Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

2-(2-hexyloxyethoxy)ethanol

2-(2-hexyloxyethoxy)ethanol is a water-white liquid.

CAS 112-59-4 Danger

01 · Identification

What 2-(2-hexyloxyethoxy)ethanol is

2-(2-hexyloxyethoxy)ethanol is a water-white liquid. It boils at 258 °C, melts at -28 °C.

Under the GHS it carries the signal word Danger.

02 · Identifiers

2-(2-hexyloxyethoxy)ethanol identifiers and molecular data

2-(2-hexyloxyethoxy)ethanol CAS number and EC number

CAS number112-59-4
EC number203-988-3
Index number (CLP Annex VI)603-175-00-7

Other names for 2-(2-hexyloxyethoxy)ethanol

  • DEGHE
  • diethylene glycol monohexyl ether
  • 3,6-dioxa-1-dodecanol
  • hexyl carbitol
  • 3,6-dioxadodecan-1-ol

03 · GHS classification

2-(2-hexyloxyethoxy)ethanol hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

2-(2-hexyloxyethoxy)ethanol pictograms and signal word

Signal wordDanger

2-(2-hexyloxyethoxy)ethanol hazard class and category

GHS hazard classes 2-(2-hexyloxyethoxy)ethano… falls into
Hazard class Category From code Pictogram
Acute toxicity - dermal GHS chapter 3.1 Category 4 H312 GHS07
Serious eye damage/eye irritation GHS chapter 3.3 Category 1 H318 GHS05

2-(2-hexyloxyethoxy)ethanol hazard statements (H-codes)

Hazard statements assigned to 2-(2-hexyloxyethoxy)ethano…
CodeHazard statement
H312 Harmful in contact with skin.
H318 Causes serious eye damage.

This page lists only the codes assigned to 2-(2-hexyloxyethoxy)ethano…. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for 2-(2-hexyloxyethoxy)ethano…

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of 2-(2-hexyloxyethoxy)et… issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

2-(2-hexyloxyethoxy)ethanol precautionary statements

CLP Annex VI assigns 7 precautionary statements to 2-(2-hexyloxyethoxy)ethano…. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Prevention

What to do before and during handling so the hazard never happens.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

2-(2-hexyloxyethoxy)ethanol name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български 2-(2-хексилоксиетокси)етанол DEGHEмонохексилов етер на диетиленгликола3,6-диоксa-1-додеканолхексилкарбитол3,6-диоксадодекан-1-ол
Spanish español 2-(2-Hexiloxietoxi)etanol DEGHEéter monohexílico de dietilenglicol3,6-dioxa-1-dodecanolhexil-carbitol3,6-dioxadodecan-1-ol
Czech čeština 2-[2-(hexyloxy)ethoxy]ethan-1-ol DEGHEdiethylenglykolmonohexylether3,6-dioxa-1-dodekanolhexylkarbitol
Danish dansk 2-(2-hexyloxyethoxy)ethanol DEGHEdiethylenglycolmonohexylether3,6-dioxa-1-dodecanolhexylcarbitol3,6-dioxadodecan-1-ol
German Deutsch 2-(2-Hexyloxyethoxy)ethanol DEGHEDiethylenglycolmonohexylether3,6-Dioxa-1-dodecanolHexylcarbitol3,6-Dioxadodecan-1-ol
Estonian eesti 2-(2-heksüüloksüetoksü)etanool DEGHEdietüleenglükooli monoheksüüleeter3,6-dioksa-1-dodekanoolheksüülkarbitool3,6-dioksadodekaan-1-ool
Greek ελληνικά 2-(2-εξυλοξυαιθοξυ)αιθανόλη DEGHEμονοεξυλαιθέρας διαιθυλενογλυκόλης3,6-διοξα-1-δωδεκανόληεξυλοκαρβιτόλη3,6-διοξαδωδεκαν-1-όλη
English English 2-(2-hexyloxyethoxy)ethanol DEGHEdiethylene glycol monohexyl ether3,6-dioxa-1-dodecanolhexyl carbitol3,6-dioxadodecan-1-ol
French français 2-(2-hexyloxyéthoxy)éthanol DEGHEéther monohexylique du diéthylène glycol3,6-dioxa-1-dodécanolhexylcarbitol3,6-dioxadodécan-1-ol
Croatian hrvatski 2-(2-heksiloksietoksi)etanol DEGHEdietilen-glikol-monoheksil-eter3,6-dioksa-1-dodekanolheksil-karbitol3,6-dioksadodekan-1-ol
Italian italiano 2-(2-esilossietossi)etanolo DEGHEDietileneglicol monoesiletere3,6-diossa-1-decanoloesilcarbitolo
Latvian latviešu 2-(2-heksiloksietoksi)etanols DEGHEdietilēnglikola monoheksilēteris3,6-dioksa-1-dodekanolsheksilkarbitols3,6-dioksadodekān-1-ols
Lithuanian lietuvių 2-(2-heksiloksietoksi)etanolis DEGHEdietilenglikolio monoheksileteris3,6-dioksa-1-dodekanolisheksilkarbitolis3,6-dioksadodekan-1-olis
Hungarian magyar 2-(2-hexiloxietoxi)etanol DEGHEdietilén-glikol-monohexil-éter3,6-dioxa-1-dodekanolhexil-karbitol3,6-dioxadodekán-1-ol
Maltese Malti 2-(2-essilossietossi)etanol DEGHEeter tal-monoeżil tal-glikol dietileniku3,6-diossa-1-dodekanolkarbitol tal-eżil3,6-diossadodekan-1-ol
Dutch Nederlands 2-(2-hexyloxyethoxy)ethanol DEGHEdiëthyleenglycolmonohexylether3,6-dioxa-1-dodecanolhexylcarbitol3,6-dioxadodecaan-1-ol
Polish polski 2-(2-heksyloksyetoksy)etanol DEGHEeter monoheksylowy glikolu dietylenowego3,6-dioksa-1-dodekanolkarbitol heksylowy3,6-dioksadodekan-1-ol
Portuguese português 2-(2-hexiloxietoxi)etanol DEGHEéter mono-hexílico de dietilenoglicol3,6-dioxa-1-dodecanolhexilcarbitol3,6-dioxadodecan-1-ol
Romanian română 2-(2-hexiloxietoxi)etanol DEGHEeter monohexilic al dietilen-glicolului3,6-dioxa-1-dodecanolhexilcarbitol3,6-dioxadodecan-1-ol
Slovak slovenčina 2-[2-(hexyloxy)etoxy]etanol DEGHEdietylénglykol-monohexyléter3,6-dioxa-1-dodekanolhexyl-karbitol3,6-dioxadodekán-1-ol
Slovenian slovenščina 2-(2-heksiloksietoksi)etanol DEGHEdietilen glikol monoheksil eter3,6-dioksa-1-dodekanolheksil karbitol3,6-dioksadodekan-1-ol
Finnish suomi 2-(2-heksyylioksietoksi)etanoli DEGHEdietyleeniglykolimonoheksyylieetteri3,6-dioksa-1-dodekanoliheksyylikarbitoli3,6-dioksadodekan-1-oli
Swedish svenska 2-(2-hexyloxietoxi)etanol DEGHEdietylenglykolmonohexyleter3,6-dioxa-1-dodekanolhexylkarbitol3,6-dioxadodekan-1-ol

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

2-(2-hexyloxyethoxy)ethanol GHS label elements

Everything CLP Annex VI fixes for 2-(2-hexyloxyethoxy)ethano…, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS05 Corrosion pictogramGHS07 Exclamation mark pictogram

Danger

2-(2-hexyloxyethoxy)ethanol

  • Harmful in contact with skin.
  • Causes serious eye damage.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • IF ON SKIN:
  • IF IN EYES:
  • Immediately call a POISON CENTER/doctor/
  • Call a POISON CENTER/doctor/ if you feel unwell.
  • Remove contact lenses, if present and easy to do. Continue rinsing.
  • Wash with plenty of water/

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open 2-(2-hexyloxyethoxy)ethano… in the GHS label constructor →

07 · Physical and chemical properties

2-(2-hexyloxyethoxy)ethanol properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

2-(2-hexyloxyethoxy)ethanol boiling point

Property Value Conditions Source
Boiling point 258 °C (496.4 °F) at 760 mmHg HSDB
259.11 °C (498.4 °F) at 760 mmHg CAMEO
259.1 °C (498.4 °F) ICSC

2-(2-hexyloxyethoxy)ethanol melting point

Property Value Conditions Source
Melting point -28 °C (-18.4 °F) HSDB
-33 °C (-27.4 °F) CAMEO
-33.3 °C (-27.9 °F) ICSC

2-(2-hexyloxyethoxy)ethanol density

Property Value Conditions Source
Density 0.935 g/cm³ ICSC
0.9346 g/cm³ at 20 °C CAMEO
0.9346 g/cm³ at 25 °C HSDB

2-(2-hexyloxyethoxy)ethanol solubility

Property Value Conditions Source
Solubility In water, 17,000 mg/L at 20 °C at 20 °C HSDB
Solubility in water, g/100ml at 20 °C: 1.7 at 20 °C ICSC

2-(2-hexyloxyethoxy)ethanol vapor pressure

Property Value Conditions Source
Vapor pressure 0.01 mmHg at 20 °C DOE PAC
0.01 mmHg below this value, at 25 °C HSDB
0.000503 mmHg Haz-Map

2-(2-hexyloxyethoxy)ethanol flash point

Property Value Conditions Source
Flash point 132.78 °C (271 °F) HSDB
140.56 °C (285 °F) CAMEO
140.6 °C (285.1 °F) ICSC

2-(2-hexyloxyethoxy)ethanol vapor density

Property Value Conditions Source
Vapor density 6.6 (air = 1) ICSC

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

08 · Fire and explosion

2-(2-hexyloxyethoxy)ethano… fire and explosion behaviour

These are descriptions rather than measured values, so they are kept out of the table above and quoted here with the source that reported them.

2-(2-hexyloxyethoxy)ethanol fire potential

Combustible

Source: Hazardous Substances Data Bank (HSDB)

09 · Handling and storage

2-(2-hexyloxyethoxy)ethanol storage and handling

2-(2-hexyloxyethoxy)ethanol safe storage

Separated from strong oxidants.

Source: ILO-WHO International Chemical Safety Cards (ICSCs)

2-(2-hexyloxyethoxy)ethanol incompatible materials

Glycol ethers, glycols, ketones, and alcohols undergo violent decomposition in contact with 68-72% perchloric acid

Source: Hazardous Substances Data Bank (HSDB)

2-(2-hexyloxyethoxy)ethanol reactivity

Ethers, such as DIETHYLENE GLYCOL N-HEXYL ETHER can act as bases. They form salts with strong acids and addition complexes with Lewis acids. The complex between diethyl ether and boron trifluoride is an example. Ethers may react violently with strong oxidizing agents. In other reactions, which typically involve the breaking of the carbon-oxygen bond, ethers are relatively inert.

Source: CAMEO Chemicals

Planning storage for a mix of chemicals? Check 2-(2-hexyloxyethoxy)ethan… in the storage compatibility matrix →

10 · Transport

2-(2-hexyloxyethoxy)ethanol UN number and transport classification

Transport classification is a separate system from the GHS classification above. It decides how a package is marked and how a load may be carried; it does not follow from the workplace label, and the workplace label does not follow from it. The entries below are linked by CAS number, never by name.

2-(2-hexyloxyethoxy)ethanol under UN 3055 — shipping name, class and packing group

Europe · ADR 2025, Table A

Proper shipping name (3.1.2) Class Classification code PG Labels (column 5)
2-(2-AMINOETHOXY) ETHANOL 8 C7 III
  • ADR label model 8 — Corrosive substance
8

Source: ADR 2025, Table A of Chapter 3.2 · ECE/TRANS/352 Vol. I (UNECE). Class 8 is “Corrosive substances” (ADR 2.1.1.1).

Proper shipping name (column 2) Class or division PG Labels (column 6)
2-(2-Aminoethoxy) ethanol 8 III
  • US DOT CORROSIVE label (§172.442)
8

Source: 49 CFR 172.101 Hazardous Materials Table · eCFR, revision 2026-08-03. Class 8 is “Corrosive material” (49 CFR 173.2).

Full UN 3055 entry — special provisions, packing instructions, quantity limits and the orange plate →

11 · Questions

2-(2-hexyloxyethoxy)ethanol — frequently asked questions

What is the CAS number of 2-(2-hexyloxyethoxy)ethanol?

The CAS number of 2-(2-hexyloxyethoxy)ethanol is 112-59-4. Its EC number is 203-988-3.

What does a 2-(2-hexyloxyethoxy)ethanol label have to show?

Under CLP Annex VI the label for 2-(2-hexyloxyethoxy)ethanol carries the pictograms Corrosion and Exclamation mark and the signal word is Danger.

Is 2-(2-hexyloxyethoxy)ethanol flammable?

CLP Annex VI assigns 2-(2-hexyloxyethoxy)ethanol no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it. The flash point reported for it is 132.78 °C (271 °F) (HSDB).

Is 2-(2-hexyloxyethoxy)ethanol a carcinogen?

CLP Annex VI records no harmonised carcinogenicity classification for 2-(2-hexyloxyethoxy)ethanol. Annex VI is a list of agreed classifications, not a list of substances found safe, so this is an absence of a classification rather than a clean bill of health.

What is the boiling point of 2-(2-hexyloxyethoxy)ethanol?

The boiling point reported for 2-(2-hexyloxyethoxy)ethanol is 258 °C (496.4 °F), at 760 mmHg (HSDB).

What is the melting point of 2-(2-hexyloxyethoxy)ethanol?

The melting point reported for 2-(2-hexyloxyethoxy)ethanol is -28 °C (-18.4 °F) (HSDB).

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