Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

2-(Methylamino)ethanol

2-(Methylamino)ethanol is a viscous liquid with a fishy odor.

CAS 109-83-1 C3H9NO 75.11 g/mol Danger

01 · Identification

What 2-(Methylamino)ethanol is

2-(Methylamino)ethanol is a viscous liquid with a fishy odor. Its molecular formula is C3H9NO and its molecular weight is 75.11 g/mol. It boils at 1559 °C, melts at -3 °C, is miscible with water.

Under the GHS it carries the signal word Danger. It is classed as corrosives.

02 · Identifiers

2-(Methylamino)ethanol identifiers and molecular data

2-(Methylamino)ethanol CAS number and EC number

CAS number109-83-1
EC number203-710-0
Index number (CLP Annex VI)603-080-00-0

2-(Methylamino)ethanol molecular formula and molecular weight

Molecular formulaC3H9NO
Molecular weight75.11 g/mol
Chemical class Corrosives

Other names for 2-(Methylamino)ethanol

  • 2-methylaminoethanol
  • N-methylethanolamine
  • N-methyl-2-ethanolamine
  • N-methyl-2-amino ethanol

03 · GHS classification

2-(Methylamino)ethanol hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

2-(Methylamino)ethanol pictograms and signal word

Signal wordDanger

2-(Methylamino)ethanol hazard class and category

GHS hazard classes 2-(Methylamino)ethanol falls into
Hazard class Category From code Pictogram
Acute toxicity - oral GHS chapter 3.1 Category 4 H302 GHS07
Acute toxicity - dermal GHS chapter 3.1 Category 4 H312 GHS07
Skin corrosion/irritation GHS chapter 3.2 Category 1A or 1B or 1C H314 GHS05

Where two values are shown with “or”, the hazard statement is shared by more than one category or by more than one class, and the code alone does not say which. H272, for example, belongs to oxidising liquids and to oxidising solids — the physical state decides. The binding answer for a specific entry is in the CLP Annex VI table itself.

2-(Methylamino)ethanol hazard statements (H-codes)

Hazard statements assigned to 2-(Methylamino)ethanol
CodeHazard statement
H312 Harmful in contact with skin.
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.

This page lists only the codes assigned to 2-(Methylamino)ethanol. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for 2-(Methylamino)ethanol

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of 2-(Methylamino)ethanol issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

2-(Methylamino)ethanol precautionary statements

CLP Annex VI assigns 10 precautionary statements to 2-(Methylamino)ethanol. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

2-(Methylamino)ethanol name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български 2-метиламиноетанол N -метилетаноламинN -метил-2-етаноламинN -метил-2-аминоетанол2-(метиламино)етанол
Spanish español 2-Metilaminoetanol N -metiletanolaminaN -metil-2-etanolaminaN -metil-2-amino-etanol2-(metilamino)etanol
Czech čeština 2-methylaminoethan-1-ol N -methylethanolaminN -methyl-2-ethanolaminN -methyl-2-aminoethanol2-(methylamino)ethanol
Danish dansk 2-methylaminoethanol N- methylethanolaminN- methyl-2-ethanolaminN- methyl-2-aminoethanol2-(methylamino)ethanol
German Deutsch 2-Methylaminoethanol N -MethylethanolaminN -Methyl-2-ethanolaminN -Methyl-2-aminoethanol2-(Methylamino)ethanol
Estonian eesti 2-metüülaminoetanool N -metüületanoolamiinN -metüül-2-etanoolamiinN -metüül-2-aminoetanool2-(metüülamino)etanool
Greek ελληνικά 2-μεθυλαμινοαιθανόλη N -μεθυλαιθανολαμίνηN -μεθυλ-2-αιθανολαμίνηN -μεθυλ-2-αμινική αιθανόλη2-(μεθυλαμινο)αιθανόλη
English English 2-methylaminoethanol N -methylethanolamineN -methyl-2-ethanolamineN -methyl-2-amino ethanol2-(methylamino)ethanol
French français 2-méthylaminoéthanol N -méthyléthanolamineN -méthyl-2-éthanolamineN -méthyl-2-aminoéthanol2-(méthylamino)éthanol
Croatian hrvatski 2-metilaminoetanol N -metiletanolaminN -metil-2-etanolaminN -metil-2-aminoetanol2-(metilamino)etanol
Italian italiano 2-metilaminoetanolo N -metiletanolaminaN -metil-2-ethanolaminaN -metil-2-amino ethanol2-(metilamino)ethanol
Latvian latviešu 2-metilaminoetanols N -metiletanolamīnsN -metil-2-etanolamīnsN -metil-2-aminoetanols2-(metilamino)etanols
Lithuanian lietuvių 2-metilaminoetanolis N -metiletanolaminasN -metil-2-etanolaminasN -metil-2-aminoetanolis2-(metilamino)etanolis
Hungarian magyar 2-metilaminoetanol N -metiletanolaminN -metil-2-etanolaminN -metil-2-aminoetanol2-(metilamino)etanol
Maltese Malti 2-metilamminoetanol N -metiletanolamminaN -metil-2-etanolamminaetanol ta’ N -metil-2-ammino2-(metilammino)etanol
Dutch Nederlands 2-methylaminoëthanol N -methyl-2-aminoëthanolN -methyl-2-ethanolamine2-(methylamino)ethanol
Polish polski 2-(metyloamino)etanol N -metyloetanoloaminaN -metylo-2-etanoloamina N -metylo-2-aminoetanol
Portuguese português 2-metilaminoetanol N -metiletanolaminaN- metil-2-etanolaminaN- metil-2-aminoetanol2-(metilamino)etanol
Romanian română 2-metilaminoetanol N -metiletanolaminăN -metil-2-etanolaminăN -metil-2-aminoetanol2-(metilamino)etanol
Slovak slovenčina 2-metylaminoetanol N -metyletanolamínN -metyl-2-etanolamínN -metyl-2-aminoetanol2-(metylamino)etanol
Slovenian slovenščina 2-metilaminoetanol N -metiletanolaminN -metil-2-etanolaminN -metil-2-aminoetanol2-(metilamino)etanol
Finnish suomi 2-metyyliaminoetanoli N -metyylietanoliamiiniN -metyyli-2-etanoliamiiniN -metyyli-2-aminoetanoli2-(metyyliamino)etanoli
Swedish svenska 2-metylaminoetanol N -metyletanolaminN -metyl-2-etanolaminN -metyl-2-aminoetanol2-(metylamino)etanol

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

2-(Methylamino)ethanol GHS label elements

Everything CLP Annex VI fixes for 2-(Methylamino)ethanol, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS05 Corrosion pictogramGHS07 Exclamation mark pictogram

Danger

2-(Methylamino)ethanol

  • Harmful in contact with skin.
  • Harmful if swallowed.
  • Causes severe skin burns and eye damage.
  • Do not breathe dust/fume/gas/mist/vapours/spray.
  • Do not eat, drink or smoke when using this product.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • IF SWALLOWED:
  • IF ON SKIN:
  • Immediately call a POISON CENTER/doctor/
  • Call a POISON CENTER/doctor/ if you feel unwell.
  • Rinse mouth.
  • Do NOT induce vomiting.
  • Wash with plenty of water/

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open 2-(Methylamino)ethanol in the GHS label constructor →

07 · Health hazards

2-(Methylamino)ethanol health hazards and exposure limits

2-(Methylamino)ethanol hazard summary

A corrosive substance that can cause injury to the skin, eyes, and respiratory tract; [ICSC] Not teratogenic in one study of rats receiving a vaporized dose of 150 ppm 7 hours/day during gestation days 7-15. [REPROTOX] May be absorbed through skin; Effects in high-dose animal studies include seizures and coma; [MSDSonline]

Source: Haz-Map, Information on Hazardous Chemicals and Occupational Diseases

08 · Physical and chemical properties

2-(Methylamino)ethanol properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

2-(Methylamino)ethanol boiling point

Property Value Conditions Source
Boiling point 1559 °C (2838.6 °F) HSDB
157.78 °C (316 °F) at 760 mmHg CAMEO
156 °C (312.8 °F) ICSC

2-(Methylamino)ethanol melting point

Property Value Conditions Source
Melting point -3 °C (26.6 °F) HSDB
-4.5 °C (23.9 °F) CAMEO

2-(Methylamino)ethanol density

Property Value Conditions Source
Density 0.9414 g/cm³ CAMEO
0.93 g/cm³ ICSC
0.937 g/cm³ at 20 °C HSDB

2-(Methylamino)ethanol solubility

Property Value Conditions Source
Solubility Miscible with alcohol, ether HSDB
In water, 1X10+6 mg/L (miscible) HSDB
Very soluble (NTP, 1992) CAMEO

2-(Methylamino)ethanol vapor pressure

Property Value Conditions Source
Vapor pressure 0.7 mmHg at 20 °C CAMEO
6.9756 mmHg at 20 °C ICSC
1.08 mmHg at 25 °C HSDB

2-(Methylamino)ethanol flash point

Property Value Conditions Source
Flash point 76 °C (168.8 °F) HSDB
73.89 °C (165 °F) HSDB

2-(Methylamino)ethanol autoignition temperature

Property Value Conditions Source
Autoignition temperature 350 °C (662 °F) ICSC

2-(Methylamino)ethanol lower explosive limit (LEL)

Property Value Conditions Source
Lower explosive limit (LEL) 0.9 % by volume HSDB
Above 74 °C explosive vapor/air mixtures may be formed. HSDB

2-(Methylamino)ethanol upper explosive limit (UEL)

Property Value Conditions Source
Upper explosive limit (UEL) 2.6 % by volume HSDB

2-(Methylamino)ethanol vapor density

Property Value Conditions Source
Vapor density 2.59 (air = 1) HSDB
2.6 (air = 1) ICSC

2-(Methylamino)ethanol corrosivity

Property Value Conditions Source
Corrosivity Corrosive to cork, metals HSDB

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

09 · Fire and explosion

2-(Methylamino)ethanol fire and explosion behaviour

These are descriptions rather than measured values, so they are kept out of the table above and quoted here with the source that reported them.

2-(Methylamino)ethanol fire potential

Flammable when exposed to heat, flame, or oxidizers.

Source: Hazardous Substances Data Bank (HSDB)

10 · Handling and storage

2-(Methylamino)ethanol storage and handling

2-(Methylamino)ethanol safe storage

Separated from strong oxidants and acids.

Source: ILO-WHO International Chemical Safety Cards (ICSCs)

2-(Methylamino)ethanol storage conditions

Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Storage class (TRGS 510): Combustible, corrosive hazardous materials.

Source: Hazardous Substances Data Bank (HSDB)

2-(Methylamino)ethanol incompatible materials

Incompatible materials: Oxidizing agents, copper, zinc, iron. Do not store near acids.

Source: Hazardous Substances Data Bank (HSDB)

2-(Methylamino)ethanol reactivity

METHYLETHANOLAMINE is an aminoalcohol. Amines are chemical bases. They neutralize acids to form salts plus water. These acid-base reactions are exothermic. The amount of heat that is evolved per mole of amine in a neutralization is largely independent of the strength of the amine as a base. Amines may be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen is generated by amines in combination with strong reducing agents, such as hydrides. This compound may react with oxidizing materials. (NTP, 1992)

Source: CAMEO Chemicals

Planning storage for a mix of chemicals? Check 2-(Methylamino)ethanol in the storage compatibility matrix →

11 · Transport

2-(Methylamino)ethanol UN number and transport classification

Transport classification is a separate system from the GHS classification above. It decides how a package is marked and how a load may be carried; it does not follow from the workplace label, and the workplace label does not follow from it. The entries below are linked by CAS number, never by name.

2-(Methylamino)ethanol under UN 3055 — shipping name, class and packing group

Europe · ADR 2025, Table A

Proper shipping name (3.1.2) Class Classification code PG Labels (column 5)
2-(2-AMINOETHOXY) ETHANOL 8 C7 III
  • ADR label model 8 — Corrosive substance
8

Source: ADR 2025, Table A of Chapter 3.2 · ECE/TRANS/352 Vol. I (UNECE). Class 8 is “Corrosive substances” (ADR 2.1.1.1).

Proper shipping name (column 2) Class or division PG Labels (column 6)
2-(2-Aminoethoxy) ethanol 8 III
  • US DOT CORROSIVE label (§172.442)
8

Source: 49 CFR 172.101 Hazardous Materials Table · eCFR, revision 2026-08-03. Class 8 is “Corrosive material” (49 CFR 173.2).

Full UN 3055 entry — special provisions, packing instructions, quantity limits and the orange plate →

12 · Questions

2-(Methylamino)ethanol — frequently asked questions

What is the CAS number of 2-(Methylamino)ethanol?

The CAS number of 2-(Methylamino)ethanol is 109-83-1. Its EC number is 203-710-0.

What is the chemical formula of 2-(Methylamino)ethanol?

The molecular formula of 2-(Methylamino)ethanol is C3H9NO and its molecular weight is 75.11 g/mol.

What does a 2-(Methylamino)ethanol label have to show?

Under CLP Annex VI the label for 2-(Methylamino)ethanol carries the pictograms Corrosion and Exclamation mark and the signal word is Danger.

Is 2-(Methylamino)ethanol flammable?

CLP Annex VI assigns 2-(Methylamino)ethanol no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it. The flash point reported for it is 76 °C (168.8 °F) (HSDB).

Is 2-(Methylamino)ethanol a carcinogen?

CLP Annex VI records no harmonised carcinogenicity classification for 2-(Methylamino)ethanol. Annex VI is a list of agreed classifications, not a list of substances found safe, so this is an absence of a classification rather than a clean bill of health.

What is the boiling point of 2-(Methylamino)ethanol?

The boiling point reported for 2-(Methylamino)ethanol is 1559 °C (2838.6 °F) (HSDB).

What is the melting point of 2-(Methylamino)ethanol?

The melting point reported for 2-(Methylamino)ethanol is -3 °C (26.6 °F) (HSDB).

How should 2-(Methylamino)ethanol be stored?

Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Storage class (TRGS 510): Combustible, corrosive hazardous materials. (Hazardous Substances Data Bank (HSDB))

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