Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Erionite

Erionite is a hexagonal, cage-like structure composed of a framework of linked (Si,Al)O4 tetrahedra.

CAS 12510-42-8 AlCaH60KNaO36Si2+3 821.77 g/mol Danger

01 · Identification

What Erionite is

Erionite is a hexagonal, cage-like structure composed of a framework of linked (Si,Al)O4 tetrahedra. Its molecular formula is AlCaH60KNaO36Si2+3 and its molecular weight is 821.77 g/mol.

Under the GHS it carries the signal word Danger. It is classed as carcinogens.

02 · Identifiers

Erionite identifiers and molecular data

Erionite CAS number and EC number

CAS number12510-42-8
Index number (CLP Annex VI)650-012-00-0

Erionite molecular formula and molecular weight

Molecular formulaAlCaH60KNaO36Si2+3
Molecular weight821.77 g/mol
Chemical class Carcinogens

03 · GHS classification

Erionite hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Erionite pictograms and signal word

Signal wordDanger

Erionite hazard class and category

GHS hazard classes Erionite falls into
Hazard class Category From code Pictogram
Carcinogenicity GHS chapter 3.6 Category 1A or 1B H350 GHS08

Where two values are shown with “or”, the hazard statement is shared by more than one category or by more than one class, and the code alone does not say which. H272, for example, belongs to oxidising liquids and to oxidising solids — the physical state decides. The binding answer for a specific entry is in the CLP Annex VI table itself.

Erionite hazard statements (H-codes)

Hazard statements assigned to Erionite
CodeHazard statement
H350 May cause cancer <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.

This page lists only the codes assigned to Erionite. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for Erionite

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of Erionite issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

Erionite precautionary statements

CLP Annex VI assigns 4 precautionary statements to Erionite. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Response

What to do once exposure, spillage or fire has already happened.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

Erionite name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български ерионит
Spanish español Erionita
Czech čeština erionit
Danish dansk erionit
German Deutsch Erionit
Estonian eesti erioniit
Greek ελληνικά εριονίτης
English English erionite
French français Érionite
Croatian hrvatski erionit
Italian italiano erionite
Latvian latviešu erionīts
Lithuanian lietuvių erionitas
Hungarian magyar erionit
Maltese Malti erionit
Dutch Nederlands erioniet
Polish polski Erionit
Portuguese português erionite
Romanian română erionit
Slovak slovenčina erionit
Slovenian slovenščina erionit
Finnish suomi erioniitti
Swedish svenska erionit

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

Erionite GHS label elements

Everything CLP Annex VI fixes for Erionite, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS08 Health hazard pictogram

Danger

Erionite

  • May cause cancer <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
  • Obtain special instructions before use.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • IF exposed or concerned:
  • Get medical advice/attention.

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open Erionite in the GHS label constructor →

07 · Health hazards

Erionite health hazards and exposure limits

Erionite hazard summary

Natural zeolites include analcite, chabazite, heulandite, natrolite, stilbite, and thomosonite. [Hawley] Erionite is one of about 40 natural zeolites, which are hydrated aluminosilicates of the alkaline and alkaline-earth metals. Studies of Turkish villages with high dust exposures to erionite found increased incidence of mesotheliomas, and erionite fibers were found in lung tissue samples. Erionite causes mesothelioma in experimental mice and rats. [NTP]

Source: Haz-Map, Information on Hazardous Chemicals and Occupational Diseases

Erionite carcinogenicity classification

IARC classification Group 1 — Carcinogenic to humans
IARC monographs Volume 42: (1987) Silica and Some Silicates

ERIONITE (Group 1). A. Evidence for carcinogenicity to humans (sufficient). B. Evidence for carcinogenicity to animals (sufficient).

Source: Hazardous Substances Data Bank (HSDB)

Erionite is known to be a human carcinogen based on sufficient evidence of carcinogenicity in humans.

Source: Hazardous Substances Data Bank (HSDB)

An IARC group and a CLP classification answer different questions. IARC judges whether the evidence for cancer in humans is strong enough; CLP Annex VI is the legally binding EU classification. A substance can carry one and not the other.

08 · Physical and chemical properties

Erionite properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

Erionite density

Property Value Conditions Source
Density 2.05 g/cm³ range, midpoint shown HSDB

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

09 · Handling and storage

Erionite storage and handling

Erionite storage conditions

PRECAUTIONS FOR "CARCINOGENS": Storage site should be as close as practical to lab in which carcinogens are to be used, so that only small quantities required for ... expt need to be carried. Carcinogens should be kept in only one section of cupboard, an explosion-proof refrigerator or freezer (depending on chemicophysical properties ...) that bears appropriate label. An inventory ... should be kept, showing quantity of carcinogen & date it was acquired ... Facilities for dispensing ... should be contiguous to storage area. /Chemical Carcinogens/

Source: Hazardous Substances Data Bank (HSDB)

Planning storage for a mix of chemicals? Check Erionite in the storage compatibility matrix →

10 · Questions

Erionite — frequently asked questions

What is the CAS number of Erionite?

The CAS number of Erionite is 12510-42-8.

What is the chemical formula of Erionite?

The molecular formula of Erionite is AlCaH60KNaO36Si2+3 and its molecular weight is 821.77 g/mol.

What does a Erionite label have to show?

Under CLP Annex VI the label for Erionite carries the pictogram Health hazard and the signal word is Danger.

Is Erionite flammable?

CLP Annex VI assigns Erionite no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it.

Is Erionite a carcinogen?

Yes. CLP Annex VI classifies Erionite as a category 1A or 1B carcinogen and assigns it H350: may cause cancer. IARC places it in Group 1: carcinogenic to humans.

How should Erionite be stored?

PRECAUTIONS FOR "CARCINOGENS": Storage site should be as close as practical to lab in which carcinogens are to be used, so that only small quantities required for ... expt need to be carried. Carcinogens should be kept in only one section of cupboard, an explosion-proof refrigerator or freezer (depending on chemicophysical properties ...) that bears appropriate label. An inventory ... should be kept, showing quantity of carcinogen & date it was acquired ... Facilities for dispensing ... should be contiguous to storage area. /Chemical Carcinogens/ (Hazardous Substances Data Bank (HSDB))

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