Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Copper(II) carbonate--copper(II) hydroxide (1:1)

Copper(II) carbonate--copper(II) hydroxide (1:1) is a substance with a harmonised classification under EU CLP.

CAS 12069-69-1 Warning

01 · Identification

What Copper(II) carbonate--copper(I… is

Copper(II) carbonate--copper(II) hydroxide (1:1) is a substance with a harmonised classification under EU CLP.

Under the GHS it carries the signal word Warning.

02 · Identifiers

Copper(II) carbonate--copper(I… identifiers and molecular data

Copper(II) carbonate--copper(I… CAS number and EC number

CAS number12069-69-1
EC number235-113-6
Index number (CLP Annex VI)029-020-00-8

03 · GHS classification

Copper(II) carbonate--copper(I… hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Copper(II) carbonate--copper(I… pictograms and signal word

Signal wordWarning

Copper(II) carbonate--copper(I… hazard class and category

GHS hazard classes Copper(II) carbonate--copp… falls into
Hazard class Category From code Pictogram
Acute toxicity - oral GHS chapter 3.1 Category 4 H302 GHS07
Acute toxicity - inhalation GHS chapter 3.1 Category 4 H332 GHS07
Serious eye damage/eye irritation GHS chapter 3.3 Category 2A H319 GHS07
Hazardous to the aquatic environment - acute GHS chapter 4.1 Category 1 H400 GHS09
Hazardous to the aquatic environment - chronic GHS chapter 4.1 Category 1 H410 GHS09

Copper(II) carbonate--copper(I… hazard statements (H-codes)

Hazard statements assigned to Copper(II) carbonate--copp…
CodeHazard statement
H332 Harmful if inhaled.
H302 Harmful if swallowed.
H319 Causes serious eye irritation.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.

This page lists only the codes assigned to Copper(II) carbonate--copp…. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for Copper(II) carbonate--copp…

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of Copper(II) carbonate… issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

Copper(II) carbonate--copper(I… precautionary statements

CLP Annex VI assigns 16 precautionary statements to Copper(II) carbonate--copp…. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Disposal

What has to happen to the contents and the empty container.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

Copper(II) carbonate--copper(I… name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български меден(II) карбонат -- меден(II) хидроксид (1:1)
Spanish español Carbonato de cobre (II)--hidróxido de cobre (II) (1:1)
Czech čeština uhličitan měďnatý – hydroxid měďnatý (1:1)
Danish dansk kobber(II)carbonat—kobber(II)hydroxid (1:1)
German Deutsch Kupfer(II)-carbonat — Kupfer(II)-hydroxid (1:1)
Estonian eesti vask(II)karbonaat – vask(II)hüdroksiid (1: 1)
Greek ελληνικά ανθρακικός χαλκός (II) — υδροξείδιο του χαλκού (II) (1:1)
English English copper(II) carbonate—copper(II) hydroxide (1:1)
French français carbonate de cuivre(II) -- hydroxyde de cuivre(II) (1:1)
Croatian hrvatski bakar(II) karbonat--bakar(II) hidroksid (1:1)
Italian italiano carbonato di rame(II)-idrossido di rame (II) (1:1)
Latvian latviešu vara(II) karbonāts--vara(II) hidroksīds (1:1)
Lithuanian lietuvių vario (II) karbonatas – vario (II) hidroksidas (1:1)
Hungarian magyar réz(II)-karbonát – réz(II)-hidroxid (1:1)
Maltese Malti idrossidu tal-karbonat tar-ram(II) tar-ram(II) (1:1)
Dutch Nederlands koper(II)carbonaat--koper(II)hydroxide (1:1)
Polish polski węglan miedzi(II) –wodorotlenek miedzi(II) (1:1)
Portuguese português carbonato de cobre (II)-hidróxido de cobre (II) (1:1)
Romanian română amestecul (1:1) de carbonat de cupru (II)--hidroxid de cupru (II)
Slovak slovenčina uhličitan (II) meďnatý – hydroxid (II) meďnatý, komplex (1:1)
Slovenian slovenščina bakrov (II) karbonat--bakrov (II) hidroksid (1:1)
Finnish suomi kupari(II)karbonaatti--kupari(II)hydroksidi (1:1)
Swedish svenska koppar(II)karbonat--koppar(II)hydroxid (1:1)

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

Copper(II) carbonate--copper(I… GHS label elements

Everything CLP Annex VI fixes for Copper(II) carbonate--copp…, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS07 Exclamation mark pictogramGHS09 Environment pictogram

Warning

Copper(II) carbonate--copper(I…

  • Harmful if inhaled.
  • Harmful if swallowed.
  • Causes serious eye irritation.
  • Very toxic to aquatic life.
  • Very toxic to aquatic life with long lasting effects.
  • Do not breathe dust/fume/gas/mist/vapours/spray.
  • Wash thoroughly after handling.
  • Do not eat, drink or smoke when using this product.
  • Use only outdoors or in a well-ventilated area.
  • Avoid release to the environment.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • IF SWALLOWED:
  • IF INHALED:
  • IF IN EYES:
  • Call a POISON CENTER/doctor/ if you feel unwell.
  • Get medical advice/attention.
  • Rinse mouth.
  • If eye irritation persists:
  • Remove contact lenses, if present and easy to do. Continue rinsing.
  • Collect spillage.
  • Dispose of contents/container to

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open Copper(II) carbonate--copp… in the GHS label constructor →

07 · Questions

Copper(II) carbonate--copper(I… — frequently asked questions

What is the CAS number of Copper(II) carbonate--copper(I…?

The CAS number of Copper(II) carbonate--copper(I… is 12069-69-1. Its EC number is 235-113-6.

What does a Copper(II) carbonate--copper(I… label have to show?

Under CLP Annex VI the label for Copper(II) carbonate--copper(I… carries the pictograms Exclamation mark and Environment and the signal word is Warning.

Is Copper(II) carbonate--copper(I… flammable?

CLP Annex VI assigns Copper(II) carbonate--copper(I… no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it.

Is Copper(II) carbonate--copper(I… a carcinogen?

CLP Annex VI records no harmonised carcinogenicity classification for Copper(II) carbonate--copper(I…. Annex VI is a list of agreed classifications, not a list of substances found safe, so this is an absence of a classification rather than a clean bill of health.

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