Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

Build a label

Substance profile

3-Aminophenol

3-Aminophenol is white prisms from toluene or water.

CAS 591-27-5 C6H7NO 109.13 g/mol Warning

01 · Identification

What 3-Aminophenol is

3-Aminophenol is white prisms from toluene or water. Its molecular formula is C6H7NO and its molecular weight is 109.13 g/mol. It boils at 284 °C, melts at 123 °C, is soluble in water.

Under the GHS it carries the signal word Warning.

02 · Identifiers

3-Aminophenol identifiers and molecular data

3-Aminophenol CAS number and EC number

CAS number591-27-5
EC number209-711-2
Index number (CLP Annex VI)612-127-00-4

3-Aminophenol molecular formula and molecular weight

Molecular formulaC6H7NO
Molecular weight109.13 g/mol

03 · GHS classification

3-Aminophenol hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

3-Aminophenol pictograms and signal word

Signal wordWarning

3-Aminophenol hazard class and category

GHS hazard classes 3-Aminophenol falls into
Hazard class Category From code Pictogram
Acute toxicity - oral GHS chapter 3.1 Category 4 H302 GHS07
Acute toxicity - inhalation GHS chapter 3.1 Category 4 H332 GHS07
Hazardous to the aquatic environment - chronic GHS chapter 4.1 Category 2 H411 GHS09

3-Aminophenol hazard statements (H-codes)

Hazard statements assigned to 3-Aminophenol
CodeHazard statement
H332 Harmful if inhaled.
H302 Harmful if swallowed.
H411 Toxic to aquatic life with long lasting effects.

This page lists only the codes assigned to 3-Aminophenol. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for 3-Aminophenol

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of 3-Aminophenol issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

3-Aminophenol precautionary statements

CLP Annex VI assigns 10 precautionary statements to 3-Aminophenol. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Disposal

What has to happen to the contents and the empty container.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

3-Aminophenol name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български 3-аминофенол
Spanish español 3-Aminofenol
Czech čeština 3-aminofenol
Danish dansk 3-aminophenol
German Deutsch 3-Aminophenol
Estonian eesti 3-aminofenool
Greek ελληνικά 3-αμινοφαινόλη
English English 3-aminophenol
French français 3-aminophénol
Croatian hrvatski 3-aminofenol
Italian italiano 3-aminofenolo
Latvian latviešu 3-aminofenols
Lithuanian lietuvių 3-aminofenolis
Hungarian magyar 3-aminofenol
Maltese Malti 3-amminofenol
Dutch Nederlands 3-aminofenol
Polish polski 3-aminofenol
Portuguese português 3-aminofenol
Romanian română 3-aminofenol
Slovak slovenčina 3-aminofenol
Slovenian slovenščina 3-aminofenol
Finnish suomi 3-aminofenoli
Swedish svenska 3-aminofenol

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

3-Aminophenol GHS label elements

Everything CLP Annex VI fixes for 3-Aminophenol, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS07 Exclamation mark pictogramGHS09 Environment pictogram

Warning

3-Aminophenol

  • Harmful if inhaled.
  • Harmful if swallowed.
  • Toxic to aquatic life with long lasting effects.
  • Do not breathe dust/fume/gas/mist/vapours/spray.
  • Do not eat, drink or smoke when using this product.
  • Use only outdoors or in a well-ventilated area.
  • Avoid release to the environment.
  • IF SWALLOWED:
  • IF INHALED:
  • Call a POISON CENTER/doctor/ if you feel unwell.
  • Rinse mouth.
  • Collect spillage.
  • Dispose of contents/container to

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open 3-Aminophenol in the GHS label constructor →

07 · Health hazards

3-Aminophenol health hazards and exposure limits

3-Aminophenol hazard summary

A mutagen, reproductive effector, and moderate eye irritant; Causes spastic paralysis in lethal-dose feeding studies of rats; [RTECS] Emergency treatment: Methemoglobinemia; Irritating to skin and eyes; [HSDB] A skin, eye, and mucous membrane irritant; [CAMEO] Danger of skin sensitization; [MAK]

Source: Haz-Map, Information on Hazardous Chemicals and Occupational Diseases

08 · Physical and chemical properties

3-Aminophenol properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

3-Aminophenol boiling point

Property Value Conditions Source
Boiling point 284 °C (543.2 °F) at 760 mmHg DOE PAC
164 °C (327.2 °F) at 11 mmHg (reduced pressure) HSDB
163.89 °C (327 °F) at 11 mmHg (reduced pressure) CAMEO

3-Aminophenol melting point

Property Value Conditions Source
Melting point 123 °C (253.4 °F) HSDB
122 °C (251.6 °F) DOE PAC
124.44 °C (256 °F) range, midpoint shown CAMEO

3-Aminophenol density

Property Value Conditions Source
Density 1.195 g/cm³ HSDB

3-Aminophenol solubility

Property Value Conditions Source
Solubility Freely soluble in amyl alcohol and hot water; soluble in 40 parts cold water; very slightly soluble in petroleum ether HSDB
Soluble in toluene; very soluble in ethanol, ethyl ether; slightly soluble in benzene, dimethyl sulfoxide HSDB
Soluble in alkalies; slightly soluble in ligroin HSDB

3-Aminophenol vapor pressure

Property Value Conditions Source
Vapor pressure 0.0095 mmHg Haz-Map

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

09 · Handling and storage

3-Aminophenol storage and handling

3-Aminophenol storage conditions

Store in tightly closed containers in a cool, well-ventilated area. Aminophenols must be stored to avoid contact with strong oxidizers (such as chlorine, bromine, and fluorine), since violent reactions occur. /Aminophenols/

Source: Hazardous Substances Data Bank (HSDB)

3-Aminophenol incompatible materials

Strong oxidants. /Aminophenols/

Source: Hazardous Substances Data Bank (HSDB)

3-Aminophenol reactivity

M-AMINOPHENOL may react with strong oxidizers and mineral acids or bases. (NTP, 1992)

Source: CAMEO Chemicals

Planning storage for a mix of chemicals? Check 3-Aminophenol in the storage compatibility matrix →

10 · Questions

3-Aminophenol — frequently asked questions

What is the CAS number of 3-Aminophenol?

The CAS number of 3-Aminophenol is 591-27-5. Its EC number is 209-711-2.

What is the chemical formula of 3-Aminophenol?

The molecular formula of 3-Aminophenol is C6H7NO and its molecular weight is 109.13 g/mol.

What does a 3-Aminophenol label have to show?

Under CLP Annex VI the label for 3-Aminophenol carries the pictograms Exclamation mark and Environment and the signal word is Warning.

Is 3-Aminophenol flammable?

CLP Annex VI assigns 3-Aminophenol no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it.

Is 3-Aminophenol a carcinogen?

CLP Annex VI records no harmonised carcinogenicity classification for 3-Aminophenol. Annex VI is a list of agreed classifications, not a list of substances found safe, so this is an absence of a classification rather than a clean bill of health.

What is the boiling point of 3-Aminophenol?

The boiling point reported for 3-Aminophenol is 284 °C (543.2 °F), at 760 mmHg (DOE PAC).

What is the melting point of 3-Aminophenol?

The melting point reported for 3-Aminophenol is 123 °C (253.4 °F) (HSDB).

How should 3-Aminophenol be stored?

Store in tightly closed containers in a cool, well-ventilated area. Aminophenols must be stored to avoid contact with strong oxidizers (such as chlorine, bromine, and fluorine), since violent reactions occur. /Aminophenols/ (Hazardous Substances Data Bank (HSDB))

Get the free GHS / CLP / OSHA deadline calendar

Verified 2026–2029 compliance dates in one PDF — plus alerts when the rules change.