Substance profile
1,3,5-tris(oxiranylmethyl)-1,3,5-triazine-2,4,6(1H,3H,5H)-trione
1,3,5-tris(oxiranylmethyl)-1,3,5-triazine-2,4,6(1H,3H,5H)-trione is a white crystalline solid with a no odor at room temperature.
01 · Identification
What 1,3,5-tris(oxiranylmethyl)-1,3… is
1,3,5-tris(oxiranylmethyl)-1,3,5-triazine-2,4,6(1H,3H,5H)-trione is a white crystalline solid with a no odor at room temperature. It boils at 240 °C, melts at 95 °C.
Under the GHS it carries the signal word Danger.
02 · Identifiers
1,3,5-tris(oxiranylmethyl)-1,3… identifiers and molecular data
1,3,5-tris(oxiranylmethyl)-1,3… CAS number and EC number
Other names for 1,3,5-tris(oxiranylmethyl)-1,3…
- TGIC
03 · GHS classification
1,3,5-tris(oxiranylmethyl)-1,3… hazard classification
Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.
1,3,5-tris(oxiranylmethyl)-1,3… pictograms and signal word
1,3,5-tris(oxiranylmethyl)-1,3… hazard class and category
| Hazard class | Category | From code | Pictogram |
|---|---|---|---|
| Acute toxicity - oral GHS chapter 3.1 | Category 3 | H301 | GHS06 |
| Acute toxicity - inhalation GHS chapter 3.1 | Category 3 | H331 | GHS06 |
| Serious eye damage/eye irritation GHS chapter 3.3 | Category 1 | H318 | GHS05 |
| Skin sensitisation GHS chapter 3.4 | Category 1 or 1A or 1B | H317 | GHS07 |
| Germ cell mutagenicity GHS chapter 3.5 | Category 1A or 1B | H340 | GHS08 |
| Specific target organ toxicity - repeated exposure GHS chapter 3.9 | Category 2 | H373 | GHS08 |
| Hazardous to the aquatic environment - chronic GHS chapter 4.1 | Category 3 | H412 | — |
Where two values are shown with “or”, the hazard statement is shared by more than one category or by more than one class, and the code alone does not say which. H272, for example, belongs to oxidising liquids and to oxidising solids — the physical state decides. The binding answer for a specific entry is in the CLP Annex VI table itself.
1,3,5-tris(oxiranylmethyl)-1,3… hazard statements (H-codes)
| Code | Hazard statement |
|---|---|
| H340 | May cause genetic defects <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>. |
| H331 | Toxic if inhaled. |
| H301 | Toxic if swallowed. |
| H373 | May cause damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>. |
| H318 | Causes serious eye damage. |
| H317 | May cause an allergic skin reaction. |
| H412 | Harmful to aquatic life with long lasting effects. |
This page lists only the codes assigned to 1,3,5-tris(oxiranylmethyl)…. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.
Safety Data Sheet
Getting an SDS for 1,3,5-tris(oxiranylmethyl)…
A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of 1,3,5-tris(oxiranylmet… issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.
04 · Precautionary statements
1,3,5-tris(oxiranylmethyl)-1,3… precautionary statements
CLP Annex VI assigns 19 precautionary statements to 1,3,5-tris(oxiranylmethyl)…. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.
Prevention
What to do before and during handling so the hazard never happens.
Response
What to do once exposure, spillage or fire has already happened.
Disposal
What has to happen to the contents and the empty container.
Reading the notation. … is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.
05 · Names in the regulation
1,3,5-tris(oxiranylmethyl)-1,3… name in 23 EU languages
CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.
| Language | Name in CLP Annex VI Part 3 |
|---|---|
| Bulgarian български | 1,3,5-трис(оксиранилметил)-1,3,5-триазин-2,4,6(1 H ,3 H ,5 H )-трион TGIC |
| Spanish español | 1,3,5-Tris(oxiranilmetil)-1,3,5-triazina-2,4,6(1 H ,3 H ,5 H )-triona TGIC |
| Czech čeština | 1,3,5-tris(2,3-epoxypropyl)-1,3,5-triazin-2(1 H ),4(3 H ),6(5 H )-trion TGIC |
| Danish dansk | 1,3,5-tris(oxiranylmethyl)-1,3,5-triazin-2,4,6(1 H, 3 H, 5 H )-trion TGIC |
| German Deutsch | 1,3,5-Tris(oxiranylmethyl)-1,3,5-triazin-2,4,6(1 H ,3 H ,5 H )trion TGICTriglycidylisocyanurat |
| Estonian eesti | 1,3,5-tris(oksiranüülmetüül)-1,3,5-triasiin-2,4,6-(1 H ,3 H ,5 H )-trioon TGIC |
| Greek ελληνικά | 1,3,5,-τρις(οξιρανυλομεθυλο)-1,3,5-τριαζινο-2,4,6(1 H ,3 H ,5 H )-τριόνη TGIC |
| English English | 1,3,5-tris(oxiranylmethyl)-1,3,5-triazine-2,4,6(1 H ,3 H ,5 H )-trione TGIC |
| French français | 1,3,5-tris(oxiranylméthyl)-1,3,5-triazine-2,4,6(1 H ,3 H ,5 H )-trione TGIC |
| Croatian hrvatski | 1,3,5-tris(oksiranilmetil)-1,3,5-triazin-2,4,6(1 H ,3 H ,5 H )-trion TGIC |
| Italian italiano | 1,3,5-tris(ossiranilmetil)-1,3,5-triazin-2,4,6(1 H ,3 H ,5 H )-trione TGIC |
| Latvian latviešu | 1,3,5-tris(oksiranilmetil)-1,3,5-triazīn-2,4,6(1 H ,3 H ,5 H )-trions TGIC |
| Lithuanian lietuvių | 1,3,5-tri(oksiranilmetil)-1,3,5-triazin-2,4,6(1 H ,3 H ,5 H )-trionas TGIC |
| Hungarian magyar | 1,3,5-trisz(oxiranilmetil)-1,3,5-triazin-2,4,6-(1 H ,3 H ,5 H )-trion TGIC |
| Maltese Malti | 1,3,5-tris(ossiranilmetil)-1,3,5-triażina-2,4,6(1 H ,3 H ,5 H )-trion TGIC |
| Dutch Nederlands | 1,3,5-tris(oxiranylmethyl)-1,3,5-triazine-2,4,6(1 H ,3 H ,5 H )-trion TGIC |
| Polish polski | 1,3,5-tris(oksiranylometylo)-1,3,5-triazyno-2,4,6(1 H ,3 H ,5 H )-trion TGIC |
| Portuguese português | 1,3,5-tris(oxiranilmetil)-1,3,5-triazina-2,4,6-(1 H ,3 H ,5 H )-triona TGIC |
| Romanian română | 1,3,5-tris(oxiranilmetil)-1,3,5-triazin-2,4,6(1 H ,3 H ,5 H )-trionă TGIC |
| Slovak slovenčina | 1,3,5-tris(oxiranylmetyl)-1,3,5-triazín-2,4,6(1 H ,3 H ,5 H )-trión TGIC |
| Slovenian slovenščina | 1,3,5-tris(oksiranilmetil)-1,3,5-triazin-2,4,6(1 H ,3 H ,5 H )-trion TGIC |
| Finnish suomi | 1,3,5-tris(oksiranyylimetyyli)-1,3,5-triatsiini-2,4,6(1 H ,3 H ,5 H )-trioni TGIC |
| Swedish svenska | 1,3,5-tris(oxiranylmetyl)-1,3,5-triazin-2,4,6(1 H ,3 H ,5 H )-trion TGIC |
All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.
06 · Label elements
1,3,5-tris(oxiranylmethyl)-1,3… GHS label elements
Everything CLP Annex VI fixes for 1,3,5-tris(oxiranylmethyl)…, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.
Danger
1,3,5-tris(oxiranylmethyl)-1,3…
- May cause genetic defects <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
- Toxic if inhaled.
- Toxic if swallowed.
- May cause damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
- Causes serious eye damage.
- May cause an allergic skin reaction.
- Harmful to aquatic life with long lasting effects.
- Obtain special instructions before use.
- Do not breathe dust/fume/gas/mist/vapours/spray.
- Avoid breathing dust/fume/gas/mist/vapours/spray.
- Do not eat, drink or smoke when using this product.
- Use only outdoors or in a well-ventilated area.
- Contaminated work clothing should not be allowed out of the workplace.
- Avoid release to the environment.
- Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/…
- IF SWALLOWED:
- IF INHALED:
- IF IN EYES:
- IF exposed or concerned:
- Immediately call a POISON CENTER/doctor/…
- Get medical advice/attention.
- Get medical advice/attention if you feel unwell.
- Rinse mouth.
- If skin irritation or rash occurs:
- Remove contact lenses, if present and easy to do. Continue rinsing.
- Dispose of contents/container to …
Supplier name, address and telephone number· Product identifier·Nominal quantity
Need this as an actual label? Open 1,3,5-tris(oxiranylmethyl)… in the GHS label constructor →
07 · Health hazards
1,3,5-tris(oxiranylmethyl)-1,3… health hazards and exposure limits
1,3,5-tris(oxiranylmethyl)-1,3… hazard summary
A nonsmoking spray painter, after using a polyester powder paint containing 4% TGIC for four years, developed allergic contact dermatitis and work-related asthma. The painter had negative skin tests for common allergens and negative challenge test with lactose powder. A challenge test with 4% TGIC induced a dual response with a late 23% fall in FEV1. [Piirila P, et al. Occupational Asthma Caused by Triglycidyl Isocyanurate (TGIC). Clin Exp Allergy 1997 May;27(5):510-4] TGIC causes male reproductive damage in high-dose animal studies. [ACGIH] A severe eye irritant; May cause skin sensitization; [ICSC] Danger of skin and airway sensitization; [MAK]
Source: Haz-Map, Information on Hazardous Chemicals and Occupational Diseases
08 · Physical and chemical properties
1,3,5-tris(oxiranylmethyl)-1,3… properties
Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.
1,3,5-tris(oxiranylmethyl)-1,3… boiling point
| Property | Value | Conditions | Source |
|---|---|---|---|
| Boiling point | 240 °C (464 °F) | above this value | HSDB |
| 210 °C (410 °F) | at 0.2 mmHg (reduced pressure) | HSDB |
1,3,5-tris(oxiranylmethyl)-1,3… melting point
| Property | Value | Conditions | Source |
|---|---|---|---|
| Melting point | 95 °C (203 °F) | HSDB | |
| 96.39 °C (205.5 °F) | range, midpoint shown | HSDB |
1,3,5-tris(oxiranylmethyl)-1,3… density
| Property | Value | Conditions | Source |
|---|---|---|---|
| Density | 142-144 at 20 °C | at 20 °C | HSDB |
1,3,5-tris(oxiranylmethyl)-1,3… solubility
| Property | Value | Conditions | Source |
|---|---|---|---|
| Solubility | Exists as a mixture of 2 pairs of diastereomer racemates, designated alpha and beta, that are separable on the basis of their solubility properties | HSDB | |
| log Kow: -0.8. Solubility in water: 0.9 g/100 mL at 25 °C | at 25 °C, Triglycidyl isocyanurate technical grade | HSDB | |
| In water, 9-10.5 g/L at 25 °C, pH 5-8 | at 25 °C | HSDB |
1,3,5-tris(oxiranylmethyl)-1,3… vapor pressure
| Property | Value | Conditions | Source |
|---|---|---|---|
| Vapor pressure | 0.0000525 mmHg | below this value, at 20 °C | HSDB |
1,3,5-tris(oxiranylmethyl)-1,3… flash point
| Property | Value | Conditions | Source |
|---|---|---|---|
| Flash point | 170 °C (338 °F) | Open cup vs. closed cup not specified | HSDB |
| 170 °C (338 °F) | above this value, technical grade | ICSC |
1,3,5-tris(oxiranylmethyl)-1,3… autoignition temperature
| Property | Value | Conditions | Source |
|---|---|---|---|
| Autoignition temperature | 200 °C (392 °F) | above this value, technical grade | ICSC |
Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.
09 · Fire and explosion
1,3,5-tris(oxiranylmethyl)… fire and explosion behaviour
These are descriptions rather than measured values, so they are kept out of the table above and quoted here with the source that reported them.
1,3,5-tris(oxiranylmethyl)-1,3… fire potential
A combustible liquid.
Source: Hazardous Substances Data Bank (HSDB)
10 · Handling and storage
1,3,5-tris(oxiranylmethyl)-1,3… storage and handling
1,3,5-tris(oxiranylmethyl)-1,3… safe storage
Well closed.
Source: ILO-WHO International Chemical Safety Cards (ICSCs)
1,3,5-tris(oxiranylmethyl)-1,3… storage conditions
Keep container tightly closed in a dry and well-ventilated place. Storage class (TRGS 510): Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects.
Source: Hazardous Substances Data Bank (HSDB)
1,3,5-tris(oxiranylmethyl)-1,3… incompatible materials
Incompatible materials: Strong oxidizing agents.
Source: Hazardous Substances Data Bank (HSDB)
1,3,5-tris(oxiranylmethyl)-1,3… reactivity
Epoxides are highly reactive. They polymerize in the presence of catalysts or when heated. These polymerization reactions can be violent. Compounds in this group react with acids, bases, and oxidizing and reducing agents. They react, possibly violently with water in the presence of acid and other catalysts.
Source: CAMEO Chemicals
Planning storage for a mix of chemicals? Check 1,3,5-tris(oxiranylmethyl… in the storage compatibility matrix →
11 · Questions
1,3,5-tris(oxiranylmethyl)-1,3… — frequently asked questions
What is the CAS number of 1,3,5-tris(oxiranylmethyl)-1,3…?
The CAS number of 1,3,5-tris(oxiranylmethyl)-1,3… is 2451-62-9. Its EC number is 219-514-3.
What does a 1,3,5-tris(oxiranylmethyl)-1,3… label have to show?
Under CLP Annex VI the label for 1,3,5-tris(oxiranylmethyl)-1,3… carries the pictograms Skull and crossbones, Health hazard and Corrosion and the signal word is Danger.
Is 1,3,5-tris(oxiranylmethyl)-1,3… flammable?
CLP Annex VI assigns 1,3,5-tris(oxiranylmethyl)-1,3… no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it. The flash point reported for it is 170 °C (338 °F), Open cup vs. closed cup not specified (HSDB).
Is 1,3,5-tris(oxiranylmethyl)-1,3… a carcinogen?
CLP Annex VI records no harmonised carcinogenicity classification for 1,3,5-tris(oxiranylmethyl)-1,3…. Annex VI is a list of agreed classifications, not a list of substances found safe, so this is an absence of a classification rather than a clean bill of health.
What is the boiling point of 1,3,5-tris(oxiranylmethyl)-1,3…?
The boiling point reported for 1,3,5-tris(oxiranylmethyl)-1,3… is 240 °C (464 °F), above this value (HSDB).
What is the melting point of 1,3,5-tris(oxiranylmethyl)-1,3…?
The melting point reported for 1,3,5-tris(oxiranylmethyl)-1,3… is 95 °C (203 °F) (HSDB).
How should 1,3,5-tris(oxiranylmethyl)-1,3… be stored?
Keep container tightly closed in a dry and well-ventilated place. Storage class (TRGS 510): Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects. (Hazardous Substances Data Bank (HSDB))
Nearby
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