Substance profile
1,7,7-trimethylbicyclo(2,2,1)hept-2-yl thiocyanatoacetate
1,7,7-trimethylbicyclo(2,2,1)hept-2-yl thiocyanatoacetate is a clear, amber liquid with a terpene-like odor.
01 · Identification
What 1,7,7-trimethylbicyclo(2,2,1)h… is
1,7,7-trimethylbicyclo(2,2,1)hept-2-yl thiocyanatoacetate is a clear, amber liquid with a terpene-like odor.
Under the GHS it carries the signal word Warning.
02 · Identifiers
1,7,7-trimethylbicyclo(2,2,1)h… identifiers and molecular data
1,7,7-trimethylbicyclo(2,2,1)h… CAS number and EC number
Other names for 1,7,7-trimethylbicyclo(2,2,1)h…
- isobornyl thiocyanoacetate
03 · GHS classification
1,7,7-trimethylbicyclo(2,2,1)h… hazard classification
Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.
1,7,7-trimethylbicyclo(2,2,1)h… pictograms and signal word
1,7,7-trimethylbicyclo(2,2,1)h… hazard class and category
| Hazard class | Category | From code | Pictogram |
|---|---|---|---|
| Acute toxicity - oral GHS chapter 3.1 | Category 4 | H302 | GHS07 |
| Hazardous to the aquatic environment - acute GHS chapter 4.1 | Category 1 | H400 | GHS09 |
| Hazardous to the aquatic environment - chronic GHS chapter 4.1 | Category 1 | H410 | GHS09 |
1,7,7-trimethylbicyclo(2,2,1)h… hazard statements (H-codes)
| Code | Hazard statement |
|---|---|
| H302 | Harmful if swallowed. |
| H400 | Very toxic to aquatic life. |
| H410 | Very toxic to aquatic life with long lasting effects. |
This page lists only the codes assigned to 1,7,7-trimethylbicyclo(2,2…. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.
Safety Data Sheet
Getting an SDS for 1,7,7-trimethylbicyclo(2,2…
A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of 1,7,7-trimethylbicyclo… issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.
04 · Precautionary statements
1,7,7-trimethylbicyclo(2,2,1)h… precautionary statements
CLP Annex VI assigns 7 precautionary statements to 1,7,7-trimethylbicyclo(2,2…. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.
Prevention
What to do before and during handling so the hazard never happens.
Response
What to do once exposure, spillage or fire has already happened.
Disposal
What has to happen to the contents and the empty container.
Reading the notation. … is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.
05 · Names in the regulation
1,7,7-trimethylbicyclo(2,2,1)h… name in 23 EU languages
CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.
| Language | Name in CLP Annex VI Part 3 |
|---|---|
| Bulgarian български | 1,7,7-триметилбицикло[2.2.1]хепт-2-илов тиоцианатоацетат изоборнилов тиоцианоацетат |
| Spanish español | Tiocianatoacetato de 1,7,7-trimetilbiciclo(2,2,1)hept-2-ilo tiocianoacetato de isobornilo |
| Czech čeština | (1,7,7-trimethylbicyklo[2.2.1]heptan-2-yl)-2-thiokyanatoacetát isobornyl-thiokyanatoacetát |
| Danish dansk | 1,7,7-trimethylbicyclo(2,2,1)hept-2-ylthiocyanatoacetat isobornyl thiocyanoacetat |
| German Deutsch | 1,7,7-Trimethylbicyclo(2,2,1)hept-2-yl- thiocyanatoacetat Isobornylthiocyanoacetat |
| Estonian eesti | 1,7,7-trimetüülbitsüklo[2,2,1]hept-2-üültiotsüanatoatsetaat isobornüültiotsüanoatsetaat |
| Greek ελληνικά | θειοκυανοξικό 1,7,7-τριμεθυλοδικυκλο[2.2.1]επτ-2-ύλιο θειοκυανοξικό ισοβορνύλιο |
| English English | 1,7,7-trimethylbicyclo(2,2,1)hept-2-yl thiocyanatoacetate isobornyl thiocyanoacetate |
| French français | thiocyanatoacétate de 1,7,7-triméthylbicyclo(2,2,1)hept-2-yle thiocyanoacétate d'isobornyle |
| Croatian hrvatski | 1,7,7-trimetilbiciklo(2,2,1)hept-2-il tiocijanatoacetat izobornil tiocijanoacetat |
| Italian italiano | tiocianatoacetato di 1,7,7-trimetilbiciclo(2,2,1)ept-2-ile |
| Latvian latviešu | 1,7,7-trimetilbiciklo(2,2,1)hept-2-iltiocianatoacetāts izoborniltiociānacetāts |
| Lithuanian lietuvių | 1,7,7-trimetilbiciklo[2.2.1]hept-2-iltiocianatoacetatas izoborniltiocianoacetatas |
| Hungarian magyar | 1,7,7-trimetilbiciklo[2.2.1]hept-2-il-tiocianoacetát izobornil-tiocianoacetát |
| Maltese Malti | tioċjanatoaċetat ta’ 1,7,7-trimetilbiċiklo(2,2,1)ett-2-il tijoċjanoaċetat tal-isobornil |
| Dutch Nederlands | 1,7,7-trimethylbicyclo(2.2.1)hept-2-ylthiocyanatoacetaat isobornylthiocyaanacetaat |
| Polish polski | tiocyjanianooctan 1,7,7-trimetylobicyklo[2.2.1]heptan-2-ylu tiocyjanianooctan 2-bornylu |
| Portuguese português | tiocianatoacetato de 1,7,7-trimetilbiciclo[2.2.1]hept-2-ilo tiocianoacetato de isobornilo |
| Romanian română | tiocianatoacetat de 1,7,7-trimetilbiciclo[2.2.1]hept-2-il tiocianoacetat de izobornil |
| Slovak slovenčina | O -(1,7,7-trimetylbicyklo[2.2.1]heptán-2-yl)-tiokyanátoacetát izobornyl-tiokyanoacetát |
| Slovenian slovenščina | 1,7,7-trimetilbiciklo[2.2.1]hept-2-il tiocianatoacetat izobornil tiocianoacetat |
| Finnish suomi | 1,7,7-trimetyylibisyklo[2,2,1]hept-2-yylitiosyanaattoasetaatti isobornyylitiosyaaniasetaatti |
| Swedish svenska | 1,7,7-trimetylbicyklo(2,2,1)hept-2-yltiocyanatoacetat isobornyltiocyanoacetat |
All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.
06 · Label elements
1,7,7-trimethylbicyclo(2,2,1)h… GHS label elements
Everything CLP Annex VI fixes for 1,7,7-trimethylbicyclo(2,2…, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.
Warning
1,7,7-trimethylbicyclo(2,2,1)h…
- Harmful if swallowed.
- Very toxic to aquatic life.
- Very toxic to aquatic life with long lasting effects.
- Do not eat, drink or smoke when using this product.
- Avoid release to the environment.
- IF SWALLOWED:
- Call a POISON CENTER/doctor/… if you feel unwell.
- Rinse mouth.
- Collect spillage.
- Dispose of contents/container to …
Supplier name, address and telephone number· Product identifier·Nominal quantity
Need this as an actual label? Open 1,7,7-trimethylbicyclo(2,2… in the GHS label constructor →
07 · Health hazards
1,7,7-trimethylbicyclo(2,2,1)h… health hazards and exposure limits
1,7,7-trimethylbicyclo(2,2,1)h… hazard summary
Highly irritating; [Hawley] A strong skin, eye, and mucous membrane irritant; Poisoning is due to release of cyanide ion; Repeated dermal doses of 1000 mg/kg/day was fatal to rabbits after 4-5 doses; A fatal human case after ingestion reported--shock, unconsciousness, and death within 8 hours; Aliphatic thiocyanate poisoning may include injury to liver and kidneys; [HSDB]
Source: Haz-Map, Information on Hazardous Chemicals and Occupational Diseases
08 · Physical and chemical properties
1,7,7-trimethylbicyclo(2,2,1)h… properties
Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.
1,7,7-trimethylbicyclo(2,2,1)h… boiling point
| Property | Value | Conditions | Source |
|---|---|---|---|
| Boiling point | 95 °C (203 °F) | at 0.06 mmHg (reduced pressure) | HSDB |
1,7,7-trimethylbicyclo(2,2,1)h… density
| Property | Value | Conditions | Source |
|---|---|---|---|
| Density | 1.1465 g/cm³ | at 25 °C | HSDB |
1,7,7-trimethylbicyclo(2,2,1)h… solubility
| Property | Value | Conditions | Source |
|---|---|---|---|
| Solubility | Very soluble in alcohol, benzene, chloroform, ether; practically insoluble in water. | HSDB |
1,7,7-trimethylbicyclo(2,2,1)h… vapor pressure
| Property | Value | Conditions | Source |
|---|---|---|---|
| Vapor pressure | 0.06 mmHg | at 95 °C | HSDB |
| 0.000025 mmHg | Haz-Map |
1,7,7-trimethylbicyclo(2,2,1)h… flash point
| Property | Value | Conditions | Source |
|---|---|---|---|
| Flash point | 82 °C (179.6 °F) | HSDB |
1,7,7-trimethylbicyclo(2,2,1)h… corrosivity
| Property | Value | Conditions | Source |
|---|---|---|---|
| Corrosivity | SOMEWHAT CORROSIVE TO GALVANIZED IRON | HSDB |
Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.
09 · Fire and explosion
1,7,7-trimethylbicyclo(2,2… fire and explosion behaviour
These are descriptions rather than measured values, so they are kept out of the table above and quoted here with the source that reported them.
1,7,7-trimethylbicyclo(2,2,1)h… fire potential
Flammable when exposed to heat or flame; can react vigorously with oxidizing materials.
Source: Hazardous Substances Data Bank (HSDB)
10 · Handling and storage
1,7,7-trimethylbicyclo(2,2,1)h… storage and handling
1,7,7-trimethylbicyclo(2,2,1)h… incompatible materials
... Can react vigorously with oxidizing materials.
Source: Hazardous Substances Data Bank (HSDB)
Planning storage for a mix of chemicals? Check 1,7,7-trimethylbicyclo(2… in the storage compatibility matrix →
11 · Questions
1,7,7-trimethylbicyclo(2,2,1)h… — frequently asked questions
What is the CAS number of 1,7,7-trimethylbicyclo(2,2,1)h…?
The CAS number of 1,7,7-trimethylbicyclo(2,2,1)h… is 115-31-1. Its EC number is 204-081-5.
What does a 1,7,7-trimethylbicyclo(2,2,1)h… label have to show?
Under CLP Annex VI the label for 1,7,7-trimethylbicyclo(2,2,1)h… carries the pictograms Exclamation mark and Environment and the signal word is Warning.
Is 1,7,7-trimethylbicyclo(2,2,1)h… flammable?
CLP Annex VI assigns 1,7,7-trimethylbicyclo(2,2,1)h… no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it. The flash point reported for it is 82 °C (179.6 °F) (HSDB).
Is 1,7,7-trimethylbicyclo(2,2,1)h… a carcinogen?
CLP Annex VI records no harmonised carcinogenicity classification for 1,7,7-trimethylbicyclo(2,2,1)h…. Annex VI is a list of agreed classifications, not a list of substances found safe, so this is an absence of a classification rather than a clean bill of health.
What is the boiling point of 1,7,7-trimethylbicyclo(2,2,1)h…?
The boiling point reported for 1,7,7-trimethylbicyclo(2,2,1)h… is 95 °C (203 °F), at 0.06 mmHg (reduced pressure) (HSDB).
Nearby
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