Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

2,3,6-TBA (ISO)

2,3,6-TBA (ISO) is a substance with a harmonised classification under EU CLP.

CAS 50-31-7 Warning

01 · Identification

What 2,3,6-TBA (ISO) is

2,3,6-TBA (ISO) is a substance with a harmonised classification under EU CLP. It melts at 125 °C, is soluble in water.

Under the GHS it carries the signal word Warning.

02 · Identifiers

2,3,6-TBA (ISO) identifiers and molecular data

2,3,6-TBA (ISO) CAS number and EC number

CAS number50-31-7
EC number200-026-4
Index number (CLP Annex VI)607-152-00-2

Other names for 2,3,6-TBA (ISO)

  • 2,3,6-trichlorobenzoic acid

03 · GHS classification

2,3,6-TBA (ISO) hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

2,3,6-TBA (ISO) pictograms and signal word

Signal wordWarning

2,3,6-TBA (ISO) hazard class and category

GHS hazard classes 2,3,6-TBA (ISO) falls into
Hazard class Category From code Pictogram
Acute toxicity - oral GHS chapter 3.1 Category 4 H302 GHS07
Hazardous to the aquatic environment - chronic GHS chapter 4.1 Category 2 H411 GHS09

2,3,6-TBA (ISO) hazard statements (H-codes)

Hazard statements assigned to 2,3,6-TBA (ISO)
CodeHazard statement
H302 Harmful if swallowed.
H411 Toxic to aquatic life with long lasting effects.

This page lists only the codes assigned to 2,3,6-TBA (ISO). The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for 2,3,6-TBA (ISO)

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of 2,3,6-TBA (ISO) issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

2,3,6-TBA (ISO) precautionary statements

CLP Annex VI assigns 7 precautionary statements to 2,3,6-TBA (ISO). They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Prevention

What to do before and during handling so the hazard never happens.

Disposal

What has to happen to the contents and the empty container.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

2,3,6-TBA (ISO) name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български 2,3,6-TBA (ISO) 2,3,6-трихлоробензоена киселина
Spanish español 2,3,6-TBA (ISO) ácido 2,3,6-triclorobenzoico
Czech čeština 2,3,6-TBA (ISO) 2,3,6-trichlorbenzoová kyselina
Danish dansk 2,3,6-TBA (ISO), 2,3,6-trichlorbenzoesyre
German Deutsch 2,3,6-TBA (ISO) 2,3,6-Trichlorbenzoesäure
Estonian eesti 2,3,6-TBA (ISO) 2,3,6-triklorobensoehape
Greek ελληνικά 2,3,6-TBA (ISO) 2,3,6-τριχλωροβενζοϊκό οξύ
English English 2,3,6-TBA (ISO) 2,3,6-trichlorobenzoic acid
French français 2,3,6-TBA (ISO) acide 2,3,6-trichlorobenzoïque
Croatian hrvatski 2,3,6-TBA (ISO) 2,3,6-triklorbenzojeva kiselina
Italian italiano 2,3,6-TBA (ISO) acido 2,3,6-triclorobenzoico
Latvian latviešu 2,3,6-TBA (ISO) 2,3,6-trihlorbenzoskābe
Lithuanian lietuvių 2,3,6-TBA (ISO) 2,3,6-trichlorbenzenkarboksirūgštis
Hungarian magyar 2,3,6-TBA (ISO) 2,3,6-triklórbenzoesav
Maltese Malti 2,3,6-TBA (ISO) aċidu 2,3,6-triklorobenżojku
Dutch Nederlands 2,3,6-TBA (ISO) 2,3,6-trichloorbenzoëzuur
Polish polski 2,3,6-TBA (ISO) kwas 2,3,6-trichlorobenzoesowy
Portuguese português 2,3,6-TBA (ISO) ácido 2,3,6-triclorobenzóico
Romanian română 2,3,6-TBA (ISO) acid 2,3,6-triclorobenzoic
Slovak slovenčina 2,3,6-TBA (ISO) kyselina 2,3,6-trichlórbenzoová
Slovenian slovenščina 2,3,6-TBA (ISO) 2,3,6-triklorobenzojska kislina
Finnish suomi 2,3,6-TBA (ISO) 2,3,6-triklooribentsoehappo
Swedish svenska 2,3,6-TBA (ISO) 2,3,6-triklorbensoesyra

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

2,3,6-TBA (ISO) GHS label elements

Everything CLP Annex VI fixes for 2,3,6-TBA (ISO), laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS07 Exclamation mark pictogramGHS09 Environment pictogram

Warning

2,3,6-TBA (ISO)

  • Harmful if swallowed.
  • Toxic to aquatic life with long lasting effects.
  • Do not eat, drink or smoke when using this product.
  • Avoid release to the environment.
  • IF SWALLOWED:
  • Call a POISON CENTER/doctor/ if you feel unwell.
  • Rinse mouth.
  • Collect spillage.
  • Dispose of contents/container to

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open 2,3,6-TBA (ISO) in the GHS label constructor →

07 · Health hazards

2,3,6-TBA (ISO) health hazards and exposure limits

2,3,6-TBA (ISO) hazard summary

Effects in animal experiments include enzyme inhibition/induction; [RTECS] In a subchronic feeding study of rats, hepatic degenerative changes were seen microscopically; [HSDB] May cause irritation; Targets the liver; [MSDSonline]

Source: Haz-Map, Information on Hazardous Chemicals and Occupational Diseases

08 · Physical and chemical properties

2,3,6-TBA (ISO) properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

2,3,6-TBA (ISO) melting point

Property Value Conditions Source
Melting point 124.5 °C (256.1 °F) HSDB

2,3,6-TBA (ISO) solubility

Property Value Conditions Source
Solubility Soluble in ethyl ether HSDB
In water, 7.7X10+3 mg/L at 22 °C at 22 °C HSDB

2,3,6-TBA (ISO) vapor pressure

Property Value Conditions Source
Vapor pressure 0.00055 mmHg at 25 °C HSDB
0.00055 mmHg Haz-Map

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

09 · Questions

2,3,6-TBA (ISO) — frequently asked questions

What is the CAS number of 2,3,6-TBA (ISO)?

The CAS number of 2,3,6-TBA (ISO) is 50-31-7. Its EC number is 200-026-4.

What does a 2,3,6-TBA (ISO) label have to show?

Under CLP Annex VI the label for 2,3,6-TBA (ISO) carries the pictograms Exclamation mark and Environment and the signal word is Warning.

Is 2,3,6-TBA (ISO) flammable?

CLP Annex VI assigns 2,3,6-TBA (ISO) no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it.

Is 2,3,6-TBA (ISO) a carcinogen?

CLP Annex VI records no harmonised carcinogenicity classification for 2,3,6-TBA (ISO). Annex VI is a list of agreed classifications, not a list of substances found safe, so this is an absence of a classification rather than a clean bill of health.

What is the melting point of 2,3,6-TBA (ISO)?

The melting point reported for 2,3,6-TBA (ISO) is 124.5 °C (256.1 °F) (HSDB).

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