Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

2-Ethyl-1-butanol

2-Ethyl-1-butanol is a colorless liquid.

CAS 97-95-0 C6H14O 102.17 g/mol Warning

01 · Identification

What 2-Ethyl-1-butanol is

2-Ethyl-1-butanol is a colorless liquid. Its molecular formula is C6H14O and its molecular weight is 102.17 g/mol. It boils at 146 °C, melts at -114 °C.

Under the GHS it carries the signal word Warning. It is classed as flammable agents - 2nd degree.

02 · Identifiers

2-Ethyl-1-butanol identifiers and molecular data

2-Ethyl-1-butanol CAS number and EC number

CAS number97-95-0
EC number202-621-4
Index number (CLP Annex VI)603-051-00-2

2-Ethyl-1-butanol molecular formula and molecular weight

Molecular formulaC6H14O
Molecular weight102.17 g/mol
Chemical class Flammable agents - 2nd degree

Other names for 2-Ethyl-1-butanol

  • 2-ethylbutan-1-ol

03 · GHS classification

2-Ethyl-1-butanol hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

2-Ethyl-1-butanol pictograms and signal word

Signal wordWarning

2-Ethyl-1-butanol hazard class and category

GHS hazard classes 2-Ethyl-1-butanol falls into
Hazard class Category From code Pictogram
Acute toxicity - oral GHS chapter 3.1 Category 4 H302 GHS07
Acute toxicity - dermal GHS chapter 3.1 Category 4 H312 GHS07

2-Ethyl-1-butanol hazard statements (H-codes)

Hazard statements assigned to 2-Ethyl-1-butanol
CodeHazard statement
H312 Harmful in contact with skin.
H302 Harmful if swallowed.

This page lists only the codes assigned to 2-Ethyl-1-butanol. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for 2-Ethyl-1-butanol

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of 2-Ethyl-1-butanol issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

2-Ethyl-1-butanol precautionary statements

CLP Annex VI assigns 7 precautionary statements to 2-Ethyl-1-butanol. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

2-Ethyl-1-butanol name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български 2-етилбутан-1-ол
Spanish español 2-Etilbutan-1-ol
Czech čeština 2-ethylbutan-1-ol
Danish dansk 2-ethylbutanol
German Deutsch 2-Ethylbutanol
Estonian eesti 2-etüülbutaan-1-ool
Greek ελληνικά 2-αιθυλοβoυταν-1-όλη
English English 2-ethylbutan-1-ol
French français 2-éthylbutan-1-ol
Croatian hrvatski 2-etilbutan-1-ol
Italian italiano 2-etilbutanolo
Latvian latviešu 2-etilbutān-1-ols
Lithuanian lietuvių 2-etilbutanolis
Hungarian magyar 2-etilbután-1-ol
Maltese Malti 2-etilbutan-1-ol
Dutch Nederlands 2-ethylbutaan-1-ol
Polish polski 2-etylobutan-1-ol alkohol 2-etylobutylowy
Portuguese português 2-etil-1-butanol
Romanian română 2-etilbutan-1-ol
Slovak slovenčina 2-etylbután-1-ol
Slovenian slovenščina 2-etilbutan-1-ol
Finnish suomi 2-etyylibutan-1-oli
Swedish svenska 2-etylbutan-1-ol

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

2-Ethyl-1-butanol GHS label elements

Everything CLP Annex VI fixes for 2-Ethyl-1-butanol, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS07 Exclamation mark pictogram

Warning

2-Ethyl-1-butanol

  • Harmful in contact with skin.
  • Harmful if swallowed.
  • Do not eat, drink or smoke when using this product.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • IF SWALLOWED:
  • IF ON SKIN:
  • Call a POISON CENTER/doctor/ if you feel unwell.
  • Rinse mouth.
  • Wash with plenty of water/

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open 2-Ethyl-1-butanol in the GHS label constructor →

07 · Health hazards

2-Ethyl-1-butanol health hazards and exposure limits

2-Ethyl-1-butanol hazard summary

May burn eyes; A mild nose and throat irritant; [CAMEO] A nose and throat irritant; A severe eye irritant, based on animal studies; Inhalation of high concentrations can cause CNS depression; [CHEMINFO] An irritant; Can be absorbed through skin; [MSDSonline]

Source: Haz-Map, Information on Hazardous Chemicals and Occupational Diseases

08 · Physical and chemical properties

2-Ethyl-1-butanol properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

2-Ethyl-1-butanol boiling point

Property Value Conditions Source
Boiling point 146.27 °C (295.3 °F) at 760 mmHg HSDB
145 °C (293 °F) at 760 mmHg CAMEO

2-Ethyl-1-butanol melting point

Property Value Conditions Source
Melting point -113.89 °C (-173 °F) CAMEO
-15 °C (5 °F) below this value HSDB

2-Ethyl-1-butanol density

Property Value Conditions Source
Density 0.8326 g/cm³ at 20 °C HSDB
0.834 g/cm³ at 20 °C CAMEO

2-Ethyl-1-butanol solubility

Property Value Conditions Source
Solubility SLIGHTLY SOL IN WATER; SOL IN ALCOHOL, ETHER HSDB
MISCIBLE WITH MOST ORGANIC SOLVENTS HSDB

2-Ethyl-1-butanol vapor pressure

Property Value Conditions Source
Vapor pressure 3.62 mmHg CAMEO
0.9 mmHg at 20 °C HSDB
1.53 mmHg Haz-Map

2-Ethyl-1-butanol flash point

Property Value Conditions Source
Flash point 58.33 °C (137 °F) HSDB
53.33 °C (128 °F) CAMEO

2-Ethyl-1-butanol autoignition temperature

Property Value Conditions Source
Autoignition temperature 304.44 °C (580 °F) CAMEO

2-Ethyl-1-butanol lower explosive limit (LEL)

Property Value Conditions Source
Lower explosive limit (LEL) 1.9 % by volume CAMEO

2-Ethyl-1-butanol upper explosive limit (UEL)

Property Value Conditions Source
Upper explosive limit (UEL) 8.8 % by volume CAMEO

2-Ethyl-1-butanol odor threshold

Property Value Conditions Source
Odor threshold Odor Threshold Low: 0.07 [ppm] Haz-Map
Odor Threshold High: 0.77 [ppm] Haz-Map
Odor threshold low (perception) and high (recognition) from CHEMINFO Haz-Map

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

09 · Fire and explosion

2-Ethyl-1-butanol fire and explosion behaviour

These are descriptions rather than measured values, so they are kept out of the table above and quoted here with the source that reported them.

2-Ethyl-1-butanol fire potential

COMBUSTIBLE.

Source: Hazardous Substances Data Bank (HSDB)

10 · Handling and storage

2-Ethyl-1-butanol storage and handling

2-Ethyl-1-butanol peroxide formation

D: Other compounds that may form peroxides

Source: Lab and Research Safety, University of Minnesota

2-Ethyl-1-butanol reactivity

Flammable and/or toxic gases are generated by the combination of alcohols, such as 2-ETHYLBUTANOL, with alkali metals, nitrides, and strong reducing agents. Alcohols react with oxoacids and carboxylic acids to form esters plus water. Oxidizing agents convert them to aldehydes or ketones. Alcohols exhibit both weak acid and weak base behavior. They may initiate the polymerization of isocyanates and epoxides.

Source: CAMEO Chemicals

Planning storage for a mix of chemicals? Check 2-Ethyl-1-butanol in the storage compatibility matrix →

11 · Questions

2-Ethyl-1-butanol — frequently asked questions

What is the CAS number of 2-Ethyl-1-butanol?

The CAS number of 2-Ethyl-1-butanol is 97-95-0. Its EC number is 202-621-4.

What is the chemical formula of 2-Ethyl-1-butanol?

The molecular formula of 2-Ethyl-1-butanol is C6H14O and its molecular weight is 102.17 g/mol.

What does a 2-Ethyl-1-butanol label have to show?

Under CLP Annex VI the label for 2-Ethyl-1-butanol carries the pictogram Exclamation mark and the signal word is Warning.

Is 2-Ethyl-1-butanol flammable?

CLP Annex VI assigns 2-Ethyl-1-butanol no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it. The flash point reported for it is 58.33 °C (137 °F) (HSDB).

Is 2-Ethyl-1-butanol a carcinogen?

CLP Annex VI records no harmonised carcinogenicity classification for 2-Ethyl-1-butanol. Annex VI is a list of agreed classifications, not a list of substances found safe, so this is an absence of a classification rather than a clean bill of health.

What is the boiling point of 2-Ethyl-1-butanol?

The boiling point reported for 2-Ethyl-1-butanol is 146.27 °C (295.3 °F), at 760 mmHg (HSDB).

What is the melting point of 2-Ethyl-1-butanol?

The melting point reported for 2-Ethyl-1-butanol is -113.89 °C (-173 °F) (CAMEO).

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