Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Copper chloride

Copper chloride: dry Powder; Liquid.

CAS 7758-89-6 ClCu 99 g/mol Warning

01 · Identification

What Copper chloride is

Copper chloride: dry Powder; Liquid. Its molecular formula is ClCu and its molecular weight is 99 g/mol. It boils at 1490 °C, melts at 423 °C.

Under the GHS it carries the signal word Warning.

02 · Identifiers

Copper chloride identifiers and molecular data

Copper chloride CAS number and EC number

CAS number7758-89-6
EC number231-842-9
Index number (CLP Annex VI)029-001-00-4

Copper chloride molecular formula and molecular weight

Molecular formulaClCu
Molecular weight99 g/mol

Other names for Copper chloride

  • copper (I) chloride
  • cuprous chloride

03 · GHS classification

Copper chloride hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Copper chloride pictograms and signal word

Signal wordWarning

Copper chloride hazard class and category

GHS hazard classes Copper chloride falls into
Hazard class Category From code Pictogram
Acute toxicity - oral GHS chapter 3.1 Category 4 H302 GHS07
Hazardous to the aquatic environment - acute GHS chapter 4.1 Category 1 H400 GHS09
Hazardous to the aquatic environment - chronic GHS chapter 4.1 Category 1 H410 GHS09

Copper chloride hazard statements (H-codes)

Hazard statements assigned to Copper chloride
CodeHazard statement
H302 Harmful if swallowed.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.

This page lists only the codes assigned to Copper chloride. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for Copper chloride

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of Copper chloride issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

Copper chloride precautionary statements

CLP Annex VI assigns 7 precautionary statements to Copper chloride. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Prevention

What to do before and during handling so the hazard never happens.

Disposal

What has to happen to the contents and the empty container.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

Copper chloride name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български меден хлорид меден(I) хлоридкупрохлорид
Spanish español Cloruro de cobre cloruro de cobre (I)cloruro cuproso
Czech čeština chlorid měďný
Danish dansk kobberchlorid kobber(I)chlorid
German Deutsch Kupferchlorid Kupfer(I)-chlorid
Estonian eesti vaskkloriid vask(I)kloriid
Greek ελληνικά χλωριούχος χαλκός χλωριούχος χαλκός(I)χλωριούχος υποχαλκός
English English copper chloride copper (I) chloridecuprous chloride
French français chlorure de cuivre chlorure de cuivre (I)chlorure cuivreux
Croatian hrvatski bakrov klorid bakrov(I) kloridbakreni klorid
Italian italiano cloruro di rame
Latvian latviešu vara hlorīds vara(I) hlorīdsvara(II) hlorīds
Lithuanian lietuvių vario chloridas vario (I) chloridasvario (II) chloridas
Hungarian magyar réz-klorid réz(I)-klorid
Maltese Malti klorur tar-ram klorur tar-ram (I)klorur kupruż
Dutch Nederlands koperchloride koper(I)chloridekopermonochloride
Polish polski chlorek miedzi(I) chlorek miedziawy
Portuguese português cloreto de cobre cloreto de cobre(I)cloreto cuproso
Romanian română clorură de cupru clorură de cupru (I)clorură cuproasă
Slovak slovenčina chlorid meďný chlorid meďný chlorid meďný
Slovenian slovenščina bakrov klorid bakrov(I) klorid
Finnish suomi kuparikloridi kupari(I)kloridikuparimonokloridi
Swedish svenska kopparklorid koppar(I)kloridkopparmonoklorid

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

Copper chloride GHS label elements

Everything CLP Annex VI fixes for Copper chloride, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS07 Exclamation mark pictogramGHS09 Environment pictogram

Warning

Copper chloride

  • Harmful if swallowed.
  • Very toxic to aquatic life.
  • Very toxic to aquatic life with long lasting effects.
  • Do not eat, drink or smoke when using this product.
  • Avoid release to the environment.
  • IF SWALLOWED:
  • Call a POISON CENTER/doctor/ if you feel unwell.
  • Rinse mouth.
  • Collect spillage.
  • Dispose of contents/container to

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open Copper chloride in the GHS label constructor →

07 · Health hazards

Copper chloride health hazards and exposure limits

Copper chloride hazard summary

Harmful if swallowed; [MSDSonline] Acute copper poisoning after ingestion can cause liver injury, methemoglobinemia, and hemolytic anemia. Acute renal failure may result, secondary to massive hemoglobinuria. [Goldfrank, p. 1259] Classified as category I for skin and eye irritation (corrosive); Category II for acute oral and dermal exposure (moderate toxicity); Category III for acute inhalation exposure (low toxicity); Positive results in dermal sensitization studies; [Reference #2] May cause irritation; Harmful by ingestion; [Alfa Aesar MSDS] See Copper.

Source: Haz-Map, Information on Hazardous Chemicals and Occupational Diseases

Copper chloride occupational exposure limits

US occupational exposure limits reported for Copper chloride. PEL is enforceable (OSHA), REL is a recommendation (NIOSH), IDLH is the concentration at which escape becomes impossible without injury.
Limit Value Source
PEL 1.0 [mg/m3], as Cu Haz-Map, Information on Hazardous Chemicals and Occupational Diseases
IDLH 100.0 [mg/m3], as Cu Haz-Map, Information on Hazardous Chemicals and Occupational Diseases

These are United States values. The European Union sets its own indicative and binding limits, and the figure that applies at a given workplace is the one in the local regulation — not the one shown here.

08 · Physical and chemical properties

Copper chloride properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

Copper chloride boiling point

Property Value Conditions Source
Boiling point 1490 °C (2714 °F) at 760 mmHg DOE PAC

Copper chloride melting point

Property Value Conditions Source
Melting point 423 °C (793.4 °F) DOE PAC

Copper chloride density

Property Value Conditions Source
Density 4.14 g/cm³ at 25 °C DOE PAC

Copper chloride vapor pressure

Property Value Conditions Source
Vapor pressure 1 mmHg at 546 °C DOE PAC

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

09 · Transport

Copper chloride UN number and transport classification

Transport classification is a separate system from the GHS classification above. It decides how a package is marked and how a load may be carried; it does not follow from the workplace label, and the workplace label does not follow from it. The entries below are linked by CAS number, never by name.

Copper chloride under UN 2802 — shipping name, class and packing group

Europe · ADR 2025, Table A

Proper shipping name (3.1.2) Class Classification code PG Labels (column 5)
COPPER CHLORIDE 8 C2 III
  • ADR label model 8 — Corrosive substance
8

Source: ADR 2025, Table A of Chapter 3.2 · ECE/TRANS/352 Vol. I (UNECE). Class 8 is “Corrosive substances” (ADR 2.1.1.1).

Proper shipping name (column 2) Class or division PG Labels (column 6)
Copper chloride 8 III
  • US DOT CORROSIVE label (§172.442)
8

Source: 49 CFR 172.101 Hazardous Materials Table · eCFR, revision 2026-08-03. Class 8 is “Corrosive material” (49 CFR 173.2).

Full UN 2802 entry — special provisions, packing instructions, quantity limits and the orange plate →

10 · Questions

Copper chloride — frequently asked questions

What is the CAS number of Copper chloride?

The CAS number of Copper chloride is 7758-89-6. Its EC number is 231-842-9.

What is the chemical formula of Copper chloride?

The molecular formula of Copper chloride is ClCu and its molecular weight is 99 g/mol.

What does a Copper chloride label have to show?

Under CLP Annex VI the label for Copper chloride carries the pictograms Exclamation mark and Environment and the signal word is Warning.

Is Copper chloride flammable?

CLP Annex VI assigns Copper chloride no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it.

Is Copper chloride a carcinogen?

CLP Annex VI records no harmonised carcinogenicity classification for Copper chloride. Annex VI is a list of agreed classifications, not a list of substances found safe, so this is an absence of a classification rather than a clean bill of health.

What is the exposure limit for Copper chloride?

The US occupational exposure limit reported for Copper chloride is 1.0 [mg/m3], as Cu (Haz-Map, Information on Hazardous Chemicals and Occupational Diseases). Limits differ by country: the EU sets its own indicative and binding values, and the figure that applies at a given workplace is the one in the local regulation.

What is the boiling point of Copper chloride?

The boiling point reported for Copper chloride is 1490 °C (2714 °F), at 760 mmHg (DOE PAC).

What is the melting point of Copper chloride?

The melting point reported for Copper chloride is 423 °C (793.4 °F) (DOE PAC).

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