Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Cinerin I

Cinerin I is a viscous liquid.

CAS 25402-06-6 Warning

01 · Identification

What Cinerin I is

Cinerin I is a viscous liquid.

Under the GHS it carries the signal word Warning.

02 · Identifiers

Cinerin I identifiers and molecular data

Cinerin I CAS number and EC number

CAS number25402-06-6
EC number246-948-0
Index number (CLP Annex VI)613-025-00-2

Other names for Cinerin I

  • 3-(but-2-enyl)-2-methyl-4-oxocyclopent-2-enyl 2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropanecarboxylate

03 · GHS classification

Cinerin I hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Cinerin I pictograms and signal word

Signal wordWarning

Cinerin I hazard class and category

GHS hazard classes Cinerin I falls into
Hazard class Category From code Pictogram
Acute toxicity - oral GHS chapter 3.1 Category 4 H302 GHS07
Hazardous to the aquatic environment - acute GHS chapter 4.1 Category 1 H400 GHS09
Hazardous to the aquatic environment - chronic GHS chapter 4.1 Category 1 H410 GHS09

Cinerin I hazard statements (H-codes)

Hazard statements assigned to Cinerin I
CodeHazard statement
H302 Harmful if swallowed.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.

This page lists only the codes assigned to Cinerin I. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for Cinerin I

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of Cinerin I issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

Cinerin I precautionary statements

CLP Annex VI assigns 7 precautionary statements to Cinerin I. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Prevention

What to do before and during handling so the hazard never happens.

Disposal

What has to happen to the contents and the empty container.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

Cinerin I name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български цинерин I 3-(бут-2-енил)-2-метил-4-оксоциклопент-2-енилов 2,2-диметил-3-(2-метилпроп-1-енил)циклопропанкарбоксилат
Spanish español Cinerina I 2,2-dimetil-3-(2-metilprop-1-enil)ciclopropanocarboxilato de 3-(but-2-enil)-2-metil-4- oxociclopent-2-enilo
Czech čeština cinerin I 3-(but-2-en-1-yl)-2-methyl-4-oxocyklopent-2-en-1-yl-[2,2-dimethyl-3-(2-methylprop-1-en-1-yl)cyklopropan-1-karboxylát]
Danish dansk cinerin I 3-(but-2-enyl)-2-methyl-4- oxocyclopent-2-enyl 2,2- dimethyl-3-(2-methylprop-1- enyl)cyclopropanecarboxylate
German Deutsch Cinerin I 3-(But-2-enyl)-2-methyl-4-oxocyclopent-2-enyl-2,2- dimethyl-3-(2-methylprop-1-enyl)cyclopropancarboxylat
Estonian eesti tsineriin I 3-(but-2-enüül)-2-metüül-4-oksotsüklopent-2-enüül-2,2-dimetüül-3-(2-metüülprop-1-enüül)tsüklopropaankarboksülaat
Greek ελληνικά κινερίνη Ι 2,2-διμεθυλο-3-(2-μεθυλοπροπ-1-ενυλο)κυκλοπροπανοκαρβοξυλικός 3-(βουτ-2-ενυλο)-2-μεθυλ-4-οξοκυκλοπεντ-2-ενυλεστέρας
English English cinerin I 3-(but-2-enyl)-2-methyl-4- oxocyclopent-2-enyl 2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropanecarboxylate
French français cinérine I 2,2-diméthyl-3-(2-méthylprop-1-ényl)cyclopropanecarboxylatede 3-(but-2-ényl)-2-méthyl-4-oxocyclopent-2-ényle
Croatian hrvatski cinerin I 3-(but-2-enil)-2-metil-4-oksociklopent-2-enil 2,2-dimetil-3-(2-metilprop-1-enil)ciklopropankarboksilat
Italian italiano cinerina I 2,2-dimetil-3-(2-metilprop-1-enil)ciclopropancarbossilato di 3-(but-2-enil)-2-metil-4-ossociclopent-2-enile
Latvian latviešu cinerīns I 3-(but-2-enil)-2-metil-4-oksociklopent-2-enila 2,2-dimetil-3-(2-metilprop-1-enil)ciklopropānkarboksilāts
Lithuanian lietuvių cinerinas I 3-(but-2-enil)-2-metil-4-oksociklopent-2-enil-2,2-dimetil-3-(2-metilprop-1-enil)ciklopropankarboksilatas
Hungarian magyar cinerin I 3-(but-2-enil)-2-metil-4-oxociklopent-2-enil-2,2-dimetil-3-(2-metilprop-1-enil)ciklopropánkarboxilát
Maltese Malti cinerin I 3-(but-2-enil)-2-metil-4- ossoċiklopent-2-enil 2,2-dimetil-3-(2-metilprop-1-enil)ċiklopropanekarbossilat
Dutch Nederlands cinerine I 3-(but-2-enyl)-2-methyl-4-oxocyclopent-2-enyl-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropaancarboxylaat
Polish polski cyneryna I (1 R ,3 R )-2,2-dimetylo-3-(2-metyloprop-1-en-1-ylo)cyklopropanokarboksylan ( Z )-( S )-3-(but-2-en-1-ylo)-2-metylo-4-oksocyklopent-2-en-1-ylu
Portuguese português cinerina I 2,2-dimetil-3-(2-metilprop-1-enil)ciclopropanocarboxilato de 3-(but-2-enil)-2-metil-4-oxociclopent-2-enilo
Romanian română cinerină I 2,2-dimetil-3-(2-metilprop-1-enil) ciclopropan carboxilat de 3-(but-2-enil)-2-metil-4-oxociclo-pent-2-enil
Slovak slovenčina cinerín I O -[3-(but-2-én-1-yl)-2-metyl-4-oxocyklopent-2-enyl]-2,2-dimetyl-3-(2-metylprop-1-enyl)cyklopropánkarboxylát
Slovenian slovenščina cinerin I 3-(but-2-enil)-2-metil-4-oksociklopent-2-enil 2,2-dimetil-3-(2-metilprop-1-enil)ciklopropankarboksilat
Finnish suomi sineriini I 3-(but-2-enyyli)-2-metyyli-4-oksosyklopent-2-enyyli-2,2- dimetyyli-3-(2-metyyliprop-1-enyyli)syklopropaanikarboksylaatti
Swedish svenska cinerin I 3-(but-2-enyl)-2-metyl-4-oxocyklopent-2-enyl-2,2-dimetyl-3-(2-metylprop-1-enyl)cyklopropankarboxylat

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

Cinerin I GHS label elements

Everything CLP Annex VI fixes for Cinerin I, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS07 Exclamation mark pictogramGHS09 Environment pictogram

Warning

Cinerin I

  • Harmful if swallowed.
  • Very toxic to aquatic life.
  • Very toxic to aquatic life with long lasting effects.
  • Do not eat, drink or smoke when using this product.
  • Avoid release to the environment.
  • IF SWALLOWED:
  • Call a POISON CENTER/doctor/ if you feel unwell.
  • Rinse mouth.
  • Collect spillage.
  • Dispose of contents/container to

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open Cinerin I in the GHS label constructor →

07 · Health hazards

Cinerin I health hazards and exposure limits

Cinerin I hazard summary

May cause allergic reactions; [Merck Index] See Pyrethrum.

Source: Haz-Map, Information on Hazardous Chemicals and Occupational Diseases

Cinerin I occupational exposure limits

US occupational exposure limits reported for Cinerin I. PEL is enforceable (OSHA), REL is a recommendation (NIOSH), IDLH is the concentration at which escape becomes impossible without injury.
Limit Value Source
IDLH 5000 mg/cu m /Pyrethrum/ Hazardous Substances Data Bank (HSDB)

These are United States values. The European Union sets its own indicative and binding limits, and the figure that applies at a given workplace is the one in the local regulation — not the one shown here.

08 · Physical and chemical properties

Cinerin I properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

Cinerin I boiling point

Property Value Conditions Source
Boiling point 200 °C (392 °F) at 0.1 mmHg (reduced pressure) HSDB
137 °C (278.6 °F) range, midpoint shown, at 0.008 mmHg (reduced pressure) HSDB

Cinerin I solubility

Property Value Conditions Source
Solubility Practically insoluble in water HSDB
Soluble in alcohol, petroleum ether, kerosene, carbon tetrachloride, ethylene dichloride, nitromethane HSDB

Cinerin I corrosivity

Property Value Conditions Source
Corrosivity Non-corrosive HSDB

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

09 · Handling and storage

Cinerin I storage and handling

Cinerin I storage conditions

Pyrethrins with piperonyl butoxide topical preparations should be stored in well-closed containers at a temperature less than 40 °C, preferably between 15-30 °C. /Pyrethrins/

Source: Hazardous Substances Data Bank (HSDB)

Cinerin I incompatible materials

... Incompatible with lime and ordinary soaps because acids & alkalies speed up processes of hydrolysis. /Pyrethrins/

Source: Hazardous Substances Data Bank (HSDB)

Planning storage for a mix of chemicals? Check Cinerin I in the storage compatibility matrix →

10 · Questions

Cinerin I — frequently asked questions

What is the CAS number of Cinerin I?

The CAS number of Cinerin I is 25402-06-6. Its EC number is 246-948-0.

What does a Cinerin I label have to show?

Under CLP Annex VI the label for Cinerin I carries the pictograms Exclamation mark and Environment and the signal word is Warning.

Is Cinerin I flammable?

CLP Annex VI assigns Cinerin I no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it.

Is Cinerin I a carcinogen?

CLP Annex VI records no harmonised carcinogenicity classification for Cinerin I. Annex VI is a list of agreed classifications, not a list of substances found safe, so this is an absence of a classification rather than a clean bill of health.

What is the boiling point of Cinerin I?

The boiling point reported for Cinerin I is 200 °C (392 °F), at 0.1 mmHg (reduced pressure) (HSDB).

How should Cinerin I be stored?

Pyrethrins with piperonyl butoxide topical preparations should be stored in well-closed containers at a temperature less than 40 °C, preferably between 15-30 °C. /Pyrethrins/ (Hazardous Substances Data Bank (HSDB))

Nearby

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