Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

2-isopropoxyethanol

2-isopropoxyethanol is a colorless liquid with a mild ethereal odor.

CAS 109-59-1 C5H12O2 104.15 g/mol Warning

01 · Identification

What 2-isopropoxyethanol is

2-isopropoxyethanol is a colorless liquid with a mild ethereal odor. Its molecular formula is C5H12O2 and its molecular weight is 104.15 g/mol. It boils at 144 °C, melts at -60 °C.

Under the GHS it carries the signal word Warning. It is classed as flammable agents - 2nd degree.

02 · Identifiers

2-isopropoxyethanol identifiers and molecular data

2-isopropoxyethanol CAS number and EC number

CAS number109-59-1
EC number203-685-6
Index number (CLP Annex VI)603-013-00-5

2-isopropoxyethanol molecular formula and molecular weight

Molecular formulaC5H12O2
Molecular weight104.15 g/mol
Chemical class Flammable agents - 2nd degree

Other names for 2-isopropoxyethanol

  • ethylene glycol monoisopropyl ether

03 · GHS classification

2-isopropoxyethanol hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

2-isopropoxyethanol pictograms and signal word

Signal wordWarning

2-isopropoxyethanol hazard class and category

GHS hazard classes 2-isopropoxyethanol falls into
Hazard class Category From code Pictogram
Acute toxicity - dermal GHS chapter 3.1 Category 4 H312 GHS07
Acute toxicity - inhalation GHS chapter 3.1 Category 4 H332 GHS07
Serious eye damage/eye irritation GHS chapter 3.3 Category 2A H319 GHS07

2-isopropoxyethanol hazard statements (H-codes)

Hazard statements assigned to 2-isopropoxyethanol
CodeHazard statement
H332 Harmful if inhaled.
H312 Harmful in contact with skin.
H319 Causes serious eye irritation.

This page lists only the codes assigned to 2-isopropoxyethanol. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for 2-isopropoxyethanol

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of 2-isopropoxyethanol issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

2-isopropoxyethanol precautionary statements

CLP Annex VI assigns 12 precautionary statements to 2-isopropoxyethanol. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

2-isopropoxyethanol name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български 2-изопропоксиетанол моноизопропилов етер на етиленгликола
Spanish español 2-Isopropoxietanol éter monoisopropílico de etilenglicol
Czech čeština 2-isopropoxyethan-1-ol isopropylglykol
Danish dansk 2-isopropoxyethanol isopropylglycol
German Deutsch 2-Isopropoxyethanol IsopropylglycolEthylenglykol-monoisopropylether
Estonian eesti 2-isopropoksüetanool etüleenglükooli monoisopropüüleeter
Greek ελληνικά 2-ισοπροποξυαιθανόλη μονοϊσοπροπυλαιθέρας της αιθυλενογλυκόλης
English English 2-isopropoxyethanol ethylene glycol monoisopropyl ether
French français 2-isopropoxyéthanol éther monoisopropylique d'éthylène glycol
Croatian hrvatski 2-izopropoksietanol etilen-glikol-monoizopropil-eter
Italian italiano 2-isopropossietanolo etilenglicol-monoisopropiletere isopropilglicol
Latvian latviešu 2-izopropoksietanols etiletilēnglikola monoizopropiletilēteris
Lithuanian lietuvių 2-izopropoksietanolis etilenglikolio monoizopropileteris
Hungarian magyar 2-izopropoxietanol etilén-glikol-monoizopropil-éter
Maltese Malti 2-isopropossietanol eter tal-monoisopropil tal-glikol tal-etilen
Dutch Nederlands 2-isopropoxyethanol ethyleenglycolmonoïsopropylether
Polish polski 2-izopropoksyetanol eter monoizopropylowy glikolu etylenowegocellosolw izopropylowy
Portuguese português 2-isopropoxietanol éter monoisopropílico de etilenoglicol
Romanian română 2-isopropoxietanol eter monoizopropilic al etilenglicolului
Slovak slovenčina 2-izopropoxyetanol etylénglykol-monoizopropyléter
Slovenian slovenščina 2-izopropoksietanol etilenglikol monoizopropil eter
Finnish suomi 2-isopropoksietanoli etyleeniglykolimonoisopropyylieetteri
Swedish svenska 2-isopropoxietanol etylenglykolmonoisopropyleter

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

2-isopropoxyethanol GHS label elements

Everything CLP Annex VI fixes for 2-isopropoxyethanol, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS07 Exclamation mark pictogram

Warning

2-isopropoxyethanol

  • Harmful if inhaled.
  • Harmful in contact with skin.
  • Causes serious eye irritation.
  • Do not breathe dust/fume/gas/mist/vapours/spray.
  • Wash thoroughly after handling.
  • Use only outdoors or in a well-ventilated area.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • IF ON SKIN:
  • IF INHALED:
  • IF IN EYES:
  • Call a POISON CENTER/doctor/ if you feel unwell.
  • Get medical advice/attention.
  • If eye irritation persists:
  • Remove contact lenses, if present and easy to do. Continue rinsing.
  • Wash with plenty of water/

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open 2-isopropoxyethanol in the GHS label constructor →

07 · Health hazards

2-isopropoxyethanol health hazards and exposure limits

2-isopropoxyethanol hazard summary

Osmotic fragility of rat erythrocytes markedly increased at exposures of 200 ppm; [ACGIH] Inhalation of high concentrations can cause CNS depression; [HSDB] May cause skin and eye irritation; [CAMEO] See Glycol ethers.

Source: Haz-Map, Information on Hazardous Chemicals and Occupational Diseases

2-isopropoxyethanol occupational exposure limits

US occupational exposure limits reported for 2-isopropoxyethanol. PEL is enforceable (OSHA), REL is a recommendation (NIOSH), IDLH is the concentration at which escape becomes impossible without injury.
Limit Value Source
PEL none See Appendix G The National Institute for Occupational Safety and Health (NIOSH)
IDLH N.D. The National Institute for Occupational Safety and Health (NIOSH)

These are United States values. The European Union sets its own indicative and binding limits, and the figure that applies at a given workplace is the one in the local regulation — not the one shown here.

08 · Physical and chemical properties

2-isopropoxyethanol properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

2-isopropoxyethanol boiling point

Property Value Conditions Source
Boiling point 144 °C (291.2 °F) at 743 mmHg HSDB
139.44 °C (283 °F) NIOSH
141 °C (285.8 °F) at 760 mmHg CAMEO

2-isopropoxyethanol melting point

Property Value Conditions Source
Melting point -60 °C (-76 °F) ICSC

2-isopropoxyethanol density

Property Value Conditions Source
Density 0.9 g/cm³ NIOSH
0.91 g/cm³ CAMEO
0.903 g/cm³ at 20 °C HSDB

2-isopropoxyethanol solubility

Property Value Conditions Source
Solubility SOL IN ALL PROP IN WATER, ALC, ETHER; SOL IN ACETONE HSDB
Miscible NIOSH
Miscible (NIOSH, 2024) CAMEO

2-isopropoxyethanol vapor pressure

Property Value Conditions Source
Vapor pressure 3 mmHg NIOSH
5.2 mmHg at 25 °C HSDB

2-isopropoxyethanol flash point

Property Value Conditions Source
Flash point 33.33 °C (92 °F) HSDB
33 °C (91.4 °F) CAMEO

2-isopropoxyethanol autoignition temperature

Property Value Conditions Source
Autoignition temperature 240 °C (464 °F) ICSC

2-isopropoxyethanol lower explosive limit (LEL)

Property Value Conditions Source
Lower explosive limit (LEL) 1.6 % by volume ICSC
Class IC Flammable Liquid: Fl.P. at or above 73 °F and below 100 °F. NIOSH

2-isopropoxyethanol upper explosive limit (UEL)

Property Value Conditions Source
Upper explosive limit (UEL) 13 % by volume ICSC

2-isopropoxyethanol vapor density

Property Value Conditions Source
Vapor density 3.6 (air = 1) HSDB

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

09 · Fire and explosion

2-isopropoxyethanol fire and explosion behaviour

These are descriptions rather than measured values, so they are kept out of the table above and quoted here with the source that reported them.

2-isopropoxyethanol fire potential

MODERATE; CAN REACT WITH OXIDIZING MATERIALS

Source: Hazardous Substances Data Bank (HSDB)

10 · Handling and storage

2-isopropoxyethanol storage and handling

2-isopropoxyethanol safe storage

Cool. Fireproof. Separated from strong oxidants.

Source: ILO-WHO International Chemical Safety Cards (ICSCs)

2-isopropoxyethanol storage conditions

SEE ETHERS. ETHERS SHOULD NOT BE STORED NEAR POWERFUL OXIDIZERS OR IN AREAS OF HIGH FIRE HAZARD. THEY SHOULD BE KEPT COOL AND THE CONTAINERS ELECTRICALLY GROUNDED TO AVOID SPARKS. /ETHERS/

Source: Hazardous Substances Data Bank (HSDB)

2-isopropoxyethanol incompatible materials

Oxidizers.

Source: Hazardous Substances Data Bank (HSDB)

2-isopropoxyethanol reactivity

ETHYLENE GLYCOL ISOPROPYL ETHER acts both as an alcohol and ether. May react violently with strong oxidizing agents. May generate flammable and/or toxic gases with alkali metals, nitrides, and other strong reducing agents. May initiate the polymerization of isocyanates and epoxides.

Source: CAMEO Chemicals

Planning storage for a mix of chemicals? Check 2-isopropoxyethanol in the storage compatibility matrix →

11 · Questions

2-isopropoxyethanol — frequently asked questions

What is the CAS number of 2-isopropoxyethanol?

The CAS number of 2-isopropoxyethanol is 109-59-1. Its EC number is 203-685-6.

What is the chemical formula of 2-isopropoxyethanol?

The molecular formula of 2-isopropoxyethanol is C5H12O2 and its molecular weight is 104.15 g/mol.

What does a 2-isopropoxyethanol label have to show?

Under CLP Annex VI the label for 2-isopropoxyethanol carries the pictogram Exclamation mark and the signal word is Warning.

Is 2-isopropoxyethanol flammable?

CLP Annex VI assigns 2-isopropoxyethanol no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it. The flash point reported for it is 33.33 °C (92 °F) (HSDB).

Is 2-isopropoxyethanol a carcinogen?

CLP Annex VI records no harmonised carcinogenicity classification for 2-isopropoxyethanol. Annex VI is a list of agreed classifications, not a list of substances found safe, so this is an absence of a classification rather than a clean bill of health.

What is the exposure limit for 2-isopropoxyethanol?

The US occupational exposure limit reported for 2-isopropoxyethanol is none See Appendix G (The National Institute for Occupational Safety and Health (NIOSH)). Limits differ by country: the EU sets its own indicative and binding values, and the figure that applies at a given workplace is the one in the local regulation.

What is the boiling point of 2-isopropoxyethanol?

The boiling point reported for 2-isopropoxyethanol is 144 °C (291.2 °F), at 743 mmHg (HSDB).

What is the melting point of 2-isopropoxyethanol?

The melting point reported for 2-isopropoxyethanol is -60 °C (-76 °F) (ICSC).

How should 2-isopropoxyethanol be stored?

SEE ETHERS. ETHERS SHOULD NOT BE STORED NEAR POWERFUL OXIDIZERS OR IN AREAS OF HIGH FIRE HAZARD. THEY SHOULD BE KEPT COOL AND THE CONTAINERS ELECTRICALLY GROUNDED TO AVOID SPARKS. /ETHERS/ (Hazardous Substances Data Bank (HSDB))

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