 2,2'-ethyleendioxydiëthyldimethacrylaat
Polish polski dimetakrylan 2,2’-etylenodioksydietylu
Portuguese português dimetacrilato de 2,2’-etilenodioxidietilo
Romanian română 2,2’-etilendioxidietil dimetacrilat
Slovak slovenčina 2‚2’-etylénbis(oxy)dietylén-dimetakrylát
Slovenian slovenščina 2‚2’-etilendioksidietil dimetakrilat
Finnish suomi 2,2’-etyleenidioksidietyylidimetakrylaatti
Swedish svenska 2,2’-etylendioxidietyldimetakrylat

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

Triethylene Glycol Dimethacryl… GHS label elements

Everything CLP Annex VI fixes for Triethylene Glycol…, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS07 Exclamation mark pictogram

Warning

Triethylene Glycol Dimethacryl…

  • May cause an allergic skin reaction.
  • Avoid breathing dust/fume/gas/mist/vapours/spray.
  • Contaminated work clothing should not be allowed out of the workplace.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • Get medical advice/attention.
  • If skin irritation or rash occurs:

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open Triethylene Glycol… in the GHS label constructor →

07 · Health hazards

Triethylene Glycol Dimethacryl… health hazards and exposure limits

Triethylene Glycol Dimethacryl… hazard summary

Allergic contact dermatitis reported in dental technicians; [Kanerva, p. 1744] May polymerize on exposure to light; An irritant; May cause skin sensitization; [Aldrich MSDS]

Source: Haz-Map, Information on Hazardous Chemicals and Occupational Diseases

08 · Physical and chemical properties

Triethylene Glycol Dimethacryl… properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

Triethylene Glycol Dimethacryl… boiling point

Property Value Conditions Source
Boiling point 155 °C (311 °F) at 0.97508 mmHg (reduced pressure) HSDB

Triethylene Glycol Dimethacryl… density

Property Value Conditions Source
Density 1.09 g/cm³ at 20 °C DOE PAC
1.072 g/cm³ at 25 °C HSDB

Triethylene Glycol Dimethacryl… solubility

Property Value Conditions Source
Solubility > 10% in acetone HSDB
> 10% in ethanol HSDB
> 10% in ether HSDB

Triethylene Glycol Dimethacryl… vapor pressure

Property Value Conditions Source
Vapor pressure 0.00094 mmHg Haz-Map

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

09 · Handling and storage

Triethylene Glycol Dimethacryl… storage and handling

Triethylene Glycol Dimethacryl… storage conditions

Temp during storage must be kept low to minimize formation of peroxides and other oxidation products. ... Storage temp below 30 °C are recommended for the polyfunctional methacrylates. ... The methacrylate monomers should not be stored for longer than one year. Shorter storage times are recommended for the aminomethacrylates, ie, three months, and the polyfunctional methacrylates, ie, six months. Many of these cmpd are sensitive to UV light and should, therefore, be stored in the dark. The methacrylic esters may be stored in mild steel, stainless steel, or aluminum. /Methacrylic acid & derivatives/

Source: Hazardous Substances Data Bank (HSDB)

Planning storage for a mix of chemicals? Check Triethylene Glycol… in the storage compatibility matrix →

10 · Questions

Triethylene Glycol Dimethacryl… — frequently asked questions

What is the CAS number of Triethylene Glycol Dimethacryl…?

The CAS number of Triethylene Glycol Dimethacryl… is 109-16-0. Its EC number is 203-652-6.

What is the chemical formula of Triethylene Glycol Dimethacryl…?

The molecular formula of Triethylene Glycol Dimethacryl… is C14H22O6 and its molecular weight is 286.32 g/mol.

What does a Triethylene Glycol Dimethacryl… label have to show?

Under CLP Annex VI the label for Triethylene Glycol Dimethacryl… carries the pictogram Exclamation mark and the signal word is Warning.

Is Triethylene Glycol Dimethacryl… flammable?

CLP Annex VI assigns Triethylene Glycol Dimethacryl… no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it.

Is Triethylene Glycol Dimethacryl… a carcinogen?

CLP Annex VI records no harmonised carcinogenicity classification for Triethylene Glycol Dimethacryl…. Annex VI is a list of agreed classifications, not a list of substances found safe, so this is an absence of a classification rather than a clean bill of health.

What is the boiling point of Triethylene Glycol Dimethacryl…?

The boiling point reported for Triethylene Glycol Dimethacryl… is 155 °C (311 °F), at 0.97508 mmHg (reduced pressure) (HSDB).

How should Triethylene Glycol Dimethacryl… be stored?

Temp during storage must be kept low to minimize formation of peroxides and other oxidation products. ... Storage temp below 30 °C are recommended for the polyfunctional methacrylates. ... The methacrylate monomers should not be stored for longer than one year. Shorter storage times are recommended for the aminomethacrylates, ie, three months, and the polyfunctional methacrylates, ie, six months. Many of these cmpd are sensitive to UV light and should, therefore, be stored in the dark. The methacrylic esters may be stored in mild steel, stainless steel, or aluminum. /Methacrylic acid & derivatives/ (Hazardous Substances Data Bank (HSDB))

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