Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

1-Methylimidazole

1-Methylimidazole: liquid.

CAS 616-47-7 Danger

01 · Identification

What 1-Methylimidazole is

1-Methylimidazole: liquid. It boils at 196 °C, melts at -6 °C.

Under the GHS it carries the signal word Danger.

02 · Identifiers

1-Methylimidazole identifiers and molecular data

1-Methylimidazole CAS number and EC number

CAS number616-47-7
EC number210-484-7
Index number (CLP Annex VI)613-035-00-7

03 · GHS classification

1-Methylimidazole hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

1-Methylimidazole pictograms and signal word

Signal wordDanger

1-Methylimidazole hazard class and category

GHS hazard classes 1-Methylimidazole falls into
Hazard class Category From code Pictogram
Acute toxicity - oral GHS chapter 3.1 Category 4 H302 GHS07
Acute toxicity - dermal GHS chapter 3.1 Category 4 H312 GHS07
Skin corrosion/irritation GHS chapter 3.2 Category 1A or 1B or 1C H314 GHS05

Where two values are shown with “or”, the hazard statement is shared by more than one category or by more than one class, and the code alone does not say which. H272, for example, belongs to oxidising liquids and to oxidising solids — the physical state decides. The binding answer for a specific entry is in the CLP Annex VI table itself.

1-Methylimidazole hazard statements (H-codes)

Hazard statements assigned to 1-Methylimidazole
CodeHazard statement
H312 Harmful in contact with skin.
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.

This page lists only the codes assigned to 1-Methylimidazole. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for 1-Methylimidazole

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of 1-Methylimidazole issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

1-Methylimidazole precautionary statements

CLP Annex VI assigns 10 precautionary statements to 1-Methylimidazole. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

1-Methylimidazole name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български 1-метилимидазол
Spanish español 1-Metilimidazol
Czech čeština 1-methylimidazol
Danish dansk 1-methylimidazol
German Deutsch 1-Methylimidazol
Estonian eesti 1-metüülimidasool
Greek ελληνικά 1-μεθυλιμιδαζόλιο
English English 1-methylimidazole
French français 1-méthylimidazole
Croatian hrvatski 1-metilimidazol
Italian italiano 1-metilimidazolo
Latvian latviešu 1-metilimidazols
Lithuanian lietuvių 1-metilimidazolas
Hungarian magyar 1-metilimidazol
Maltese Malti 1-metilimidażol
Dutch Nederlands 1-methylimidazool
Polish polski 1-metylimidazol
Portuguese português 1-metilimidazole
Romanian română 1-metilimidazol
Slovak slovenčina 1-metylimidazol
Slovenian slovenščina 1-metilimidazol
Finnish suomi 1-metyyli-imidatsoli
Swedish svenska 1-metylimidazol

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

1-Methylimidazole GHS label elements

Everything CLP Annex VI fixes for 1-Methylimidazole, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS05 Corrosion pictogramGHS07 Exclamation mark pictogram

Danger

1-Methylimidazole

  • Harmful in contact with skin.
  • Harmful if swallowed.
  • Causes severe skin burns and eye damage.
  • Do not breathe dust/fume/gas/mist/vapours/spray.
  • Do not eat, drink or smoke when using this product.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • IF SWALLOWED:
  • IF ON SKIN:
  • Immediately call a POISON CENTER/doctor/
  • Call a POISON CENTER/doctor/ if you feel unwell.
  • Rinse mouth.
  • Do NOT induce vomiting.
  • Wash with plenty of water/

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open 1-Methylimidazole in the GHS label constructor →

07 · Physical and chemical properties

1-Methylimidazole properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

1-Methylimidazole boiling point

Property Value Conditions Source
Boiling point 196 °C (384.8 °F) at 760 mmHg DOE PAC
195.5 °C (383.9 °F) DrugBank

1-Methylimidazole melting point

Property Value Conditions Source
Melting point -6 °C (21.2 °F) DOE PAC

1-Methylimidazole density

Property Value Conditions Source
Density 1.0325 g/cm³ at 25 °C DOE PAC

1-Methylimidazole solubility

Property Value Conditions Source
Solubility 1000000 mg/L (at 20 °C) at 20 °C DrugBank

1-Methylimidazole vapor pressure

Property Value Conditions Source
Vapor pressure 0.47 mmHg Haz-Map

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

08 · Questions

1-Methylimidazole — frequently asked questions

What is the CAS number of 1-Methylimidazole?

The CAS number of 1-Methylimidazole is 616-47-7. Its EC number is 210-484-7.

What does a 1-Methylimidazole label have to show?

Under CLP Annex VI the label for 1-Methylimidazole carries the pictograms Corrosion and Exclamation mark and the signal word is Danger.

Is 1-Methylimidazole flammable?

CLP Annex VI assigns 1-Methylimidazole no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it.

Is 1-Methylimidazole a carcinogen?

CLP Annex VI records no harmonised carcinogenicity classification for 1-Methylimidazole. Annex VI is a list of agreed classifications, not a list of substances found safe, so this is an absence of a classification rather than a clean bill of health.

What is the boiling point of 1-Methylimidazole?

The boiling point reported for 1-Methylimidazole is 196 °C (384.8 °F), at 760 mmHg (DOE PAC).

What is the melting point of 1-Methylimidazole?

The melting point reported for 1-Methylimidazole is -6 °C (21.2 °F) (DOE PAC).

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