Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Benzoic acid, N-tert-butyl-N'-(4-chlorobenzoyl)hydrazide

Benzoic acid, N-tert-butyl-N'-(4-chlorobenzoyl)hydrazide is a white solid.

CAS 112226-61-6 C18H19ClN2O2 330.8 g/mol Warning

01 · Identification

What Benzoic acid, N-tert-butyl-N'… is

Benzoic acid, N-tert-butyl-N'-(4-chlorobenzoyl)hydrazide is a white solid. Its molecular formula is C18H19ClN2O2 and its molecular weight is 330.8 g/mol. It melts at 199 °C.

Under the GHS it carries the signal word Warning.

02 · Identifiers

Benzoic acid, N-tert-butyl-N'… identifiers and molecular data

Benzoic acid, N-tert-butyl-N'… CAS number and EC number

CAS number112226-61-6
EC number431-600-4
Index number (CLP Annex VI)616-138-00-5

Benzoic acid, N-tert-butyl-N'… molecular formula and molecular weight

Molecular formulaC18H19ClN2O2
Molecular weight330.8 g/mol

03 · GHS classification

Benzoic acid, N-tert-butyl-N'… hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Benzoic acid, N-tert-butyl-N'… pictograms and signal word

Signal wordWarning

Benzoic acid, N-tert-butyl-N'… hazard class and category

GHS hazard classes Benzoic acid, N-tert-butyl… falls into
Hazard class Category From code Pictogram
Skin sensitisation GHS chapter 3.4 Category 1 or 1A or 1B H317 GHS07
Hazardous to the aquatic environment - chronic GHS chapter 4.1 Category 2 H411 GHS09

Where two values are shown with “or”, the hazard statement is shared by more than one category or by more than one class, and the code alone does not say which. H272, for example, belongs to oxidising liquids and to oxidising solids — the physical state decides. The binding answer for a specific entry is in the CLP Annex VI table itself.

Benzoic acid, N-tert-butyl-N'… hazard statements (H-codes)

Hazard statements assigned to Benzoic acid, N-tert-butyl…
CodeHazard statement
H317 May cause an allergic skin reaction.
H411 Toxic to aquatic life with long lasting effects.

This page lists only the codes assigned to Benzoic acid, N-tert-butyl…. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for Benzoic acid, N-tert-butyl…

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of Benzoic acid, N-tert-b… issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

Benzoic acid, N-tert-butyl-N'… precautionary statements

CLP Annex VI assigns 8 precautionary statements to Benzoic acid, N-tert-butyl…. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Response

What to do once exposure, spillage or fire has already happened.

Disposal

What has to happen to the contents and the empty container.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

Benzoic acid, N-tert-butyl-N'… name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български бензоена киселина, N - трет -бутил- N′ -(4-хлоробензоил)хидразид
Spanish español Ácido benzoico, N - terc -butil- N '-(4-clorobenzoil)hidrazida
Czech čeština N - terc -butyl- N' -(4-chlorbenzoyl)hydrazid kyseliny benzoové
Danish dansk benzoesyre, N-tert -butyl- N' -(4-chlorbenzoyl)hydrazid
German Deutsch Benzoesäure N - tert -butyl- N '-(4- chlorbenzoyl)hydrazid
Estonian eesti bensoehappe N - tert -butüül- N '-(4-klorobensoüül)hüdrasiid
Greek ελληνικά N - tert -βουτυλο- N ′-(4-χλωροβενζοϋλ)υδραζίδιο του βενζοϊκού οξέος
English English benzoic acid, N - tert -butyl- N '-(4-chlorobenzoyl)hydrazide
French français acide benzoïque, N - tert -butyl- N '-(4-chlorobenzoyl)hydrazide
Croatian hrvatski benzojeva kiselina, N - tert -butil- N '-(4-klorbenzoil)hidrazid
Italian italiano N - terz -butil- N ’-(4-clorobenzoil)idrazide dell’acido benzoico
Latvian latviešu benzoskābe, N - terc -butil- N '-(4-hlorbenzoil)hidrazīds
Lithuanian lietuvių benzenkarboksirūgšties, N - trans -butil- N '-(4-chlorbenzoil)hidrazidas
Hungarian magyar benzoesav, N - terc -butil- N '-(4-klórbenzoil)hidrazid
Maltese Malti aċidu benżojku, N - tert -butil- N '-(4-klorobeżoil)idrażid
Dutch Nederlands benzoëzuur, N - tert -butyl- N '-(4-chloorbenzoyl)hydrazide
Polish polski N- tert -butylo-N'-(4-chlorobenzoilo)hydrazyd kwasu benzoesowego
Portuguese português N - terc -butil- N '-(4-clorobenzoil)hidrazida de ácido benzóico
Romanian română N - terț -butil- N '-(4-clorbenzoil)hidrazidă de acid benzoic
Slovak slovenčina N '-benzoyl- N '- terc -butyl-4-chlórbenzohydrazid
Slovenian slovenščina N - terc -butil- N '-(4-klorobenzoil)hidrazid benzojske kisline
Finnish suomi bentsoehappo, N - tert -butyyli- N ’-(4-klooribentsyyli)hydratsidi
Swedish svenska bensoesyra, N - tert -butyl- N '-(4-klorbensoyl)hydrazid

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

Benzoic acid, N-tert-butyl-N'… GHS label elements

Everything CLP Annex VI fixes for Benzoic acid, N-tert-butyl…, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS07 Exclamation mark pictogramGHS09 Environment pictogram

Warning

Benzoic acid, N-tert-butyl-N'…

  • May cause an allergic skin reaction.
  • Toxic to aquatic life with long lasting effects.
  • Avoid breathing dust/fume/gas/mist/vapours/spray.
  • Contaminated work clothing should not be allowed out of the workplace.
  • Avoid release to the environment.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • Get medical advice/attention.
  • If skin irritation or rash occurs:
  • Collect spillage.
  • Dispose of contents/container to

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open Benzoic acid, N-tert-butyl… in the GHS label constructor →

07 · Physical and chemical properties

Benzoic acid, N-tert-butyl-N'… properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

Benzoic acid, N-tert-butyl-N'… melting point

Property Value Conditions Source
Melting point 198.5 °C (389.3 °F) range, midpoint shown HSDB

Benzoic acid, N-tert-butyl-N'… density

Property Value Conditions Source
Density 0.38 g/cm³ HSDB

Benzoic acid, N-tert-butyl-N'… solubility

Property Value Conditions Source
Solubility In isopropanol 3.1%, cyclohexanone 15.4%, aromatic solvents 0.01-1% HSDB
In water, 12.3 ppm at 25 °C at 25 °C HSDB

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

08 · Handling and storage

Benzoic acid, N-tert-butyl-N'… storage and handling

Benzoic acid, N-tert-butyl-N'… storage conditions

Store in well-ventilated area. Store in a dry area. Store out of direct sunlight in a cool place. Do not store this material near food, feed or drinking water. Keep container tightly closed when not in use. The minimum recommended storage temperature for this material in 32 °F (0 °C). The maximum recommended storage temperature for this material is 110 °F (43 °C). /MACH 2 2SC Insecticide/

Source: Hazardous Substances Data Bank (HSDB)

Planning storage for a mix of chemicals? Check Benzoic acid, N-tert-buty… in the storage compatibility matrix →

09 · Questions

Benzoic acid, N-tert-butyl-N'… — frequently asked questions

What is the CAS number of Benzoic acid, N-tert-butyl-N'…?

The CAS number of Benzoic acid, N-tert-butyl-N'… is 112226-61-6. Its EC number is 431-600-4.

What is the chemical formula of Benzoic acid, N-tert-butyl-N'…?

The molecular formula of Benzoic acid, N-tert-butyl-N'… is C18H19ClN2O2 and its molecular weight is 330.8 g/mol.

What does a Benzoic acid, N-tert-butyl-N'… label have to show?

Under CLP Annex VI the label for Benzoic acid, N-tert-butyl-N'… carries the pictograms Exclamation mark and Environment and the signal word is Warning.

Is Benzoic acid, N-tert-butyl-N'… flammable?

CLP Annex VI assigns Benzoic acid, N-tert-butyl-N'… no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it.

Is Benzoic acid, N-tert-butyl-N'… a carcinogen?

CLP Annex VI records no harmonised carcinogenicity classification for Benzoic acid, N-tert-butyl-N'…. Annex VI is a list of agreed classifications, not a list of substances found safe, so this is an absence of a classification rather than a clean bill of health.

What is the melting point of Benzoic acid, N-tert-butyl-N'…?

The melting point reported for Benzoic acid, N-tert-butyl-N'… is 198.5 °C (389.3 °F), range, midpoint shown (HSDB).

How should Benzoic acid, N-tert-butyl-N'… be stored?

Store in well-ventilated area. Store in a dry area. Store out of direct sunlight in a cool place. Do not store this material near food, feed or drinking water. Keep container tightly closed when not in use. The minimum recommended storage temperature for this material in 32 °F (0 °C). The maximum recommended storage temperature for this material is 110 °F (43 °C). /MACH 2 2SC Insecticide/ (Hazardous Substances Data Bank (HSDB))

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