Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Disulfoton

Disulfoton is a pure compound: yellow liquid with a characteristic, sulfur odor.

CAS 298-04-4 C8H19O2PS3 274.4 g/mol Danger

01 · Identification

What Disulfoton is

Disulfoton is a pure compound: yellow liquid with a characteristic, sulfur odor. Its molecular formula is C8H19O2PS3 and its molecular weight is 274.4 g/mol. It boils at 133 °C, melts at -25 °C, is miscible with water.

Under the GHS it carries the signal word Danger.

02 · Identifiers

Disulfoton identifiers and molecular data

Disulfoton CAS number and EC number

CAS number298-04-4
EC number206-054-3
Index number (CLP Annex VI)015-060-00-3

Disulfoton molecular formula and molecular weight

Molecular formulaC8H19O2PS3
Molecular weight274.4 g/mol

Other names for Disulfoton

  • disulfoton (ISO)
  • O,O-diethyl 2-ethylthioethyl phosphorodithioate

03 · GHS classification

Disulfoton hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Disulfoton pictograms and signal word

Signal wordDanger

Disulfoton hazard class and category

GHS hazard classes Disulfoton falls into
Hazard class Category From code Pictogram
Acute toxicity - oral GHS chapter 3.1 Category 1 or 2 H300 GHS06
Acute toxicity - dermal GHS chapter 3.1 Category 1 or 2 H310 GHS06
Hazardous to the aquatic environment - acute GHS chapter 4.1 Category 1 H400 GHS09
Hazardous to the aquatic environment - chronic GHS chapter 4.1 Category 1 H410 GHS09

Where two values are shown with “or”, the hazard statement is shared by more than one category or by more than one class, and the code alone does not say which. H272, for example, belongs to oxidising liquids and to oxidising solids — the physical state decides. The binding answer for a specific entry is in the CLP Annex VI table itself.

Disulfoton hazard statements (H-codes)

Hazard statements assigned to Disulfoton
CodeHazard statement
H310 Fatal in contact with skin.
H300 Fatal if swallowed.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.

This page lists only the codes assigned to Disulfoton. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for Disulfoton

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of Disulfoton issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

Disulfoton precautionary statements

CLP Annex VI assigns 10 precautionary statements to Disulfoton. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Disposal

What has to happen to the contents and the empty container.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

Disulfoton name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български дисулфотон (ISO) O , O -диетилов 2-етилтиоетилов фосфородитиоат
Spanish español Disulfotón (ISO) fosforoditioato de O , O -dietilo y 2-etiltioetilo
Czech čeština disulfoton (ISO) O, O -diethyl- S -[2-(ethylsulfanyl)ethyl]-fosforodithioát
Danish dansk disulfoton (ISO) O, O- diethyl-2-ethylthioethyldithiophosphat
German Deutsch Disulfoton (ISO) O , O -Diethyl-2-ethylthioethylphosphorodithioat
Estonian eesti disulfotoon (ISO) O , O -dietüül-2-etüültioetüülfosforoditioaat
Greek ελληνικά disulfoton (δισουλφοτόνη) (ISO) διθειοφωσφορικό O , O -διαιθύλιο 2-αιθυλοθειοαιθύλιο
English English disulfoton (ISO) O , O -diethyl 2-ethylthioethyl phosphorodithioate
French français disulfoton (ISO) phosphorodithioate de O , O -diéthyle et de 2-éthylthioéthyle
Croatian hrvatski disulfoton (ISO) O , O -dietil-2-etil-tioetil-fosforoditioat
Italian italiano disulfoton (ISO) ditiofosfato di O, O-dietile e 2-etiltioetile
Latvian latviešu disulfotons (ISO) O , O -dieti-2-etiltioetilfosforditioāts
Lithuanian lietuvių disulfotonas (ISO) O , O -dietil-2-etiltioetilditiofosfatas
Hungarian magyar diszulfoton (ISO) O, O -dietil-2-etiltioetil-ditiofoszfát
Maltese Malti disulfoton (ISO) fosforoditijoat ta’ O , O -dietil 2-etiltijoetil
Dutch Nederlands disulfoton (ISO) O , O -diëthyl-2-ethylthioëthyldithiofosfaat
Polish polski disulfoton (ISO) ditiofosforan O , O -dietylu- S -2-(etylosulfanylo)etylu
Portuguese português dissulfotão (ISO) ditiofosfato de O , O -dietilo e de 2-etiltioetilo
Romanian română disulfoton (ISO) ditiofosfat de O, O -dietil și de 2-etiltioetil
Slovak slovenčina disulfotón (ISO) O, O -dietyl- S -[2-(etylsulfanyl)etyl]- fosforoditioát
Slovenian slovenščina disulfoton (ISO) O , O -dietil 2-etiltioetil fosforoditioat
Finnish suomi disulfotoni (ISO) O , O -dietyyli- S -2-etyylitioetyylifosforoditioaatti
Swedish svenska disulfoton (ISO) O , O -dietyl-2-etyltioetylfosforditioat

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

Disulfoton GHS label elements

Everything CLP Annex VI fixes for Disulfoton, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS06 Skull and crossbones pictogramGHS09 Environment pictogram

Danger

Disulfoton

  • Fatal in contact with skin.
  • Fatal if swallowed.
  • Very toxic to aquatic life.
  • Very toxic to aquatic life with long lasting effects.
  • Do not eat, drink or smoke when using this product.
  • Avoid release to the environment.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • IF SWALLOWED:
  • IF ON SKIN:
  • Immediately call a POISON CENTER/doctor/
  • Rinse mouth.
  • Wash with plenty of water/
  • Collect spillage.
  • Dispose of contents/container to

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open Disulfoton in the GHS label constructor →

07 · Health hazards

Disulfoton health hazards and exposure limits

Disulfoton hazard summary

Disulfoton is a manufactured substance used as a pesticide to control a variety of harmful pests that attack many field and vegetable crops. It does not occur naturally. Pure disulfoton is a colorless oil with an unidentifiable characteristic odor and taste. The technical product is dark yellowish, with an aromatic odor. Common trade names are Di-syston, Disystox, Frumin AL, and Soilvirex. Use of trade names is for identification only and does not imply endorsement by the Agency for Toxic Substances and Disease Registry, the Public Health Service, or the U.S. Department of Health and Human Services. It is used to protect small grains, sorghum, corn, and other field crops; some vegetables, fruit, and nut crops; and ornamental and potted plants against certain insects. Although it is used mostly in agriculture, small quantities are used on home and garden plants, and for mosquito control in swamps. The use of disulfoton has decreased in recent years.

Source: Agency for Toxic Substances and Disease Registry (ATSDR)

Disulfoton carcinogenicity classification

Cancer Classification: Group E Evidence of Non-carcinogenicity for Humans

Source: Hazardous Substances Data Bank (HSDB)

An IARC group and a CLP classification answer different questions. IARC judges whether the evidence for cancer in humans is strong enough; CLP Annex VI is the legally binding EU classification. A substance can carry one and not the other.

Disulfoton occupational exposure limits

US occupational exposure limits reported for Disulfoton. PEL is enforceable (OSHA), REL is a recommendation (NIOSH), IDLH is the concentration at which escape becomes impossible without injury.
Limit Value Source
PEL none See Appendix G The National Institute for Occupational Safety and Health (NIOSH)
REL 0.1 mg/m³ Occupational Safety and Health Administration (OSHA)
REL TWA 0.1 mg/m3 [skin] The National Institute for Occupational Safety and Health (NIOSH)
IDLH N.D. The National Institute for Occupational Safety and Health (NIOSH)

These are United States values. The European Union sets its own indicative and binding limits, and the figure that applies at a given workplace is the one in the local regulation — not the one shown here.

08 · Physical and chemical properties

Disulfoton properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

Disulfoton boiling point

Property Value Conditions Source
Boiling point 132.5 °C (270.5 °F) range, midpoint shown OSHA
62 °C (143.6 °F) at 0.01 mmHg (reduced pressure) HSDB
132.5 °C (270.5 °F) range, midpoint shown, at 1.5 mmHg (reduced pressure) HSDB

Disulfoton melting point

Property Value Conditions Source
Melting point -25 °C (-13 °F) HSDB
-25 °C (-13 °F) above this value NIOSH

Disulfoton density

Property Value Conditions Source
Density 1.14 g/cm³ NIOSH
1.144 g/cm³ CAMEO
1.144 g/cm³ at 20 °C HSDB

Disulfoton solubility

Property Value Conditions Source
Solubility SOL IN MOST ORG LIQ & FATTY OILS HSDB
Miscible in n-hexane, dichloromethane, 2-propanol, toluene HSDB
In water, 16.3 mg/l @ 20 °C at 20 °C HSDB

Disulfoton vapor pressure

Property Value Conditions Source
Vapor pressure 0.0002 mmHg NIOSH
0.00018 mmHg at 20 °C CAMEO
0.0000975 mmHg at 25 °C HSDB

Disulfoton flash point

Property Value Conditions Source
Flash point 133 °C (271.4 °F) HSDB
82.22 °C (180 °F) above this value NIOSH

Disulfoton lower explosive limit (LEL)

Property Value Conditions Source
Lower explosive limit (LEL) Combustible Liquid, but will not ignite easily. NIOSH

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

09 · Fire and explosion

Disulfoton fire and explosion behaviour

These are descriptions rather than measured values, so they are kept out of the table above and quoted here with the source that reported them.

Disulfoton fire potential

... Flammable in xylene solution.

Source: Hazardous Substances Data Bank (HSDB)

10 · Handling and storage

Disulfoton storage and handling

Disulfoton safe storage

Provision to contain effluent from fire extinguishing. Separated from food and feedstuffs. Well closed.

Source: ILO-WHO International Chemical Safety Cards (ICSCs)

Disulfoton storage conditions

Store in original container, preferably in a locked area, away from children, food, feed.

Source: Hazardous Substances Data Bank (HSDB)

Disulfoton incompatible materials

Alkalis.

Source: Hazardous Substances Data Bank (HSDB)

Disulfoton reactivity

DISULFOTON is incompatible with the following: Alkalis (NIOSH, 2024). Organothiophosphates, such as DISULFOTON, are susceptible to formation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrides. Partial oxidation by oxidizing agents may result in the release of toxic phosphorus oxides.

Source: CAMEO Chemicals

Planning storage for a mix of chemicals? Check Disulfoton in the storage compatibility matrix →

11 · Questions

Disulfoton — frequently asked questions

What is the CAS number of Disulfoton?

The CAS number of Disulfoton is 298-04-4. Its EC number is 206-054-3.

What is the chemical formula of Disulfoton?

The molecular formula of Disulfoton is C8H19O2PS3 and its molecular weight is 274.4 g/mol.

What does a Disulfoton label have to show?

Under CLP Annex VI the label for Disulfoton carries the pictograms Skull and crossbones and Environment and the signal word is Danger.

Is Disulfoton flammable?

CLP Annex VI assigns Disulfoton no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it. The flash point reported for it is 133 °C (271.4 °F) (HSDB).

Is Disulfoton a carcinogen?

CLP Annex VI records no harmonised carcinogenicity classification for Disulfoton. Annex VI is a list of agreed classifications, not a list of substances found safe, so this is an absence of a classification rather than a clean bill of health.

What is the exposure limit for Disulfoton?

The US occupational exposure limit reported for Disulfoton is none See Appendix G (The National Institute for Occupational Safety and Health (NIOSH)). Limits differ by country: the EU sets its own indicative and binding values, and the figure that applies at a given workplace is the one in the local regulation.

What is the boiling point of Disulfoton?

The boiling point reported for Disulfoton is 132.5 °C (270.5 °F), range, midpoint shown (OSHA).

What is the melting point of Disulfoton?

The melting point reported for Disulfoton is -25 °C (-13 °F) (HSDB).

How should Disulfoton be stored?

Store in original container, preferably in a locked area, away from children, food, feed. (Hazardous Substances Data Bank (HSDB))

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