Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Ethylene glycol dimethacrylate

Ethylene glycol dimethacrylate: liquid.

CAS 97-90-5 C10H14O4 198.22 g/mol Warning

01 · Identification

What Ethylene glycol dimethacrylate is

Ethylene glycol dimethacrylate: liquid. Its molecular formula is C10H14O4 and its molecular weight is 198.22 g/mol. It boils at 260 °C, melts at -40 °C.

Under the GHS it carries the signal word Warning.

02 · Identifiers

Ethylene glycol dimethacrylate identifiers and molecular data

Ethylene glycol dimethacrylate CAS number and EC number

CAS number97-90-5
EC number202-617-2
Index number (CLP Annex VI)607-114-00-5

Ethylene glycol dimethacrylate molecular formula and molecular weight

Molecular formulaC10H14O4
Molecular weight198.22 g/mol

Other names for Ethylene glycol dimethacrylate

  • ethylene dimethacrylate

03 · GHS classification

Ethylene glycol dimethacrylate hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Ethylene glycol dimethacrylate pictograms and signal word

Signal wordWarning

Ethylene glycol dimethacrylate hazard class and category

GHS hazard classes Ethylene glycol dimethacry… falls into
Hazard class Category From code Pictogram
Skin sensitisation GHS chapter 3.4 Category 1 or 1A or 1B H317 GHS07
Specific target organ toxicity - single exposure GHS chapter 3.8 Category 3 H335 GHS07

Where two values are shown with “or”, the hazard statement is shared by more than one category or by more than one class, and the code alone does not say which. H272, for example, belongs to oxidising liquids and to oxidising solids — the physical state decides. The binding answer for a specific entry is in the CLP Annex VI table itself.

Ethylene glycol dimethacrylate hazard statements (H-codes)

Hazard statements assigned to Ethylene glycol dimethacry…
CodeHazard statement
H335 May cause respiratory irritation.
H317 May cause an allergic skin reaction.

This page lists only the codes assigned to Ethylene glycol dimethacry…. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for Ethylene glycol dimethacry…

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of Ethylene glycol… issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

Ethylene glycol dimethacrylate precautionary statements

CLP Annex VI assigns 5 precautionary statements to Ethylene glycol dimethacry…. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Response

What to do once exposure, spillage or fire has already happened.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

Ethylene glycol dimethacrylate name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български етиленов диметакрилат
Spanish español Dimetacrilato de etileno
Czech čeština ethylen-dimethakrylát
Danish dansk ethylendimethacrylat
German Deutsch Ethylendimethacrylat Ethylenglykoldimethacrylat
Estonian eesti etüleendimetakrülaat
Greek ελληνικά διμεθακρυλικός αιθυλενεστέρας διμεθακρυλικό αιθυλένιο
English English ethylene dimethacrylate
French français diméthacrylate d'éthylène
Croatian hrvatski etilen-dimetakrilat
Italian italiano dimetacrilato di etilene
Latvian latviešu etilēndimetakrilāts
Lithuanian lietuvių etilendimetakrilatas
Hungarian magyar etilén-dimetil-akrilát
Maltese Malti dimetakrilat tal-etilen
Dutch Nederlands ethyleendimethacrylaat
Polish polski dimetakrylan etylenu dimetakrylan glikolu etylenowego
Portuguese português dimetacrilato de etileno
Romanian română dimetacrilat de etilen
Slovak slovenčina etylén-dimetakrylát
Slovenian slovenščina etilen dimetakrilat
Finnish suomi etyleenidimetakrylaatti
Swedish svenska etylendimetakrylat

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

Ethylene glycol dimethacrylate GHS label elements

Everything CLP Annex VI fixes for Ethylene glycol dimethacry…, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS07 Exclamation mark pictogram

Warning

Ethylene glycol dimethacrylate

  • May cause respiratory irritation.
  • May cause an allergic skin reaction.
  • Avoid breathing dust/fume/gas/mist/vapours/spray.
  • Contaminated work clothing should not be allowed out of the workplace.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • Get medical advice/attention.
  • If skin irritation or rash occurs:

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open Ethylene glycol dimethacry… in the GHS label constructor →

07 · Health hazards

Ethylene glycol dimethacrylate health hazards and exposure limits

Ethylene glycol dimethacrylate hazard summary

Allergic contact dermatitis reported in dental technicians, dental assistants, and a manufacturing worker (making rear-view mirrors) ; [Kanerva, p. 1749] A lachrymator; [CHEMINFO] An eye and respiratory tract irritant; Not a sensitizer in one study of guinea pigs; Emergency treatment: Acrylates, multifunctional; [HSDB] May polymerize; An eye and respiratory tract irritant; May cause skin sensitization; [ICSC] Danger of skin sensitization; [MAK] An irritant; May cause skin sensitization; [Aldrich MSDS]

Source: Haz-Map, Information on Hazardous Chemicals and Occupational Diseases

08 · Physical and chemical properties

Ethylene glycol dimethacrylate properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

Ethylene glycol dimethacrylate boiling point

Property Value Conditions Source
Boiling point 260 °C (500 °F) HSDB
260 °C (500 °F) at 760 mmHg DOE PAC

Ethylene glycol dimethacrylate melting point

Property Value Conditions Source
Melting point -40 °C (-40 °F) HSDB

Ethylene glycol dimethacrylate density

Property Value Conditions Source
Density 1.05 g/cm³ ICSC
1.055 g/cm³ at 20 °C HSDB

Ethylene glycol dimethacrylate solubility

Property Value Conditions Source
Solubility > 10% in benzene HSDB
> 10% in ethanol HSDB
> 10% in ligroin HSDB

Ethylene glycol dimethacrylate vapor pressure

Property Value Conditions Source
Vapor pressure 3.5853 mmHg at 20 °C ICSC
3.6 mmHg Haz-Map

Ethylene glycol dimethacrylate flash point

Property Value Conditions Source
Flash point 101 °C (213.8 °F) ICSC

Ethylene glycol dimethacrylate autoignition temperature

Property Value Conditions Source
Autoignition temperature 395 °C (743 °F) ICSC

Ethylene glycol dimethacrylate vapor density

Property Value Conditions Source
Vapor density 6.8 (air = 1) ICSC

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

09 · Handling and storage

Ethylene glycol dimethacrylate storage and handling

Ethylene glycol dimethacrylate safe storage

Store only if stabilized. Cool. Refer to the manufacturer's instructions for proper storage conditions.

Source: ILO-WHO International Chemical Safety Cards (ICSCs)

Ethylene glycol dimethacrylate storage conditions

Temp during storage must be kept low to minimize formation of peroxides and other oxidation products. ... Storage temp below 30 °C are recommended for the polyfunctional methacrylates. ... The methacrylate monomers should not be stored for longer than one year. Shorter storage times are recommended for the aminomethacrylates, ie, three months, and the polyfunctional methacrylates, ie, six months. Many of these cmpd are sensitive to UV light and should, therefore, be stored in the dark. The methacrylic esters may be stored in mild steel, stainless steel, or aluminum. /Methacrylic acid & derivatives/

Source: Hazardous Substances Data Bank (HSDB)

Planning storage for a mix of chemicals? Check Ethylene glycol dimethacr… in the storage compatibility matrix →

10 · Questions

Ethylene glycol dimethacrylate — frequently asked questions

What is the CAS number of Ethylene glycol dimethacrylate?

The CAS number of Ethylene glycol dimethacrylate is 97-90-5. Its EC number is 202-617-2.

What is the chemical formula of Ethylene glycol dimethacrylate?

The molecular formula of Ethylene glycol dimethacrylate is C10H14O4 and its molecular weight is 198.22 g/mol.

What does a Ethylene glycol dimethacrylate label have to show?

Under CLP Annex VI the label for Ethylene glycol dimethacrylate carries the pictogram Exclamation mark and the signal word is Warning.

Is Ethylene glycol dimethacrylate flammable?

CLP Annex VI assigns Ethylene glycol dimethacrylate no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it. The flash point reported for it is 101 °C (213.8 °F) (ICSC).

Is Ethylene glycol dimethacrylate a carcinogen?

CLP Annex VI records no harmonised carcinogenicity classification for Ethylene glycol dimethacrylate. Annex VI is a list of agreed classifications, not a list of substances found safe, so this is an absence of a classification rather than a clean bill of health.

What is the boiling point of Ethylene glycol dimethacrylate?

The boiling point reported for Ethylene glycol dimethacrylate is 260 °C (500 °F) (HSDB).

What is the melting point of Ethylene glycol dimethacrylate?

The melting point reported for Ethylene glycol dimethacrylate is -40 °C (-40 °F) (HSDB).

How should Ethylene glycol dimethacrylate be stored?

Temp during storage must be kept low to minimize formation of peroxides and other oxidation products. ... Storage temp below 30 °C are recommended for the polyfunctional methacrylates. ... The methacrylate monomers should not be stored for longer than one year. Shorter storage times are recommended for the aminomethacrylates, ie, three months, and the polyfunctional methacrylates, ie, six months. Many of these cmpd are sensitive to UV light and should, therefore, be stored in the dark. The methacrylic esters may be stored in mild steel, stainless steel, or aluminum. /Methacrylic acid & derivatives/ (Hazardous Substances Data Bank (HSDB))

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