Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Cuprous thiocyanate

Cuprous thiocyanate: dry Powder.

CAS 1111-67-7 CCuNS 121.63 g/mol Warning

01 · Identification

What Cuprous thiocyanate is

Cuprous thiocyanate: dry Powder. Its molecular formula is CCuNS and its molecular weight is 121.63 g/mol.

Under the GHS it carries the signal word Warning.

02 · Identifiers

Cuprous thiocyanate identifiers and molecular data

Cuprous thiocyanate CAS number and EC number

CAS number1111-67-7
EC number214-183-1
Index number (CLP Annex VI)029-015-00-0

Cuprous thiocyanate molecular formula and molecular weight

Molecular formulaCCuNS
Molecular weight121.63 g/mol

Other names for Cuprous thiocyanate

  • copper thiocyanate

03 · GHS classification

Cuprous thiocyanate hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Cuprous thiocyanate pictograms and signal word

Signal wordWarning

Cuprous thiocyanate hazard class and category

GHS hazard classes Cuprous thiocyanate falls into
Hazard class Category From code Pictogram
Hazardous to the aquatic environment - acute GHS chapter 4.1 Category 1 H400 GHS09
Hazardous to the aquatic environment - chronic GHS chapter 4.1 Category 1 H410 GHS09

Cuprous thiocyanate hazard statements (H-codes)

Hazard statements assigned to Cuprous thiocyanate
CodeHazard statement
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.

Cuprous thiocyanate supplemental EU statements (EUH)

EU-specific statements assigned to Cuprous thiocyanate. They exist only in CLP and have no counterpart in UN GHS.
CodeStatement
EUH032 Contact with acids liberates very toxic gas.

This page lists only the codes assigned to Cuprous thiocyanate. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for Cuprous thiocyanate

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of Cuprous thiocyanate issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

Cuprous thiocyanate precautionary statements

CLP Annex VI assigns 3 precautionary statements to Cuprous thiocyanate. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Prevention

What to do before and during handling so the hazard never happens.

Response

What to do once exposure, spillage or fire has already happened.

Disposal

What has to happen to the contents and the empty container.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

Cuprous thiocyanate name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български меден тиоцианат
Spanish español Tiocianato de cobre
Czech čeština thiokyanatan měďný
Danish dansk kobberthiocyanat
German Deutsch Kupferthiocyanat
Estonian eesti vasktiotsüanaat
Greek ελληνικά θειοκυανικός χαλκός
English English copper thiocyanate
French français thiocyanate de cuivre
Croatian hrvatski bakrov tiocianat
Italian italiano tiocianato di rame
Latvian latviešu vara tiocianāts
Lithuanian lietuvių vario tiocianatas
Hungarian magyar réz-tiocianát
Maltese Malti tijoċjanat tar-ram
Dutch Nederlands koperthiocyanaat
Polish polski tiocyjanian miedzi
Portuguese português tiocianato de cobre
Romanian română tiocianat de cupru
Slovak slovenčina tiokyanatan meďný
Slovenian slovenščina bakrov tiocianat
Finnish suomi kuparitiosyanaatti
Swedish svenska koppartiocyanat

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

Cuprous thiocyanate GHS label elements

Everything CLP Annex VI fixes for Cuprous thiocyanate, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS09 Environment pictogram

Warning

Cuprous thiocyanate

  • Very toxic to aquatic life.
  • Very toxic to aquatic life with long lasting effects.
  • Contact with acids liberates very toxic gas.
  • Avoid release to the environment.
  • Collect spillage.
  • Dispose of contents/container to

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open Cuprous thiocyanate in the GHS label constructor →

07 · Health hazards

Cuprous thiocyanate health hazards and exposure limits

Cuprous thiocyanate hazard summary

Not a skin or eye irritant in rabbits; Not sensitizing in guinea pig maximization study; [ECHA - Proposal for Harmonised Classification and Labelling] May cause irritation; Harmful by ingestion and skin absorption; Toxic by inhalation; [Sigma-Aldrich MSDS] See Potassium thiocyanate and Sodium thiocyanate. See Copper(II) acetate.

Source: Haz-Map, Information on Hazardous Chemicals and Occupational Diseases

Cuprous thiocyanate occupational exposure limits

US occupational exposure limits reported for Cuprous thiocyanate. PEL is enforceable (OSHA), REL is a recommendation (NIOSH), IDLH is the concentration at which escape becomes impossible without injury.
Limit Value Source
PEL 1.0 [mg/m3], as Cu Haz-Map, Information on Hazardous Chemicals and Occupational Diseases
IDLH 100.0 [mg/m3], as Cu Haz-Map, Information on Hazardous Chemicals and Occupational Diseases

These are United States values. The European Union sets its own indicative and binding limits, and the figure that applies at a given workplace is the one in the local regulation — not the one shown here.

08 · Questions

Cuprous thiocyanate — frequently asked questions

What is the CAS number of Cuprous thiocyanate?

The CAS number of Cuprous thiocyanate is 1111-67-7. Its EC number is 214-183-1.

What is the chemical formula of Cuprous thiocyanate?

The molecular formula of Cuprous thiocyanate is CCuNS and its molecular weight is 121.63 g/mol.

What does a Cuprous thiocyanate label have to show?

Under CLP Annex VI the label for Cuprous thiocyanate carries the pictogram Environment and the signal word is Warning.

Is Cuprous thiocyanate flammable?

CLP Annex VI assigns Cuprous thiocyanate no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it.

Is Cuprous thiocyanate a carcinogen?

CLP Annex VI records no harmonised carcinogenicity classification for Cuprous thiocyanate. Annex VI is a list of agreed classifications, not a list of substances found safe, so this is an absence of a classification rather than a clean bill of health.

What is the exposure limit for Cuprous thiocyanate?

The US occupational exposure limit reported for Cuprous thiocyanate is 1.0 [mg/m3], as Cu (Haz-Map, Information on Hazardous Chemicals and Occupational Diseases). Limits differ by country: the EU sets its own indicative and binding values, and the figure that applies at a given workplace is the one in the local regulation.

Nearby

Substances next to Cuprous thiocyanate

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