Substance profile
(+)-(1S,2S,3S,5R)-2,6,6-trimethylbicyclo[3.1.1]heptane-3-spiro-1'-(cyclohex-2'-en-4'-one)
(+)-(1S,2S,3S,5R)-2,6,6-trimethylbicyclo[3.1.1]heptane-3-spiro-1'-(cyclohex-2'-en-4'-one) is a substance with a harmonised classification under EU CLP.
01 · Identification
What (+)-(1S,2S,3S,5R)-2,6,6-trimet… is
(+)-(1S,2S,3S,5R)-2,6,6-trimethylbicyclo[3.1.1]heptane-3-spiro-1'-(cyclohex-2'-en-4'-one) is a substance with a harmonised classification under EU CLP.
Under the GHS it carries the signal word Danger.
02 · Identifiers
(+)-(1S,2S,3S,5R)-2,6,6-trimet… identifiers and molecular data
(+)-(1S,2S,3S,5R)-2,6,6-trimet… CAS number and EC number
03 · GHS classification
(+)-(1S,2S,3S,5R)-2,6,6-trimet… hazard classification
Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.
(+)-(1S,2S,3S,5R)-2,6,6-trimet… pictograms and signal word
(+)-(1S,2S,3S,5R)-2,6,6-trimet… hazard class and category
| Hazard class | Category | From code | Pictogram |
|---|---|---|---|
| Skin corrosion/irritation GHS chapter 3.2 | Category 1A or 1B or 1C | H314 | GHS05 |
| Skin sensitisation GHS chapter 3.4 | Category 1 or 1A or 1B | H317 | GHS07 |
| Hazardous to the aquatic environment - acute GHS chapter 4.1 | Category 1 | H400 | GHS09 |
| Hazardous to the aquatic environment - chronic GHS chapter 4.1 | Category 1 | H410 | GHS09 |
Where two values are shown with “or”, the hazard statement is shared by more than one category or by more than one class, and the code alone does not say which. H272, for example, belongs to oxidising liquids and to oxidising solids — the physical state decides. The binding answer for a specific entry is in the CLP Annex VI table itself.
(+)-(1S,2S,3S,5R)-2,6,6-trimet… hazard statements (H-codes)
| Code | Hazard statement |
|---|---|
| H314 | Causes severe skin burns and eye damage. |
| H317 | May cause an allergic skin reaction. |
| H400 | Very toxic to aquatic life. |
| H410 | Very toxic to aquatic life with long lasting effects. |
This page lists only the codes assigned to (+)-(1S,2S,3S,5R)-2,6,6-tr…. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.
Safety Data Sheet
Getting an SDS for (+)-(1S,2S,3S,5R)-2,6,6-tr…
A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of (+)-(1S,2S,3S,5R)-2,6… issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.
04 · Precautionary statements
(+)-(1S,2S,3S,5R)-2,6,6-trimet… precautionary statements
CLP Annex VI assigns 12 precautionary statements to (+)-(1S,2S,3S,5R)-2,6,6-tr…. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.
Prevention
What to do before and during handling so the hazard never happens.
Response
What to do once exposure, spillage or fire has already happened.
Disposal
What has to happen to the contents and the empty container.
Reading the notation. … is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.
05 · Names in the regulation
(+)-(1S,2S,3S,5R)-2,6,6-trimet… name in 23 EU languages
CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.
| Language | Name in CLP Annex VI Part 3 |
|---|---|
| Bulgarian български | (+)-(1 S ,2 S ,3 S ,5 R )-2,6,6-триметилбицикло[3.1.1]хептан-3-спиро-1′-(циклохекс-2′-ен-4′-он) |
| Spanish español | (+)-(1 S ,2 S ,3 S ,5 R )-2,6,6-Trimetilbiciclo[3.1.1]heptano-3-espiro-1'-(ciclohex-2'-en-4'-ona) |
| Czech čeština | (+)-(1 S ,2 S ,3 S ,5 R )-2,6,6-trimethylbicyklo[3.1.1]heptan-3-spiro-1'-(cyklohex-2'-en-4'-on) |
| Danish dansk | (+)-(1 S ,2 S ,3 S ,5 R )-2,6,6-trimethylbicyclo[3.1.1]heptan-3-spiro-1'-(cyclohex-2'-en-4'-on) |
| German Deutsch | (+)-(1 S ,2 S ,3 S ,5 R )-2,6,6-Trimethylbicyclo[3.1.1]heptan-3-spiro-1'-(cyclohex-2'-en-4'-on) |
| Estonian eesti | (+)-(1 S ,2 S ,3 S ,5 R )-2,6,6-trimetüülbitsüklo[3.1.1]heptaan-3-spiro-1'-(tsükloheks-2'-een-4'-oon) |
| Greek ελληνικά | (+)-(1 S ,2 S ,3 S ,5 R )-2,6,6-τριμεθυλοδικυκλο[3.1.1]επτανο-3-σπειρο-1′-(κυκλοεξ-2′-εν-4′-όνη) |
| English English | (+)-(1 S , 2 S , 3 S , 5 R )-2,6,6-trimethylbicyclo[3.1.1]heptane-3-spiro-1'-(cyclohex-2'-en-4'-one) |
| French français | (+)-(1 S , 2 S , 3 S , 5 R )-2,6,6-triméthylbicyclo[3.1.1]heptane-3-spiro-1'-(cyclohex-2'-en-4'-one) |
| Croatian hrvatski | (+)-(1 S ,2 S ,3 S ,5 R )-2,6,6-trimetilbiciklo[3.1.1]heptan-3-spiro-1'-(cikloheks-2'-en-4'-on) |
| Italian italiano | (+)-(1 S ,2 S ,3 S ,5 R )-2,6,6-trimetilbiciclo[3.1.1]eptan-3-spiro-1'-(cicloesene-2'-4'-one) |
| Latvian latviešu | (+)-(1 S ,2 S ,3 S ,5 R )-2,6,6-trimetilbiciklo[3.1.1]heptān-3-spiro-1′-(cikloheks-2′-ēn-4′-ons) |
| Lithuanian lietuvių | (+)-(1 S ,2 S ,3 S ,5 R )-2,6,6-trimetilbiciklo[3.1.1]heptan-3-spiro-1'-(cikloheks-2'-en-4'-onas) |
| Hungarian magyar | (+)-(1 S , 2 S , 3 S , 5 R )-2,6,6-trimetilbiciklo[3.1.1]heptán-3-spiro-1'-(ciklohex-2'-én-4'-on) |
| Maltese Malti | (+)-(1 S , 2 S , 3 S , 5 R )-2,6,6-trimetilbiċiklo[3.1.1]ettan-3-spiro-1'-(ċikloeż-2'-en-4'-on) |
| Dutch Nederlands | (+)-(1 S ,2 S ,3 S ,5 R )-2,6,6-trimethylbicyclo[3.1.1]heptaan-3-spiro-1'-(cyclohex-2'-een-4'-on) |
| Polish polski | (+)-(1 S ,2 S ,3 S , 5 R)-2,6,6-trimetylobicyklo[3.1.1]heptano-3-spiro-1'-(cykloheks-2'-en-4'-on) |
| Portuguese português | (+)-(1 S ,2 S ,3 S ,5 R )-2,6,6-trimetilbiciclo[3.1.1]heptano-3-espiro-1'-(ciclo-hex-2'-en-4'-ona) |
| Romanian română | (+)-(1 S , 2 S , 3 S , 5 R )-2,6,6-trimetil-biciclo[3.1.1]heptan-3-spiro-1'-(ciclohex-2'-en-4'-onă) |
| Slovak slovenčina | (+)-(1 S ,2 S ,3 S ,5 R )-2,6,6-trimetylbicyklo[3.1.1]heptán-3-spiro-1'-(cyklohex-2'-én-4'-ón) |
| Slovenian slovenščina | (+)-(1 S ,2 S ,3 S ,5 R )-2,6,6-trimetilbiciklo[3.1.1]heptan-3-spiro-1'-(cikloheks-2'-en-4'-on) |
| Finnish suomi | (+)-(1S, 2S, 3S, 5R)-2,6,6-trimetyylibisyklo[3.1.1]heptaani-3-spiro-1'-(sykloheks-2'-en-4'-oni) |
| Swedish svenska | (+)-(1 S , 2 S , 3 S , 5 R )-2,6,6-trimetylbicyklo[3.1.1]heptan-3-spiro-1'-(cyklohex-2'-en-4'-on) |
All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.
06 · Label elements
(+)-(1S,2S,3S,5R)-2,6,6-trimet… GHS label elements
Everything CLP Annex VI fixes for (+)-(1S,2S,3S,5R)-2,6,6-tr…, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.
Danger
(+)-(1S,2S,3S,5R)-2,6,6-trimet…
- Causes severe skin burns and eye damage.
- May cause an allergic skin reaction.
- Very toxic to aquatic life.
- Very toxic to aquatic life with long lasting effects.
- Do not breathe dust/fume/gas/mist/vapours/spray.
- Avoid breathing dust/fume/gas/mist/vapours/spray.
- Contaminated work clothing should not be allowed out of the workplace.
- Avoid release to the environment.
- Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/…
- IF SWALLOWED:
- Immediately call a POISON CENTER/doctor/…
- Get medical advice/attention.
- Do NOT induce vomiting.
- If skin irritation or rash occurs:
- Collect spillage.
- Dispose of contents/container to …
Supplier name, address and telephone number· Product identifier·Nominal quantity
Need this as an actual label? Open (+)-(1S,2S,3S,5R)-2,6,6-tr… in the GHS label constructor →
07 · Questions
(+)-(1S,2S,3S,5R)-2,6,6-trimet… — frequently asked questions
What is the CAS number of (+)-(1S,2S,3S,5R)-2,6,6-trimet…?
The CAS number of (+)-(1S,2S,3S,5R)-2,6,6-trimet… is 133636-82-5. Its EC number is 430-460-1.
What does a (+)-(1S,2S,3S,5R)-2,6,6-trimet… label have to show?
Under CLP Annex VI the label for (+)-(1S,2S,3S,5R)-2,6,6-trimet… carries the pictograms Corrosion, Exclamation mark and Environment and the signal word is Danger.
Is (+)-(1S,2S,3S,5R)-2,6,6-trimet… flammable?
CLP Annex VI assigns (+)-(1S,2S,3S,5R)-2,6,6-trimet… no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it.
Is (+)-(1S,2S,3S,5R)-2,6,6-trimet… a carcinogen?
CLP Annex VI records no harmonised carcinogenicity classification for (+)-(1S,2S,3S,5R)-2,6,6-trimet…. Annex VI is a list of agreed classifications, not a list of substances found safe, so this is an absence of a classification rather than a clean bill of health.
Nearby
Substances next to (+)-(1S,2S,3S,5R)-2,6,6-tr…
Keep going: substances starting with 0–9, or search the whole database by name, CAS number, pictogram or signal word.