Substance profile
Ethoate-methyl
Ethoate-methyl is a white crystalline solid with a slightly aromatic odor.
01 · Identification
What Ethoate-methyl is
Ethoate-methyl is a white crystalline solid with a slightly aromatic odor. Its molecular formula is C6H14NO3PS2 and its molecular weight is 243.3 g/mol. It melts at 66.1 °C.
Under the GHS it carries the signal word Warning.
02 · Identifiers
Ethoate-methyl identifiers and molecular data
Ethoate-methyl CAS number and EC number
Ethoate-methyl molecular formula and molecular weight
Other names for Ethoate-methyl
- ethoate-methyl (ISO)
- ethylcarbamoylmethyl O,O-dimethyl phosphorodithioate
03 · GHS classification
Ethoate-methyl hazard classification
Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.
Ethoate-methyl pictograms and signal word
Ethoate-methyl hazard class and category
| Hazard class | Category | From code | Pictogram |
|---|---|---|---|
| Acute toxicity - oral GHS chapter 3.1 | Category 4 | H302 | GHS07 |
| Acute toxicity - dermal GHS chapter 3.1 | Category 4 | H312 | GHS07 |
Ethoate-methyl hazard statements (H-codes)
| Code | Hazard statement |
|---|---|
| H312 | Harmful in contact with skin. |
| H302 | Harmful if swallowed. |
This page lists only the codes assigned to Ethoate-methyl. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.
Safety Data Sheet
Getting an SDS for Ethoate-methyl
A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of Ethoate-methyl issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.
04 · Precautionary statements
Ethoate-methyl precautionary statements
CLP Annex VI assigns 7 precautionary statements to Ethoate-methyl. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.
Prevention
What to do before and during handling so the hazard never happens.
Response
What to do once exposure, spillage or fire has already happened.
Reading the notation. … is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.
05 · Names in the regulation
Ethoate-methyl name in 23 EU languages
CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.
| Language | Name in CLP Annex VI Part 3 |
|---|---|
| Bulgarian български | етоат-метил (ISO) етилкарбамоилметилов O , O -диметилов фосфородитиоат |
| Spanish español | Etoato-metilo (ISO) fosforoditioato de etilcarbamoilmetilo y O , O -dimetilo |
| Czech čeština | ethoát-methyl (ISO) S -( N -ethylkarbamoyl)methyl- O, O -dimethyl-fosforodithioát |
| Danish dansk | ethoat-methyl (ISO) ethylcarbamoylmethyl- O, O- dimethyldithiophosphat |
| German Deutsch | Ethoat-methyl (ISO) Ethylcarbamoylmethyl- O, O -dimethylphosphorodithioat |
| Estonian eesti | etoaat-metüül (ISO) etüülkarbamoüülmetüül- O , O -dimetüülfosforoditioaat |
| Greek ελληνικά | ethoate-methyl (μεθυλική αιθοάτη) (ISO) διθειοφωσφορικό αιθυλοκαρβαμοϋλομεθύλιο O , O -διμεθύλιο |
| English English | ethoate-methyl (ISO) ethylcarbamoylmethyl O , O -dimethyl phosphorodithioate |
| French français | éthoate-méthyl (ISO) phosphorodithioate d'éthylcarbamoylméthyle et de O , O -diméthyle |
| Croatian hrvatski | etoat-metil (ISO) etil-karbamoil-metil- O, O -dimetil-fosforoditioat |
| Italian italiano | etoato-metil (ISO) ditiofosfato di etilcarbammoilmetile e O, O-dimetile |
| Latvian latviešu | etoātmetils (ISO) etilkarbamoilmetil- O , O -dimetilfosforditioāts |
| Lithuanian lietuvių | etoat-metilas (ISO) etilkarbamoilmetil- O , O -dimetilditiofosfatas |
| Hungarian magyar | etoát-metil (ISO) etilkarbamoilmetil- O , O -dimetil-ditiofoszfát |
| Maltese Malti | etoat-metil (ISO) fosforoditijoat ta’ O , O -dimetil tal-etilkarbamojlmetil |
| Dutch Nederlands | ethoaat-methyl (ISO) ethylcarbamoylmethyl- O , O -dimethyldithiofosfaat |
| Polish polski | etoat-metylowy (ISO) ditiofosforan S -(etylokarbamoilo)metylu- O , O -dimetylu |
| Portuguese português | etoato-metilo (ISO) ditiofosfato de O , O -dimetilo e de etilcarbamoilmetilo |
| Romanian română | etoat-metil (ISO) ditiofosfat de etilcarbamoilmetil și de O , O -dimetil |
| Slovak slovenčina | etoát-metyl (ISO) S-[(etylkarbamoyl)metyl]-O, O-dimetyl-fosforoditioát |
| Slovenian slovenščina | etoat-metil (ISO) etilkarbamoilmetil O , O -dimetil fosforoditioat |
| Finnish suomi | etoaattimetyyli (ISO) etyylikarbamoyylimetyyli- O , O -dimetyylifosforoditioaatti |
| Swedish svenska | etoatmetyl (ISO) etylkarbamoylmetyl- O , O -dimetylfosforditioat |
All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.
06 · Label elements
Ethoate-methyl GHS label elements
Everything CLP Annex VI fixes for Ethoate-methyl, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.
Warning
Ethoate-methyl
- Harmful in contact with skin.
- Harmful if swallowed.
- Do not eat, drink or smoke when using this product.
- Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/…
- IF SWALLOWED:
- IF ON SKIN:
- Call a POISON CENTER/doctor/… if you feel unwell.
- Rinse mouth.
- Wash with plenty of water/…
Supplier name, address and telephone number· Product identifier·Nominal quantity
Need this as an actual label? Open Ethoate-methyl in the GHS label constructor →
07 · Health hazards
Ethoate-methyl health hazards and exposure limits
Ethoate-methyl hazard summary
No toxic symptoms were observed in 50 day feeding study with rats at 300 ppm; [HSDB] Effects in high-dose animal studies include changes in liver weight and inhibition of true cholinesterase; [RTECS] The average of two baseline respective cholinesterase activity determinations three days apart, with no exposures to enzyme inhibiting pesticides for at least 30 days, is recommended for each worker prior to exposure to cholinesterase inhibitors because of large inter-individual differences in published baseline values. To be established at least once a year. Removal from workplace exposures is recommended until the cholinesterase activity returns to within 20% of baseline. [TLVs and BEIs]
Source: Haz-Map, Information on Hazardous Chemicals and Occupational Diseases
08 · Physical and chemical properties
Ethoate-methyl properties
Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.
Ethoate-methyl melting point
| Property | Value | Conditions | Source |
|---|---|---|---|
| Melting point | 66.1 °C (151 °F) | range, midpoint shown | HSDB |
Ethoate-methyl density
| Property | Value | Conditions | Source |
|---|---|---|---|
| Density | 1.164 g/cm³ | at 70 °C | HSDB |
Ethoate-methyl solubility
| Property | Value | Conditions | Source |
|---|---|---|---|
| Solubility | 0.95% IN OLIVE OIL, 630 G/KG IN BENZENE, 83O G/KG IN CHLOROFORM, 430 G/KG IN DIETHYL ETHER, 6O G/KG IN XYLENE; VERY SOL IN ACETONE ETHANOL | HSDB | |
| In water, 8.5X10+3 mg/L at 25 °C | at 25 °C | HSDB |
Ethoate-methyl vapor pressure
| Property | Value | Conditions | Source |
|---|---|---|---|
| Vapor pressure | 0.00000925 mmHg | Haz-Map |
Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.
09 · Handling and storage
Ethoate-methyl storage and handling
Ethoate-methyl storage conditions
...MUST BE STORED IN ITS SEALED ORIGINAL CONTAINERS, IN WELL-AIRED, FRESH & DRY STOREHOUSES OR IN SHADED & POSSIBLY WELL-AIRED PLACES. IT IS RECOMMENDED THAT THE PRODUCT'S TEMP...NOT EXCEED 25-30 °C, & KEEP...AWAY FROM SOURCES OF HEAT, FREE FLAMES OR SPARK-GENERATING EQUIPMENT. CONTAINERS MUST BE STACKED IN SUCH A WAY AS TO PERMIT FREE CIRCULATION OF AIR...AT BOTTOM & INSIDE OF PILES. STORAGE AREAS MUST BE LOCATED AT SUITABLE DISTANCE FROM INHABITED BUILDINGS, ANIMAL SHELTERS, & FOOD STORES; MOREOVER, THEY MUST BE INACCESSIBLE TO UNAUTHORIZED PERSONS, CHILDREN, & DOMESTIC ANIMALS. /PROTHOATE/
Source: Hazardous Substances Data Bank (HSDB)
Planning storage for a mix of chemicals? Check Ethoate-methyl in the storage compatibility matrix →
10 · Questions
Ethoate-methyl — frequently asked questions
What is the CAS number of Ethoate-methyl?
The CAS number of Ethoate-methyl is 116-01-8. Its EC number is 204-121-1.
What is the chemical formula of Ethoate-methyl?
The molecular formula of Ethoate-methyl is C6H14NO3PS2 and its molecular weight is 243.3 g/mol.
What does a Ethoate-methyl label have to show?
Under CLP Annex VI the label for Ethoate-methyl carries the pictogram Exclamation mark and the signal word is Warning.
Is Ethoate-methyl flammable?
CLP Annex VI assigns Ethoate-methyl no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it.
Is Ethoate-methyl a carcinogen?
CLP Annex VI records no harmonised carcinogenicity classification for Ethoate-methyl. Annex VI is a list of agreed classifications, not a list of substances found safe, so this is an absence of a classification rather than a clean bill of health.
What is the melting point of Ethoate-methyl?
The melting point reported for Ethoate-methyl is 66.1 °C (151 °F), range, midpoint shown (HSDB).
How should Ethoate-methyl be stored?
...MUST BE STORED IN ITS SEALED ORIGINAL CONTAINERS, IN WELL-AIRED, FRESH & DRY STOREHOUSES OR IN SHADED & POSSIBLY WELL-AIRED PLACES. IT IS RECOMMENDED THAT THE PRODUCT'S TEMP...NOT EXCEED 25-30 °C, & KEEP...AWAY FROM SOURCES OF HEAT, FREE FLAMES OR SPARK-GENERATING EQUIPMENT. CONTAINERS MUST BE STACKED IN SUCH A WAY AS TO PERMIT FREE CIRCULATION OF AIR...AT BOTTOM & INSIDE OF PILES. STORAGE AREAS MUST BE LOCATED AT SUITABLE DISTANCE FROM INHABITED BUILDINGS, ANIMAL SHELTERS, & FOOD STORES; MOREOVER, THEY MUST BE INACCESSIBLE TO UNAUTHORIZED PERSONS, CHILDREN, & DOMESTIC ANIMALS. /PROTHOATE/ (Hazardous Substances Data Bank (HSDB))
Nearby
Substances next to Ethoate-methyl
Keep going: substances starting with E, or search the whole database by name, CAS number, pictogram or signal word.