Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Clomazone

Clomazone is a clear colorless to light brown viscous liquid.

CAS 81777-89-1 C12H14ClNO2 239.7 g/mol Warning

01 · Identification

What Clomazone is

Clomazone is a clear colorless to light brown viscous liquid. Its molecular formula is C12H14ClNO2 and its molecular weight is 239.7 g/mol. It boils at 275 °C, melts at 25 °C.

Under the GHS it carries the signal word Warning.

02 · Identifiers

Clomazone identifiers and molecular data

Clomazone CAS number and EC number

CAS number81777-89-1
Index number (CLP Annex VI)613-340-00-5

Clomazone molecular formula and molecular weight

Molecular formulaC12H14ClNO2
Molecular weight239.7 g/mol

Other names for Clomazone

  • clomazone (ISO)
  • 2-(2-chlorobenzyl)-4,4-dimethyl-1,2-oxazolidin-3-one

03 · GHS classification

Clomazone hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Clomazone pictograms and signal word

Signal wordWarning

Clomazone hazard class and category

GHS hazard classes Clomazone falls into
Hazard class Category From code Pictogram
Acute toxicity - oral GHS chapter 3.1 Category 4 H302 GHS07
Acute toxicity - inhalation GHS chapter 3.1 Category 4 H332 GHS07
Hazardous to the aquatic environment - acute GHS chapter 4.1 Category 1 H400 GHS09
Hazardous to the aquatic environment - chronic GHS chapter 4.1 Category 1 H410 GHS09

Clomazone hazard statements (H-codes)

Hazard statements assigned to Clomazone
CodeHazard statement
H332 Harmful if inhaled.
H302 Harmful if swallowed.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.

This page lists only the codes assigned to Clomazone. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for Clomazone

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of Clomazone issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

Clomazone precautionary statements

CLP Annex VI assigns 10 precautionary statements to Clomazone. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Disposal

What has to happen to the contents and the empty container.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

Clomazone name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български кломазон (ISO) 4,4-диметил-2-(2-хлоробензил)-1,2-оксазолидин-3-он
Spanish español Clomazona (ISO) 2-(2-clorobencil)-4,4-dimetil-1,2-oxazolidin-3-ona
Czech čeština klomazon (ISO) 2-(2-chlorbenzyl)-4,4-dimethyl-1,2-oxazolidin-3-on
Danish dansk clomazon (ISO) 2-(2-chlorbenzyl)-4,4-dimethyl-1,2-oxazolidin-3-on
German Deutsch Clomazon (ISO) 2-(2-Chlorbenzyl)-4,4-dimethyl-1,2-oxazolidin-3-on
Estonian eesti klomasoon (ISO) 2-(2-klorobensüül)-4,4-dimetüül-1,2-oksasolidiin-3-oon
Greek ελληνικά clomazone (ISO) 2-(2-χλωροβενζυλο)-4,4-διμεθυλο-1,2-οξαζολιδιν-3-όνη
English English clomazone (ISO) 2-(2-chlorobenzyl)-4,4-dimethyl-1,2-oxazolidin-3-one
French français clomazone (ISO) 2- (2-chlorobenzyl) -4,4-diméthyl-1,2-oxazolidin-3-one
Croatian hrvatski klomazon (ISO) 2-(2-klorbenzil)-4,4-dimetil-1,2-oksazolidin-3-on
Italian italiano clomazone (ISO) 2-(2-clorobenzil)-4,4-dimetil-1,2-ossazolidin-3-one
Latvian latviešu klomazons (ISO) 2-(2-hlorbenzil)-4,4-dimetil-1,2-oksazolidīn-3-ons
Lithuanian lietuvių klomazonas (ISO) 2-(2-chlorbenzil)-4,4-dimetil-1,2-oksazolidin-3-onas
Hungarian magyar klomazon (ISO) 2-(2-klórbenzil)-4,4-dimetil-1,2-oxazolidin-3-on
Maltese Malti klomażon (ISO) 2-(2-klorobenżil)-4,4-dimetil-1,2-ossażolidin-3-on
Dutch Nederlands clomazon (ISO) 2-(2-chloorbenzyl)-4,4-dimethyl-1,2-oxazolidine-3-on
Polish polski chlomazon (ISO) 2-(2-chlorobenzylo)-4,4-dimetylo-1,2-oksazolidyn-3-on
Portuguese português clomazona (ISO) 2-(2-clorobenzil)-4,4-dimetil-1,2-oxazolidin-3-ona
Romanian română clomazon (ISO) 2-(2-clorbenzil)-4,4-dimetil-1,2-oxazolidin-3-onă
Slovak slovenčina klomazón (ISO), 2-(2-chlórbenzyl)-4,4-dimetyl-1,2-oxazolidín-3-ón
Slovenian slovenščina klomazon (ISO) 2-(2-klorobenzil)-4,4-dimetil-1,2-oksazolidin-3-on
Finnish suomi klomatsoni (ISO) 2-(2-klooribentsyyli)-4,4-dimetyyli-1,2-oksatsolidiini-3-oni
Swedish svenska klomazon (ISO) 2-(2-klorbensyl)-4,4-dimetyl-1,2-oxazolidin-3-on

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

Clomazone GHS label elements

Everything CLP Annex VI fixes for Clomazone, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS07 Exclamation mark pictogramGHS09 Environment pictogram

Warning

Clomazone

  • Harmful if inhaled.
  • Harmful if swallowed.
  • Very toxic to aquatic life.
  • Very toxic to aquatic life with long lasting effects.
  • Do not breathe dust/fume/gas/mist/vapours/spray.
  • Do not eat, drink or smoke when using this product.
  • Use only outdoors or in a well-ventilated area.
  • Avoid release to the environment.
  • IF SWALLOWED:
  • IF INHALED:
  • Call a POISON CENTER/doctor/ if you feel unwell.
  • Rinse mouth.
  • Collect spillage.
  • Dispose of contents/container to

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open Clomazone in the GHS label constructor →

07 · Health hazards

Clomazone health hazards and exposure limits

Clomazone hazard summary

A minor skin irritant; [MSDSonline]

Source: Haz-Map, Information on Hazardous Chemicals and Occupational Diseases

Clomazone carcinogenicity classification

Cancer Classification: Not Likely to be Carcinogenic to Humans

Source: Hazardous Substances Data Bank (HSDB)

An IARC group and a CLP classification answer different questions. IARC judges whether the evidence for cancer in humans is strong enough; CLP Annex VI is the legally binding EU classification. A substance can carry one and not the other.

08 · Physical and chemical properties

Clomazone properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

Clomazone boiling point

Property Value Conditions Source
Boiling point 275 °C (527 °F) HSDB

Clomazone melting point

Property Value Conditions Source
Melting point 25 °C (77 °F) HSDB

Clomazone density

Property Value Conditions Source
Density 1.192 g/cm³ at 25 °C HSDB

Clomazone solubility

Property Value Conditions Source
Solubility Readily soluble in acetonitrile, hexane, dioxane, xylene HSDB
Miscible in acetone, chloroform, cyclohexanone, methylene chloride, methanol, toluene, heptane, and DMF HSDB
In water, 1,100 ppm at 25 °C at 25 °C HSDB

Clomazone vapor pressure

Property Value Conditions Source
Vapor pressure 0.00014 mmHg OSHA
0.00014 mmHg at 25 °C HSDB

Clomazone flash point

Property Value Conditions Source
Flash point 41.94 °C (107.5 °F) range, midpoint shown HSDB
72.5 °C (162.5 °F) range, midpoint shown HSDB

Clomazone vapor density

Property Value Conditions Source
Vapor density 1.192 (air = 1) at 25 °C OSHA

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

09 · Handling and storage

Clomazone storage and handling

Clomazone storage conditions

Store in a cool, well-ventilated, secure area, out of the reach of children and animals.

Source: Hazardous Substances Data Bank (HSDB)

Planning storage for a mix of chemicals? Check Clomazone in the storage compatibility matrix →

10 · Questions

Clomazone — frequently asked questions

What is the CAS number of Clomazone?

The CAS number of Clomazone is 81777-89-1.

What is the chemical formula of Clomazone?

The molecular formula of Clomazone is C12H14ClNO2 and its molecular weight is 239.7 g/mol.

What does a Clomazone label have to show?

Under CLP Annex VI the label for Clomazone carries the pictograms Exclamation mark and Environment and the signal word is Warning.

Is Clomazone flammable?

CLP Annex VI assigns Clomazone no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it. The flash point reported for it is 41.94 °C (107.5 °F), range, midpoint shown (HSDB).

Is Clomazone a carcinogen?

CLP Annex VI records no harmonised carcinogenicity classification for Clomazone. Annex VI is a list of agreed classifications, not a list of substances found safe, so this is an absence of a classification rather than a clean bill of health.

What is the boiling point of Clomazone?

The boiling point reported for Clomazone is 275 °C (527 °F) (HSDB).

What is the melting point of Clomazone?

The melting point reported for Clomazone is 25 °C (77 °F) (HSDB).

How should Clomazone be stored?

Store in a cool, well-ventilated, secure area, out of the reach of children and animals. (Hazardous Substances Data Bank (HSDB))

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