Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Bis-[4-(2,3-epoxipropoxi)phenyl]propane

Bis-[4-(2,3-epoxipropoxi)phenyl]propane is a sticky and is odorless.

CAS 1675-54-3 C21H24O4 340.4 g/mol Warning

01 · Identification

What Bis-[4-(2,3-epoxipropoxi)pheny… is

Bis-[4-(2,3-epoxipropoxi)phenyl]propane is a sticky and is odorless. Its molecular formula is C21H24O4 and its molecular weight is 340.4 g/mol. It melts at 10 °C.

Under the GHS it carries the signal word Warning.

02 · Identifiers

Bis-[4-(2,3-epoxipropoxi)pheny… identifiers and molecular data

Bis-[4-(2,3-epoxipropoxi)pheny… CAS number and EC number

CAS number1675-54-3
EC number216-823-5
Index number (CLP Annex VI)603-073-00-2

Bis-[4-(2,3-epoxipropoxi)pheny… molecular formula and molecular weight

Molecular formulaC21H24O4
Molecular weight340.4 g/mol

03 · GHS classification

Bis-[4-(2,3-epoxipropoxi)pheny… hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Bis-[4-(2,3-epoxipropoxi)pheny… pictograms and signal word

Signal wordWarning

Bis-[4-(2,3-epoxipropoxi)pheny… hazard class and category

GHS hazard classes Bis-[4-(2,3-epoxipropoxi)p… falls into
Hazard class Category From code Pictogram
Skin corrosion/irritation GHS chapter 3.2 Category 2 H315 GHS07
Serious eye damage/eye irritation GHS chapter 3.3 Category 2A H319 GHS07
Skin sensitisation GHS chapter 3.4 Category 1 or 1A or 1B H317 GHS07

Where two values are shown with “or”, the hazard statement is shared by more than one category or by more than one class, and the code alone does not say which. H272, for example, belongs to oxidising liquids and to oxidising solids — the physical state decides. The binding answer for a specific entry is in the CLP Annex VI table itself.

Bis-[4-(2,3-epoxipropoxi)pheny… hazard statements (H-codes)

Hazard statements assigned to Bis-[4-(2,3-epoxipropoxi)p…
CodeHazard statement
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H317 May cause an allergic skin reaction.

This page lists only the codes assigned to Bis-[4-(2,3-epoxipropoxi)p…. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for Bis-[4-(2,3-epoxipropoxi)p…

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of Bis-[4-(2,3-epoxipropo… issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

Bis-[4-(2,3-epoxipropoxi)pheny… precautionary statements

CLP Annex VI assigns 12 precautionary statements to Bis-[4-(2,3-epoxipropoxi)p…. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

Bis-[4-(2,3-epoxipropoxi)pheny… name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български бис[4-(2,3-епоксипропокси)фенил]пропан
Spanish español Bis-[4-(2,3-epoxipropoxi)fenil]propano
Czech čeština bis[4-(2,3-epoxypropoxy)fenyl]propan
Danish dansk bisphenol-A-diglycidylether 2,2-bis(p-(2,3-epoxipropoxi)phenyl]propan
German Deutsch Bis-[4-(2,3-epoxipropoxi)phenyl]propan 4,4'-Methylen-diphenyldiglycidyletherBisphenol-A-diglycidylether
Estonian eesti bis[4-(2,3-epoksüpropoksü)fenüül]propaan
Greek ελληνικά δις[4-(2,3-εποξυπροποξυ)φαινυλο]προπάνιο
English English bis-[4-(2,3-epoxipropoxi)phenyl]propane
French français bis-[4-(2,3-époxypropoxy)phényl]propane
Croatian hrvatski bis[4-(2,3-epoksipropoksi)fenil]propan
Italian italiano 2,2-bis-[4-(2,3-epossipropossi)fenil]-propano
Latvian latviešu bis-[4-(2,3-epoksipropoksi)fenil]propāns
Lithuanian lietuvių bis-[4-(2,3-epoksipropoksi)felil]propanas
Hungarian magyar bisz-[4-(2,3-epoxipropoxi)fenil]propán
Maltese Malti bis-[4-(2,3-epossipropossi)fenil]propan
Dutch Nederlands bis-[4-(2,3-epoxypropoxy)fenyl]propaan
Polish polski 2,2-bis[4-(2,3-epoksypropoksy)fenylo]propan
Portuguese português bis-[4-(2,3-epoxipropoxi)fenil]propano
Romanian română bis-[4-(2,3-epoxipropoxi)fenil]propan
Slovak slovenčina 2,2-bis[4-(oxiranylmetoxy)fenyl]propán
Slovenian slovenščina bis-[4-(2,3-epoksipropoksi)fenil]propan
Finnish suomi bis-[4-(2,3-epoksipropoksi)fenyyli]propaani
Swedish svenska bis-[4-(2,3-epoxipropoxi)fenyl]propan

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

Bis-[4-(2,3-epoxipropoxi)pheny… GHS label elements

Everything CLP Annex VI fixes for Bis-[4-(2,3-epoxipropoxi)p…, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS07 Exclamation mark pictogram

Warning

Bis-[4-(2,3-epoxipropoxi)pheny…

  • Causes skin irritation.
  • Causes serious eye irritation.
  • May cause an allergic skin reaction.
  • Avoid breathing dust/fume/gas/mist/vapours/spray.
  • Wash thoroughly after handling.
  • Contaminated work clothing should not be allowed out of the workplace.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • IF ON SKIN:
  • IF IN EYES:
  • Get medical advice/attention.
  • If skin irritation occurs:
  • If skin irritation or rash occurs:
  • If eye irritation persists:
  • Remove contact lenses, if present and easy to do. Continue rinsing.
  • Wash with plenty of water/

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open Bis-[4-(2,3-epoxipropoxi)p… in the GHS label constructor →

07 · Health hazards

Bis-[4-(2,3-epoxipropoxi)pheny… health hazards and exposure limits

Bis-[4-(2,3-epoxipropoxi)pheny… hazard summary

Allergic contact dermatitis reported in workers producing printed circuit boards and epoxy-impregnated fiberglass fabric; [Kanerva, p. 1759] Occupational contact urticaria has been reported; [Kanerva, p. 574] A skin and eye irritant; May cause skin sensitization; [ICSC] Occupational asthma reported in an epoxy resin handler; [Malo] Readily oxidized in air forming unstable peroxides that can spontaneously explode; [CAMEO] An eye irritant; Repeated skin contact causes dermatitis with smarting and reddening of the skin; [NTP] A skin and severe eye irritant; May cause skin sensitization; [Aldrich MSDS]

Source: Haz-Map, Information on Hazardous Chemicals and Occupational Diseases

Bis-[4-(2,3-epoxipropoxi)pheny… carcinogenicity classification

IARC classification Group 3 — Not classifiable as to its carcinogenicity to humans
IARC monographs Volume 47: (1989) Some Organic Solvents, Resin Monomers and Related Compounds, Pigments and Occupational Exposures in Paint Manufacture and Painting; Volume 71: (1999) Re-evaluation of Some Organic Chemicals, Hydrazine and Hydrogen Peroxide (Part 1, Part 2, Part 3)

Evaluation: No epidemiological data relevant to the carcinogenicity of bisphenol A diglycidyl ether were available. There is limited evidence in experimental animals for the carcinogenicity of bisphenol A diglycidyl ether. Overall evaluation: Bisphenol A diglycidyl ether is not classifiable as to its carcinogenicity to humans (Group 3).

Source: Hazardous Substances Data Bank (HSDB)

An IARC group and a CLP classification answer different questions. IARC judges whether the evidence for cancer in humans is strong enough; CLP Annex VI is the legally binding EU classification. A substance can carry one and not the other.

08 · Physical and chemical properties

Bis-[4-(2,3-epoxipropoxi)pheny… properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

Bis-[4-(2,3-epoxipropoxi)pheny… boiling point

Property Value Conditions Source
Boiling point Decomposes (NTP, 1992) decomposes CAMEO
decomposes decomposes OSHA

Bis-[4-(2,3-epoxipropoxi)pheny… melting point

Property Value Conditions Source
Melting point 10 °C (50 °F) range, midpoint shown HSDB

Bis-[4-(2,3-epoxipropoxi)pheny… density

Property Value Conditions Source
Density 1.16 g/cm³ HSDB
1.17 g/cm³ ICSC
1.16 g/cm³ at 20 °C CAMEO

Bis-[4-(2,3-epoxipropoxi)pheny… solubility

Property Value Conditions Source
Solubility less than 1 mg/mL at 67.1 °F (NTP, 1992) at 19.5 °C CAMEO

Bis-[4-(2,3-epoxipropoxi)pheny… vapor pressure

Property Value Conditions Source
Vapor pressure 1.1e-7 mmHg Haz-Map

Bis-[4-(2,3-epoxipropoxi)pheny… flash point

Property Value Conditions Source
Flash point 79.44 °C (175 °F) HSDB
79 °C (174.2 °F) ICSC
93.33 °C (200 °F) above this value CAMEO

Bis-[4-(2,3-epoxipropoxi)pheny… lower explosive limit (LEL)

Property Value Conditions Source
Lower explosive limit (LEL) Combustible HSDB
This substance can presumably form explosive peroxides. HSDB

Bis-[4-(2,3-epoxipropoxi)pheny… vapor density

Property Value Conditions Source
Vapor density 11.7 (air = 1) ICSC

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

09 · Handling and storage

Bis-[4-(2,3-epoxipropoxi)pheny… storage and handling

Bis-[4-(2,3-epoxipropoxi)pheny… safe storage

Separated from strong oxidants.

Source: ILO-WHO International Chemical Safety Cards (ICSCs)

Bis-[4-(2,3-epoxipropoxi)pheny… storage conditions

Safety cans should be used for storing flammable solvents. /Epoxy resins/

Source: Hazardous Substances Data Bank (HSDB)

Bis-[4-(2,3-epoxipropoxi)pheny… incompatible materials

Reacts with strong oxidants.

Source: Hazardous Substances Data Bank (HSDB)

Bis-[4-(2,3-epoxipropoxi)pheny… reactivity

BISPHENOL A DIGLYCIDYL ETHER, is not highly reactive. Ethers can act as bases. They form salts with strong acids and addition complexes with Lewis acids. The complex between diethyl ether and boron trifluoride is an example. Ethers may react violently with strong oxidizing agents. In other reactions, which typically involve the breaking of the carbon-oxygen bond, ethers are relatively inert.

Source: CAMEO Chemicals

Planning storage for a mix of chemicals? Check Bis-[4-(2,3-epoxipropoxi)… in the storage compatibility matrix →

10 · Questions

Bis-[4-(2,3-epoxipropoxi)pheny… — frequently asked questions

What is the CAS number of Bis-[4-(2,3-epoxipropoxi)pheny…?

The CAS number of Bis-[4-(2,3-epoxipropoxi)pheny… is 1675-54-3. Its EC number is 216-823-5.

What is the chemical formula of Bis-[4-(2,3-epoxipropoxi)pheny…?

The molecular formula of Bis-[4-(2,3-epoxipropoxi)pheny… is C21H24O4 and its molecular weight is 340.4 g/mol.

What does a Bis-[4-(2,3-epoxipropoxi)pheny… label have to show?

Under CLP Annex VI the label for Bis-[4-(2,3-epoxipropoxi)pheny… carries the pictogram Exclamation mark and the signal word is Warning.

Is Bis-[4-(2,3-epoxipropoxi)pheny… flammable?

CLP Annex VI assigns Bis-[4-(2,3-epoxipropoxi)pheny… no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it. The flash point reported for it is 79.44 °C (175 °F) (HSDB).

Is Bis-[4-(2,3-epoxipropoxi)pheny… a carcinogen?

CLP Annex VI records no harmonised carcinogenicity classification for Bis-[4-(2,3-epoxipropoxi)pheny…. Annex VI is a list of agreed classifications, not a list of substances found safe, so this is an absence of a classification rather than a clean bill of health. IARC places it in Group 3: not classifiable as to its carcinogenicity to humans.

What is the boiling point of Bis-[4-(2,3-epoxipropoxi)pheny…?

The boiling point reported for Bis-[4-(2,3-epoxipropoxi)pheny… is Decomposes (NTP, 1992), decomposes (CAMEO).

What is the melting point of Bis-[4-(2,3-epoxipropoxi)pheny…?

The melting point reported for Bis-[4-(2,3-epoxipropoxi)pheny… is 10 °C (50 °F), range, midpoint shown (HSDB).

How should Bis-[4-(2,3-epoxipropoxi)pheny… be stored?

Safety cans should be used for storing flammable solvents. /Epoxy resins/ (Hazardous Substances Data Bank (HSDB))

Nearby

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