Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

2,4,6-trichloro-1,3,5-triazine

2,4,6-trichloro-1,3,5-triazine is crystals from ether or benzene with a pungent odor.

CAS 108-77-0 C3Cl3N3 184.41 g/mol Danger

01 · Identification

What 2,4,6-trichloro-1,3,5-triazine is

2,4,6-trichloro-1,3,5-triazine is crystals from ether or benzene with a pungent odor. Its molecular formula is C3Cl3N3 and its molecular weight is 184.41 g/mol. It boils at 192 °C, melts at 146 °C.

Under the GHS it carries the signal word Danger. It is classed as corrosives.

02 · Identifiers

2,4,6-trichloro-1,3,5-triazine identifiers and molecular data

2,4,6-trichloro-1,3,5-triazine CAS number and EC number

CAS number108-77-0
EC number203-614-9
Index number (CLP Annex VI)613-009-00-5

2,4,6-trichloro-1,3,5-triazine molecular formula and molecular weight

Molecular formulaC3Cl3N3
Molecular weight184.41 g/mol
Chemical class Corrosives

Other names for 2,4,6-trichloro-1,3,5-triazine

  • cyanuric chloride

03 · GHS classification

2,4,6-trichloro-1,3,5-triazine hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

2,4,6-trichloro-1,3,5-triazine pictograms and signal word

Signal wordDanger

2,4,6-trichloro-1,3,5-triazine hazard class and category

GHS hazard classes 2,4,6-trichloro-1,3,5-tria… falls into
Hazard class Category From code Pictogram
Acute toxicity - oral GHS chapter 3.1 Category 4 H302 GHS07
Acute toxicity - inhalation GHS chapter 3.1 Category 1 or 2 H330 GHS06
Skin corrosion/irritation GHS chapter 3.2 Category 1A or 1B or 1C H314 GHS05
Skin sensitisation GHS chapter 3.4 Category 1 or 1A or 1B H317 GHS07

Where two values are shown with “or”, the hazard statement is shared by more than one category or by more than one class, and the code alone does not say which. H272, for example, belongs to oxidising liquids and to oxidising solids — the physical state decides. The binding answer for a specific entry is in the CLP Annex VI table itself.

2,4,6-trichloro-1,3,5-triazine hazard statements (H-codes)

Hazard statements assigned to 2,4,6-trichloro-1,3,5-tria…
CodeHazard statement
H330 Fatal if inhaled.
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.

2,4,6-trichloro-1,3,5-triazine supplemental EU statements (EUH)

EU-specific statements assigned to 2,4,6-trichloro-1,3,5-tria…. They exist only in CLP and have no counterpart in UN GHS.
CodeStatement
EUH014 Reacts violently with water.

This page lists only the codes assigned to 2,4,6-trichloro-1,3,5-tria…. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for 2,4,6-trichloro-1,3,5-tria…

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of 2,4,6-trichloro-1,3,5… issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

2,4,6-trichloro-1,3,5-triazine precautionary statements

CLP Annex VI assigns 14 precautionary statements to 2,4,6-trichloro-1,3,5-tria…. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

2,4,6-trichloro-1,3,5-triazine name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български 2,4,6-трихлоро-1,3,5-триазин циануров хлорид
Spanish español 2,4,6-Tricloro-1,3,5-triazina cloruro de cianurilo
Czech čeština 2,4,6-trichlor-1,3,5-triazin cyanurchlorid
Danish dansk 2,4,6-trichlor-1,3,5-triazin cyanurchlorid
German Deutsch 2,4,6-Trichlor-1,3,5-triazin Cyanurchlorid
Estonian eesti 2,4,6-trikloro-1,3,5-triasiin tsüanuurkloriid
Greek ελληνικά 2,4,6-τριχλωρο-1,3,5-τριαζίνη κυανουρικό χλωρίδιο
English English 2,4,6-trichloro-1,3,5-triazine cyanuric chloride
French français 2,4,6-trichloro-1,3,5-triazine chlorure cyanurique
Croatian hrvatski 2,4,6-triklor-1,3,5-triazin cijanurni klorid
Italian italiano 2,4,6-tricloro-1,3,5-triazina cloruro di cianurile
Latvian latviešu 2,4,6-trihlor-1,3,5-triazīns cianūrhlorīds
Lithuanian lietuvių 2,4,6-trichlor-1,3,5-triazinas cianurchloridas
Hungarian magyar 2,4,6-triklór-1,3,5-triazin cianur-klorid
Maltese Malti 2,4,6-trikloro-1,3,5-triażin klorur ċjanuriku
Dutch Nederlands 2,4,6-trichloor-1,3,5-triazine cyanuurchloride
Polish polski 2,4,6-trichloro-1,3,5-triazyna chlorek cyjanuru
Portuguese português 2,4,6-tricloro-1,3,5-triazina cloreto cianúrico
Romanian română 2,4,6-tricloro-1,3,5-triazină clorură de cianuril
Slovak slovenčina 2,4,6-trichlór-1,3,5-triazín kyanurchlorid
Slovenian slovenščina 2,4,6-trikloro-1,3,5-triazin cianurski klorid
Finnish suomi 2,4,6-trikloori-1,3,5-triatsiini syanuryylikloridi
Swedish svenska 2,4,6-triklor-1,3,5-triazin cyanurklorid

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

2,4,6-trichloro-1,3,5-triazine GHS label elements

Everything CLP Annex VI fixes for 2,4,6-trichloro-1,3,5-tria…, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS06 Skull and crossbones pictogramGHS05 Corrosion pictogram

Danger

2,4,6-trichloro-1,3,5-triazine

  • Fatal if inhaled.
  • Harmful if swallowed.
  • Causes severe skin burns and eye damage.
  • May cause an allergic skin reaction.
  • Reacts violently with water.
  • Do not breathe dust/fume/gas/mist/vapours/spray.
  • Avoid breathing dust/fume/gas/mist/vapours/spray.
  • Do not eat, drink or smoke when using this product.
  • Use only outdoors or in a well-ventilated area.
  • Contaminated work clothing should not be allowed out of the workplace.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • IF SWALLOWED:
  • IF INHALED:
  • Immediately call a POISON CENTER/doctor/
  • Call a POISON CENTER/doctor/ if you feel unwell.
  • Get medical advice/attention.
  • Rinse mouth.
  • Do NOT induce vomiting.
  • If skin irritation or rash occurs:

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open 2,4,6-trichloro-1,3,5-tria… in the GHS label constructor →

07 · Health hazards

2,4,6-trichloro-1,3,5-triazine health hazards and exposure limits

2,4,6-trichloro-1,3,5-triazine hazard summary

A severe skin, eye, and respiratory tract irritant; May cause pulmonary edema; May cause skin sensitization and asthma after prolonged contact; [ICSC] Toxic by ingestion and inhalation; [Hawley] Lachrymator; [CHEMINFO] Causes burns; Harmful if swallowed; Very toxic by inhalation; Reacts violently with water; May cause skin sensitization; [MSDSonline]

Source: Haz-Map, Information on Hazardous Chemicals and Occupational Diseases

08 · Physical and chemical properties

2,4,6-trichloro-1,3,5-triazine properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

2,4,6-trichloro-1,3,5-triazine boiling point

Property Value Conditions Source
Boiling point 192 °C (377.6 °F) HSDB
194 °C (381.2 °F) at 764 mmHg HSDB

2,4,6-trichloro-1,3,5-triazine melting point

Property Value Conditions Source
Melting point 146 °C (294.8 °F) HSDB
154 °C (309.2 °F) ICSC

2,4,6-trichloro-1,3,5-triazine density

Property Value Conditions Source
Density 1.3 g/cm³ ICSC
1.32 g/cm³ at 20 °C HSDB

2,4,6-trichloro-1,3,5-triazine solubility

Property Value Conditions Source
Solubility Insol in water; sol in alcohol HSDB
Sol in chloroform, carbon tetrachloride, hot ether, dioxane, ketones HSDB
Solubility in water: reaction ICSC

2,4,6-trichloro-1,3,5-triazine vapor pressure

Property Value Conditions Source
Vapor pressure 2 mmHg at 70 °C HSDB
2.2502 mmHg at 70 °C ICSC

2,4,6-trichloro-1,3,5-triazine vapor density

Property Value Conditions Source
Vapor density 6.36 (air = 1) HSDB
6.4 (air = 1) ICSC

2,4,6-trichloro-1,3,5-triazine odor threshold

Property Value Conditions Source
Odor threshold Olfactometric measurements ... a concn of 0.019 mg/cu /m cyanuric chloride air .... HSDB

2,4,6-trichloro-1,3,5-triazine critical temperature and pressure

Property Value Conditions Source
Critical temperature and pressure 147.7 °C (297.9 °F) HSDB

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

09 · Handling and storage

2,4,6-trichloro-1,3,5-triazine storage and handling

2,4,6-trichloro-1,3,5-triazine safe storage

Separated from food and feedstuffs. See Chemical Dangers. Dry. Well closed. Keep in a well-ventilated room.

Source: ILO-WHO International Chemical Safety Cards (ICSCs)

2,4,6-trichloro-1,3,5-triazine storage conditions

IN GENERAL, MATERIALS WHICH ARE TOXIC AS STORED OR WHICH CAN DECOMP INTO TOXIC COMPONENTS...SHOULD BE STORED IN A COOL, WELL-VENTILATED PLACE, OUT OF DIRECT RAYS OF THE SUN, AWAY FROM AREAS OF HIGH FIRE HAZARD, & SHOULD BE PERIODICALLY INSPECTED... INCOMPATIBLE MATERIALS SHOULD BE ISOLATED FROM EACH OTHER.

Source: Hazardous Substances Data Bank (HSDB)

2,4,6-trichloro-1,3,5-triazine incompatible materials

Reacts violently with water producing cyanuric acid, hydrochloric acid and heat. Reacts with methanol, dimethylformamide, dimethyl sulfoxide and 2-ethoxyethanol.

Source: Hazardous Substances Data Bank (HSDB)

Planning storage for a mix of chemicals? Check 2,4,6-trichloro-1,3,5-tri… in the storage compatibility matrix →

10 · Transport

2,4,6-trichloro-1,3,5-triazine UN number and transport classification

Transport classification is a separate system from the GHS classification above. It decides how a package is marked and how a load may be carried; it does not follow from the workplace label, and the workplace label does not follow from it. The entries below are linked by CAS number, never by name.

2,4,6-trichloro-1,3,5-triazine under UN 2670 — shipping name, class and packing group

Europe · ADR 2025, Table A

Proper shipping name (3.1.2) Class Classification code PG Labels (column 5)
CYANURIC CHLORIDE 8 C4 II
  • ADR label model 8 — Corrosive substance
8

Source: ADR 2025, Table A of Chapter 3.2 · ECE/TRANS/352 Vol. I (UNECE). Class 8 is “Corrosive substances” (ADR 2.1.1.1).

Proper shipping name (column 2) Class or division PG Labels (column 6)
Cyanuric chloride 8 II
  • US DOT CORROSIVE label (§172.442)
8

Source: 49 CFR 172.101 Hazardous Materials Table · eCFR, revision 2026-08-03. Class 8 is “Corrosive material” (49 CFR 173.2).

Full UN 2670 entry — special provisions, packing instructions, quantity limits and the orange plate →

11 · Questions

2,4,6-trichloro-1,3,5-triazine — frequently asked questions

What is the CAS number of 2,4,6-trichloro-1,3,5-triazine?

The CAS number of 2,4,6-trichloro-1,3,5-triazine is 108-77-0. Its EC number is 203-614-9.

What is the chemical formula of 2,4,6-trichloro-1,3,5-triazine?

The molecular formula of 2,4,6-trichloro-1,3,5-triazine is C3Cl3N3 and its molecular weight is 184.41 g/mol.

What does a 2,4,6-trichloro-1,3,5-triazine label have to show?

Under CLP Annex VI the label for 2,4,6-trichloro-1,3,5-triazine carries the pictograms Skull and crossbones and Corrosion and the signal word is Danger.

Is 2,4,6-trichloro-1,3,5-triazine flammable?

CLP Annex VI assigns 2,4,6-trichloro-1,3,5-triazine no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it.

Is 2,4,6-trichloro-1,3,5-triazine a carcinogen?

CLP Annex VI records no harmonised carcinogenicity classification for 2,4,6-trichloro-1,3,5-triazine. Annex VI is a list of agreed classifications, not a list of substances found safe, so this is an absence of a classification rather than a clean bill of health.

What is the boiling point of 2,4,6-trichloro-1,3,5-triazine?

The boiling point reported for 2,4,6-trichloro-1,3,5-triazine is 192 °C (377.6 °F) (HSDB).

What is the melting point of 2,4,6-trichloro-1,3,5-triazine?

The melting point reported for 2,4,6-trichloro-1,3,5-triazine is 146 °C (294.8 °F) (HSDB).

How should 2,4,6-trichloro-1,3,5-triazine be stored?

IN GENERAL, MATERIALS WHICH ARE TOXIC AS STORED OR WHICH CAN DECOMP INTO TOXIC COMPONENTS...SHOULD BE STORED IN A COOL, WELL-VENTILATED PLACE, OUT OF DIRECT RAYS OF THE SUN, AWAY FROM AREAS OF HIGH FIRE HAZARD, & SHOULD BE PERIODICALLY INSPECTED... INCOMPATIBLE MATERIALS SHOULD BE ISOLATED FROM EACH OTHER. (Hazardous Substances Data Bank (HSDB))

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