Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Dicyclohexylamine

Dicyclohexylamine is a colorless liquid with a faint fishy odor.

CAS 101-83-7 Danger

01 · Identification

What Dicyclohexylamine is

Dicyclohexylamine is a colorless liquid with a faint fishy odor. It boils at 256 °C, melts at -0.1 °C, is soluble in water.

Under the GHS it carries the signal word Danger. It is classed as corrosives.

02 · Identifiers

Dicyclohexylamine identifiers and molecular data

Dicyclohexylamine CAS number and EC number

CAS number101-83-7
EC number202-980-7
Index number (CLP Annex VI)612-066-00-3

Dicyclohexylamine molecular formula and molecular weight

Chemical class Corrosives

03 · GHS classification

Dicyclohexylamine hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Dicyclohexylamine pictograms and signal word

Signal wordDanger

Dicyclohexylamine hazard class and category

GHS hazard classes Dicyclohexylamine falls into
Hazard class Category From code Pictogram
Acute toxicity - oral GHS chapter 3.1 Category 4 H302 GHS07
Skin corrosion/irritation GHS chapter 3.2 Category 1A or 1B or 1C H314 GHS05
Hazardous to the aquatic environment - acute GHS chapter 4.1 Category 1 H400 GHS09
Hazardous to the aquatic environment - chronic GHS chapter 4.1 Category 1 H410 GHS09

Where two values are shown with “or”, the hazard statement is shared by more than one category or by more than one class, and the code alone does not say which. H272, for example, belongs to oxidising liquids and to oxidising solids — the physical state decides. The binding answer for a specific entry is in the CLP Annex VI table itself.

Dicyclohexylamine hazard statements (H-codes)

Hazard statements assigned to Dicyclohexylamine
CodeHazard statement
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.

This page lists only the codes assigned to Dicyclohexylamine. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for Dicyclohexylamine

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of Dicyclohexylamine issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

Dicyclohexylamine precautionary statements

CLP Annex VI assigns 11 precautionary statements to Dicyclohexylamine. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Disposal

What has to happen to the contents and the empty container.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

Dicyclohexylamine name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български дициклохексиламин
Spanish español Diciclohexilamina
Czech čeština dicyklohexylamin
Danish dansk dicyclohexylamin
German Deutsch Dicyclohexylamin
Estonian eesti ditsükloheksüülamiin
Greek ελληνικά δικυκλοεξυλαμίνη
English English dicyclohexylamine
French français dicyclohexylamine
Croatian hrvatski dicikloheksilamin
Italian italiano dicicloesilamina
Latvian latviešu dicikloheksilamīns
Lithuanian lietuvių dicikloheksilaminas
Hungarian magyar diciklohexilamin
Maltese Malti diċikloessilammina
Dutch Nederlands dicyclohexylamine
Polish polski dicykloheksyloamina
Portuguese português diciclo-hexilamina
Romanian română diciclohexilamină
Slovak slovenčina dicyklohexylamín
Slovenian slovenščina dicikloheksilamin
Finnish suomi disykloheksyyliamiini
Swedish svenska dicyklohexylamin

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

Dicyclohexylamine GHS label elements

Everything CLP Annex VI fixes for Dicyclohexylamine, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS05 Corrosion pictogramGHS07 Exclamation mark pictogramGHS09 Environment pictogram

Danger

Dicyclohexylamine

  • Harmful if swallowed.
  • Causes severe skin burns and eye damage.
  • Very toxic to aquatic life.
  • Very toxic to aquatic life with long lasting effects.
  • Do not breathe dust/fume/gas/mist/vapours/spray.
  • Do not eat, drink or smoke when using this product.
  • Avoid release to the environment.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • IF SWALLOWED:
  • Immediately call a POISON CENTER/doctor/
  • Call a POISON CENTER/doctor/ if you feel unwell.
  • Rinse mouth.
  • Do NOT induce vomiting.
  • Collect spillage.
  • Dispose of contents/container to

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open Dicyclohexylamine in the GHS label constructor →

07 · Health hazards

Dicyclohexylamine health hazards and exposure limits

Dicyclohexylamine hazard summary

A corrosive substance that can cause injury to the skin, eyes, and respiratory tract; May cause pulmonary edema; [ICSC] Possible skin sensitizer; [Merck Index] Toxic by ingestion, inhalation, and skin contact; [CAMEO] A corrosive substance that can cause injury to the skin, eyes, and respiratory tract; Inhalation may cause chemical pneumonitis; No sensitizing effects known; [MSDSonline] Danger of cutaneous absorption; [MAK]

Source: Haz-Map, Information on Hazardous Chemicals and Occupational Diseases

08 · Physical and chemical properties

Dicyclohexylamine properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

Dicyclohexylamine boiling point

Property Value Conditions Source
Boiling point 255.8 °C (492.4 °F) at 760 mmHg HSDB
255.78 °C (492.4 °F) at 760 mmHg CAMEO
256 °C (492.8 °F) ICSC

Dicyclohexylamine melting point

Property Value Conditions Source
Melting point -0.1 °C (31.8 °F) HSDB
20 °C (68 °F) CAMEO

Dicyclohexylamine density

Property Value Conditions Source
Density 0.9 g/cm³ ICSC
0.9104 g/cm³ at 25 °C HSDB
0.916 g/cm³ range, midpoint shown, at 15 °C CAMEO

Dicyclohexylamine solubility

Property Value Conditions Source
Solubility SPARINGLY SOL IN WATER; SOL IN USUAL ORGANIC SOLVENTS; MISCIBLE WITH CYCLOHEXYLAMINE HSDB
Soluble in ethanol, ether, benzene. HSDB
Soluble in oxygenated solvents. HSDB

Dicyclohexylamine vapor pressure

Property Value Conditions Source
Vapor pressure 12.001 mmHg at 37.7 °C ICSC
0.03 mmHg Haz-Map
3.38X10-2 at 25 °C at 25 °C HSDB

Dicyclohexylamine flash point

Property Value Conditions Source
Flash point 105 °C (221 °F) ICSC
98.89 °C (210 °F) above this value CAMEO

Dicyclohexylamine autoignition temperature

Property Value Conditions Source
Autoignition temperature 255 °C (491 °F) ICSC

Dicyclohexylamine lower explosive limit (LEL)

Property Value Conditions Source
Lower explosive limit (LEL) 0.9 % by volume ICSC

Dicyclohexylamine upper explosive limit (UEL)

Property Value Conditions Source
Upper explosive limit (UEL) 6.9 % by volume ICSC

Dicyclohexylamine vapor density

Property Value Conditions Source
Vapor density 6.25 (air = 1) HSDB
6.25 (air = 1) at 20 °C CAMEO

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

09 · Fire and explosion

Dicyclohexylamine fire and explosion behaviour

These are descriptions rather than measured values, so they are kept out of the table above and quoted here with the source that reported them.

Dicyclohexylamine fire potential

COMBUSTIBLE WHEN EXPOSED TO HEAT OR FLAME; CAN REACT WITH OXIDIZING MATERIALS.

Source: Hazardous Substances Data Bank (HSDB)

10 · Handling and storage

Dicyclohexylamine storage and handling

Dicyclohexylamine safe storage

Separated from strong oxidants, strong acids and food and feedstuffs.

Source: ILO-WHO International Chemical Safety Cards (ICSCs)

Dicyclohexylamine reactivity

DICYCLOHEXYLAMINE reacts with oxidizing agents. Forms crystalline salts with many N-protected amino acids (NTP, 1992). Neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.

Source: CAMEO Chemicals

Planning storage for a mix of chemicals? Check Dicyclohexylamine in the storage compatibility matrix →

11 · Transport

Dicyclohexylamine UN number and transport classification

Transport classification is a separate system from the GHS classification above. It decides how a package is marked and how a load may be carried; it does not follow from the workplace label, and the workplace label does not follow from it. The entries below are linked by CAS number, never by name.

Dicyclohexylamine under UN 2565 — shipping name, class and packing group

Europe · ADR 2025, Table A

Proper shipping name (3.1.2) Class Classification code PG Labels (column 5)
DICYCLOHEXYLAMINE 8 C7 III
  • ADR label model 8 — Corrosive substance
8

Source: ADR 2025, Table A of Chapter 3.2 · ECE/TRANS/352 Vol. I (UNECE). Class 8 is “Corrosive substances” (ADR 2.1.1.1).

Proper shipping name (column 2) Class or division PG Labels (column 6)
Dicyclohexylamine 8 III
  • US DOT CORROSIVE label (§172.442)
8

Source: 49 CFR 172.101 Hazardous Materials Table · eCFR, revision 2026-08-03. Class 8 is “Corrosive material” (49 CFR 173.2).

Full UN 2565 entry — special provisions, packing instructions, quantity limits and the orange plate →

12 · Questions

Dicyclohexylamine — frequently asked questions

What is the CAS number of Dicyclohexylamine?

The CAS number of Dicyclohexylamine is 101-83-7. Its EC number is 202-980-7.

What does a Dicyclohexylamine label have to show?

Under CLP Annex VI the label for Dicyclohexylamine carries the pictograms Corrosion, Exclamation mark and Environment and the signal word is Danger.

Is Dicyclohexylamine flammable?

CLP Annex VI assigns Dicyclohexylamine no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it. The flash point reported for it is 105 °C (221 °F) (ICSC).

Is Dicyclohexylamine a carcinogen?

CLP Annex VI records no harmonised carcinogenicity classification for Dicyclohexylamine. Annex VI is a list of agreed classifications, not a list of substances found safe, so this is an absence of a classification rather than a clean bill of health.

What is the boiling point of Dicyclohexylamine?

The boiling point reported for Dicyclohexylamine is 255.8 °C (492.4 °F), at 760 mmHg (HSDB).

What is the melting point of Dicyclohexylamine?

The melting point reported for Dicyclohexylamine is -0.1 °C (31.8 °F) (HSDB).

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