Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Dipropylamine

Dipropylamine is a colorless liquid with an ammonia odor.

CAS 142-84-7 Danger

01 · Identification

What Dipropylamine is

Dipropylamine is a colorless liquid with an ammonia odor. It boils at 109 °C, melts at -63 °C.

Under the GHS it carries the signal word Danger. It is classed as flammable agents - 3rd degree.

02 · Identifiers

Dipropylamine identifiers and molecular data

Dipropylamine CAS number and EC number

CAS number142-84-7
EC number205-565-9
Index number (CLP Annex VI)612-048-00-5

Dipropylamine molecular formula and molecular weight

Chemical class Flammable agents - 3rd degree

03 · GHS classification

Dipropylamine hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Dipropylamine pictograms and signal word

Signal wordDanger

Dipropylamine hazard class and category

GHS hazard classes Dipropylamine falls into
Hazard class Category From code Pictogram
Flammable liquids GHS chapter 2.6 Category 2 H225 GHS02
Acute toxicity - oral GHS chapter 3.1 Category 4 H302 GHS07
Acute toxicity - dermal GHS chapter 3.1 Category 4 H312 GHS07
Acute toxicity - inhalation GHS chapter 3.1 Category 4 H332 GHS07
Skin corrosion/irritation GHS chapter 3.2 Category 1A or 1B or 1C H314 GHS05

Where two values are shown with “or”, the hazard statement is shared by more than one category or by more than one class, and the code alone does not say which. H272, for example, belongs to oxidising liquids and to oxidising solids — the physical state decides. The binding answer for a specific entry is in the CLP Annex VI table itself.

Dipropylamine hazard statements (H-codes)

Hazard statements assigned to Dipropylamine
CodeHazard statement
H225 Highly flammable liquid and vapour.
H332 Harmful if inhaled.
H312 Harmful in contact with skin.
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.

This page lists only the codes assigned to Dipropylamine. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for Dipropylamine

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of Dipropylamine issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

Dipropylamine precautionary statements

CLP Annex VI assigns 17 precautionary statements to Dipropylamine. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Storage

How the container has to be kept between uses.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

Dipropylamine name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български дипропиламин
Spanish español Dipropilamina
Czech čeština dipropylamin
Danish dansk dipropylamin
German Deutsch Dipropylamin Di-n-propylamin
Estonian eesti dipropüülamiin
Greek ελληνικά διπροπυλαμίνη
English English dipropylamine
French français dipropylamine
Croatian hrvatski dipropilamin
Italian italiano dipropilamina
Latvian latviešu dipropilamīns
Lithuanian lietuvių dipropilaminas
Hungarian magyar dipropilamin
Maltese Malti dipropilammina
Dutch Nederlands dipropylamine
Polish polski dipropyloamina
Portuguese português dipropilamina
Romanian română dipropilamină
Slovak slovenčina dipropylamín
Slovenian slovenščina dipropilamin
Finnish suomi dipropyyliamiini
Swedish svenska dipropylamin

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

Dipropylamine GHS label elements

Everything CLP Annex VI fixes for Dipropylamine, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS02 Flame pictogramGHS05 Corrosion pictogramGHS07 Exclamation mark pictogram

Danger

Dipropylamine

  • Highly flammable liquid and vapour.
  • Harmful if inhaled.
  • Harmful in contact with skin.
  • Harmful if swallowed.
  • Causes severe skin burns and eye damage.
  • Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
  • Keep container tightly closed.
  • Use explosion-proof [electrical/ventilating/lighting/…] equipment.
  • Use only non-sparking tools.
  • Do not breathe dust/fume/gas/mist/vapours/spray.
  • Do not eat, drink or smoke when using this product.
  • Use only outdoors or in a well-ventilated area.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • IF SWALLOWED:
  • IF ON SKIN:
  • IF INHALED:
  • Immediately call a POISON CENTER/doctor/
  • Call a POISON CENTER/doctor/ if you feel unwell.
  • Rinse mouth.
  • Do NOT induce vomiting.
  • Wash with plenty of water/
  • Store in a well-ventilated place.

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open Dipropylamine in the GHS label constructor →

07 · Health hazards

Dipropylamine health hazards and exposure limits

Dipropylamine hazard summary

Highly corrosive to skin; [Quick CPC] Two of six rats died after exposure to 1000 ppm for four minutes. High inhalation exposure can cause pulmonary edema. [HSDB] Possesses pharmacologic activity as a dopamine agonist; [REPROTOX] A strong respiratory tract irritant that may cause pulmonary edema; A severe skin and eye irritant (may cause corneal edema); Degenerative changes to kidney and liver observed in chronic studies of rats and rabbits; [CHRIS]

Source: Haz-Map, Information on Hazardous Chemicals and Occupational Diseases

08 · Physical and chemical properties

Dipropylamine properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

Dipropylamine boiling point

Property Value Conditions Source
Boiling point 109.3 °C (228.7 °F) HSDB
109.39 °C (228.9 °F) at 760 mmHg CAMEO
109.3 °C (228.7 °F) at 760 mmHg DOE PAC

Dipropylamine melting point

Property Value Conditions Source
Melting point -63 °C (-81.4 °F) HSDB
-39.61 °C (-39.3 °F) CAMEO

Dipropylamine density

Property Value Conditions Source
Density 0.7309 g/cm³ HSDB
0.738 g/cm³ at 20 °C HSDB

Dipropylamine solubility

Property Value Conditions Source
Solubility Miscible in ether, very soluble in acetone, soluble in ethanol HSDB
Soluble (>=10 mg/ml) (NTP, 1992) CAMEO
In water, 3.51X10+4 mg/L at 25 °C at 25 °C HSDB

Dipropylamine vapor pressure

Property Value Conditions Source
Vapor pressure 20.1 mmHg at 25 °C HSDB
7.5 mmHg at 6 °C DOE PAC
20.1 mmHg Haz-Map

Dipropylamine flash point

Property Value Conditions Source
Flash point 17.22 °C (63 °F) HSDB
7 °C (44.6 °F) closed cup HSDB
7.22 °C (45 °F) CAMEO

Dipropylamine autoignition temperature

Property Value Conditions Source
Autoignition temperature 298.89 °C (570 °F) HSDB

Dipropylamine vapor density

Property Value Conditions Source
Vapor density 3.49 (air = 1) HSDB
3.5 (air = 1) CAMEO

Dipropylamine odor threshold

Property Value Conditions Source
Odor threshold Odor low= 0.4140 mg/ cu m; Odor high= 0.8280 mg/ cu m HSDB
Odor Threshold Low: 0.1 [ppm] Haz-Map
Odor Threshold High: 0.2 [ppm] Haz-Map

Dipropylamine critical temperature and pressure

Property Value Conditions Source
Critical temperature and pressure 282.65 °C (540.8 °F) HSDB

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

09 · Fire and explosion

Dipropylamine fire and explosion behaviour

These are descriptions rather than measured values, so they are kept out of the table above and quoted here with the source that reported them.

Dipropylamine fire potential

Forms explosive mixture with air.

Source: Hazardous Substances Data Bank (HSDB)

10 · Handling and storage

Dipropylamine storage and handling

Dipropylamine storage conditions

Before entering a confined space where this chemical may be present, check to make sure that an explosive concentration does not exist. Store in Tightly closed containers in a cool, well-ventilated area. Metal containers involving the transfer of this chemical should be grounded and bonded. Where possible, automatically pump liquid from drums or other storage containers to process containers. Drums must be equipped with self-closing valves, pressure vacuum bungs, and flame arresters. Use only non-sparking tools and equipment, especially when opening and closing containers of this chemical. Sources of ignition such as smoking and open flames are prohibited where this chemical is used, handled, or stored in a manner that could create a potential fire or explosion hazard. Wherever this chemical is used, handled, manufactured, or stored, use explosion-proof electrical equipment and fittings.

Source: Hazardous Substances Data Bank (HSDB)

Dipropylamine incompatible materials

Incompatible with acids, organic anhydrides, isocyanates, vinyl acetate, acrylates, substituted allyls, alkylene oxides, epichlorohydrin, ketones, aldehydes, alcohols, glycols, phenols, cresols, caprolactum solution. Attacks aluminum, copper, lead, tin, zinc, and their alloys.

Source: Hazardous Substances Data Bank (HSDB)

Dipropylamine reactivity

DIPROPYLAMINE neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.

Source: CAMEO Chemicals

Planning storage for a mix of chemicals? Check Dipropylamine in the storage compatibility matrix →

11 · Transport

Dipropylamine UN number and transport classification

Transport classification is a separate system from the GHS classification above. It decides how a package is marked and how a load may be carried; it does not follow from the workplace label, and the workplace label does not follow from it. The entries below are linked by CAS number, never by name.

Dipropylamine under UN 2383 — shipping name, class and packing group

Europe · ADR 2025, Table A

Proper shipping name (3.1.2) Class Classification code PG Labels (column 5)
DIPROPYLAMINE 3 FC II
  • ADR label model 3 — Flammable liquid
  • ADR label model 8 — Corrosive substance
3, 8

Source: ADR 2025, Table A of Chapter 3.2 · ECE/TRANS/352 Vol. I (UNECE). Class 3 is “Flammable liquids” (ADR 2.1.1.1).

Proper shipping name (column 2) Class or division PG Labels (column 6)
Dipropylamine 3 II
  • US DOT FLAMMABLE LIQUID label (§172.419)
  • US DOT CORROSIVE label (§172.442)
3, 8

Source: 49 CFR 172.101 Hazardous Materials Table · eCFR, revision 2026-08-03. Class 3 is “Flammable and combustible liquid” (49 CFR 173.2).

Full UN 2383 entry — special provisions, packing instructions, quantity limits and the orange plate →

12 · Questions

Dipropylamine — frequently asked questions

What is the CAS number of Dipropylamine?

The CAS number of Dipropylamine is 142-84-7. Its EC number is 205-565-9.

What does a Dipropylamine label have to show?

Under CLP Annex VI the label for Dipropylamine carries the pictograms Flame, Corrosion and Exclamation mark and the signal word is Danger.

Is Dipropylamine flammable?

Yes. CLP Annex VI assigns Dipropylamine H225 — highly flammable liquid and vapour. The flash point reported for it is 17.22 °C (63 °F) (HSDB).

Is Dipropylamine a carcinogen?

CLP Annex VI records no harmonised carcinogenicity classification for Dipropylamine. Annex VI is a list of agreed classifications, not a list of substances found safe, so this is an absence of a classification rather than a clean bill of health.

What is the boiling point of Dipropylamine?

The boiling point reported for Dipropylamine is 109.3 °C (228.7 °F) (HSDB).

What is the melting point of Dipropylamine?

The melting point reported for Dipropylamine is -63 °C (-81.4 °F) (HSDB).

How should Dipropylamine be stored?

CLP Annex VI assigns Dipropylamine the storage statement P403. Before entering a confined space where this chemical may be present, check to make sure that an explosive concentration does not exist. Store in Tightly closed containers in a cool, well-ventilated area. Metal containers involving the transfer of this chemical should be grounded and bonded. Where possible, automatically pump liquid from drums or other storage containers to process containers. Drums must be equipped with self-closing valves, pressure vacuum bungs, and flame arresters. Use only non-sparking tools and equipment, especially when opening and closing containers of this chemical. Sources of ignition such as smoking and open flames are prohibited where this chemical is used, handled, or stored in a manner that could create a potential fire or explosion hazard. Wherever this chemical is used, handled, manufactured, or stored, use explosion-proof electrical equipment and fittings. (Hazardous Substances Data Bank (HSDB))

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