Substance profile
2-(4-Morpholino)thiobenzothiazole
2-(4-Morpholino)thiobenzothiazole is buff to brown flakes with a sweet odor.
01 · Identification
What 2-(4-Morpholino)thiobenzothiaz… is
2-(4-Morpholino)thiobenzothiazole is buff to brown flakes with a sweet odor. Its molecular formula is C11H12N2OS2 and its molecular weight is 252.4 g/mol. It melts at 80 °C.
Under the GHS it carries the signal word Warning.
02 · Identifiers
2-(4-Morpholino)thiobenzothiaz… identifiers and molecular data
2-(4-Morpholino)thiobenzothiaz… CAS number and EC number
2-(4-Morpholino)thiobenzothiaz… molecular formula and molecular weight
Other names for 2-(4-Morpholino)thiobenzothiaz…
- 2-(morpholinothio)benzothiazole
03 · GHS classification
2-(4-Morpholino)thiobenzothiaz… hazard classification
Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.
2-(4-Morpholino)thiobenzothiaz… pictograms and signal word
2-(4-Morpholino)thiobenzothiaz… hazard class and category
| Hazard class | Category | From code | Pictogram |
|---|---|---|---|
| Skin corrosion/irritation GHS chapter 3.2 | Category 2 | H315 | GHS07 |
| Serious eye damage/eye irritation GHS chapter 3.3 | Category 2A | H319 | GHS07 |
| Skin sensitisation GHS chapter 3.4 | Category 1 or 1A or 1B | H317 | GHS07 |
| Hazardous to the aquatic environment - chronic GHS chapter 4.1 | Category 2 | H411 | GHS09 |
Where two values are shown with “or”, the hazard statement is shared by more than one category or by more than one class, and the code alone does not say which. H272, for example, belongs to oxidising liquids and to oxidising solids — the physical state decides. The binding answer for a specific entry is in the CLP Annex VI table itself.
2-(4-Morpholino)thiobenzothiaz… hazard statements (H-codes)
| Code | Hazard statement |
|---|---|
| H315 | Causes skin irritation. |
| H319 | Causes serious eye irritation. |
| H317 | May cause an allergic skin reaction. |
| H411 | Toxic to aquatic life with long lasting effects. |
This page lists only the codes assigned to 2-(4-Morpholino)thiobenzot…. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.
Safety Data Sheet
Getting an SDS for 2-(4-Morpholino)thiobenzot…
A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of 2-(4-Morpholino)thiobe… issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.
04 · Precautionary statements
2-(4-Morpholino)thiobenzothiaz… precautionary statements
CLP Annex VI assigns 15 precautionary statements to 2-(4-Morpholino)thiobenzot…. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.
Prevention
What to do before and during handling so the hazard never happens.
Response
What to do once exposure, spillage or fire has already happened.
Disposal
What has to happen to the contents and the empty container.
Reading the notation. … is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.
05 · Names in the regulation
2-(4-Morpholino)thiobenzothiaz… name in 23 EU languages
CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.
| Language | Name in CLP Annex VI Part 3 |
|---|---|
| Bulgarian български | 2-(морфолинотио)бензотиазол |
| Spanish español | 2-(Morfolinotio)benzotiazol |
| Czech čeština | 2-(morfolinosulfanyl)benzothiazol |
| Danish dansk | 2-(morpholinothio)benzothiazol |
| German Deutsch | 2-(morpholinothio)benzothiazole |
| Estonian eesti | 2-(morfolinotio)bensotiasool |
| Greek ελληνικά | 2-(μορφολινοθειο)βενζοθειαζόλη |
| English English | 2-(morpholinothio)benzothiazole |
| French français | 2-(morpholinothio)benzothiazole |
| Croatian hrvatski | 2-(morfolinotio)benzotiazol |
| Italian italiano | 2-(morfolinotio)benzotiazolo |
| Latvian latviešu | 2-(morfolinotio)benztiazols |
| Lithuanian lietuvių | 2-(morfolinotio)benztiazolas |
| Hungarian magyar | 2-(morfolinotio)benzotiazol |
| Maltese Malti | 2-(morfolinotio)benżotiażol |
| Dutch Nederlands | 2-(morfolinothio)benzothiazool |
| Polish polski | 2-(morfolinotio)benzotiazol |
| Portuguese português | 2-(morfolinotio)benzotiazole |
| Romanian română | 2-(morfolinotio)benzotiazol |
| Slovak slovenčina | 2-(morfolinosulfanyl)benzotiazol |
| Slovenian slovenščina | 2-(morfolinotio)benzotiazol |
| Finnish suomi | 2-(morfolinotio)bentsotiatsoli |
| Swedish svenska | 2-(morfolinotio)bensotiazol |
All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.
06 · Label elements
2-(4-Morpholino)thiobenzothiaz… GHS label elements
Everything CLP Annex VI fixes for 2-(4-Morpholino)thiobenzot…, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.
Warning
2-(4-Morpholino)thiobenzothiaz…
- Causes skin irritation.
- Causes serious eye irritation.
- May cause an allergic skin reaction.
- Toxic to aquatic life with long lasting effects.
- Avoid breathing dust/fume/gas/mist/vapours/spray.
- Wash … thoroughly after handling.
- Contaminated work clothing should not be allowed out of the workplace.
- Avoid release to the environment.
- Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/…
- IF ON SKIN:
- IF IN EYES:
- Get medical advice/attention.
- If skin irritation occurs:
- If skin irritation or rash occurs:
- If eye irritation persists:
- Remove contact lenses, if present and easy to do. Continue rinsing.
- Wash with plenty of water/…
- Collect spillage.
- Dispose of contents/container to …
Supplier name, address and telephone number· Product identifier·Nominal quantity
Need this as an actual label? Open 2-(4-Morpholino)thiobenzot… in the GHS label constructor →
07 · Health hazards
2-(4-Morpholino)thiobenzothiaz… health hazards and exposure limits
2-(4-Morpholino)thiobenzothiaz… hazard summary
May cause skin sensitization; [CHEMINFO] Danger of skin sensitization; [MAK] A skin and eye irritant; May cause skin sensitization; [eChemPortal: ESIS] A mild skin and eye irritant; May cause skin sensitization; [MSDSonline] It causes delayed-type skin sensitization; A case of immediate-type hypersensitivity was reported in a dental assistant; [Kanerva, p. 1818] See Mercaptobenzothiazole.
Source: Haz-Map, Information on Hazardous Chemicals and Occupational Diseases
08 · Physical and chemical properties
2-(4-Morpholino)thiobenzothiaz… properties
Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.
2-(4-Morpholino)thiobenzothiaz… melting point
| Property | Value | Conditions | Source |
|---|---|---|---|
| Melting point | 80 °C (176 °F) | HSDB |
2-(4-Morpholino)thiobenzothiaz… density
| Property | Value | Conditions | Source |
|---|---|---|---|
| Density | 1.34 g/cm³ | at 25 °C | HSDB |
2-(4-Morpholino)thiobenzothiaz… solubility
| Property | Value | Conditions | Source |
|---|---|---|---|
| Solubility | INSOL IN WATER, SOL IN BENZENE, ACETONE, METHANOL | HSDB |
2-(4-Morpholino)thiobenzothiaz… flash point
| Property | Value | Conditions | Source |
|---|---|---|---|
| Flash point | 188 °C (370.4 °F) | Haz-Map |
Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.
09 · Handling and storage
2-(4-Morpholino)thiobenzothiaz… storage and handling
2-(4-Morpholino)thiobenzothiaz… storage conditions
MATERIALS WHICH ARE TOXIC AS STORED OR WHICH CAN DECOMPOSE INTO TOXIC COMPONENTS...SHOULD BE STORED IN A COOL WELL-VENTILATED PLACE, OUT OF DIRECT RAYS OF THE SUN, AWAY FROM AREAS OF HIGH FIRE HAZARD, AND SHOULD BE PERIODICALLY INSPECTED... INCOMPATIBLE MATERIALS SHOULD BE ISOLATED...
Source: Hazardous Substances Data Bank (HSDB)
Planning storage for a mix of chemicals? Check 2-(4-Morpholino)thiobenzo… in the storage compatibility matrix →
10 · Questions
2-(4-Morpholino)thiobenzothiaz… — frequently asked questions
What is the CAS number of 2-(4-Morpholino)thiobenzothiaz…?
The CAS number of 2-(4-Morpholino)thiobenzothiaz… is 102-77-2. Its EC number is 203-052-4.
What is the chemical formula of 2-(4-Morpholino)thiobenzothiaz…?
The molecular formula of 2-(4-Morpholino)thiobenzothiaz… is C11H12N2OS2 and its molecular weight is 252.4 g/mol.
What does a 2-(4-Morpholino)thiobenzothiaz… label have to show?
Under CLP Annex VI the label for 2-(4-Morpholino)thiobenzothiaz… carries the pictograms Exclamation mark and Environment and the signal word is Warning.
Is 2-(4-Morpholino)thiobenzothiaz… flammable?
CLP Annex VI assigns 2-(4-Morpholino)thiobenzothiaz… no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it. The flash point reported for it is 188 °C (370.4 °F) (Haz-Map).
Is 2-(4-Morpholino)thiobenzothiaz… a carcinogen?
CLP Annex VI records no harmonised carcinogenicity classification for 2-(4-Morpholino)thiobenzothiaz…. Annex VI is a list of agreed classifications, not a list of substances found safe, so this is an absence of a classification rather than a clean bill of health.
What is the melting point of 2-(4-Morpholino)thiobenzothiaz…?
The melting point reported for 2-(4-Morpholino)thiobenzothiaz… is 80 °C (176 °F) (HSDB).
How should 2-(4-Morpholino)thiobenzothiaz… be stored?
MATERIALS WHICH ARE TOXIC AS STORED OR WHICH CAN DECOMPOSE INTO TOXIC COMPONENTS...SHOULD BE STORED IN A COOL WELL-VENTILATED PLACE, OUT OF DIRECT RAYS OF THE SUN, AWAY FROM AREAS OF HIGH FIRE HAZARD, AND SHOULD BE PERIODICALLY INSPECTED... INCOMPATIBLE MATERIALS SHOULD BE ISOLATED... (Hazardous Substances Data Bank (HSDB))
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