Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Extracts (petroleum), cold-acid, C4-6

Extracts (petroleum), cold-acid, C4-6 is a substance with a harmonised classification under EU CLP.

CAS 68477-61-2 Danger

01 · Identification

What Extracts (petroleum)… is

Extracts (petroleum), cold-acid, C4-6 is a substance with a harmonised classification under EU CLP.

Under the GHS it carries the signal word Danger.

02 · Identifiers

Extracts (petroleum)… identifiers and molecular data

Extracts (petroleum)… CAS number and EC number

CAS number68477-61-2
EC number270-741-4
Index number (CLP Annex VI)649-362-00-7

Other names for Extracts (petroleum)…

  • Low boiling point naphtha - unspecified
  • [A complex combination of organic compounds produced by cold acid unit extraction of saturated and unsaturated aliphatic hydrocarbons usually ranging in carbon numbers from C3 through C6, predominantly pentanes and amylenes. It consists predominantly of saturated and unsaturated hydrocarbons having carbon numbers in the range of C4 through C6, predominantly C5.]

03 · GHS classification

Extracts (petroleum)… hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Extracts (petroleum)… pictograms and signal word

Signal wordDanger

Extracts (petroleum)… hazard class and category

GHS hazard classes Extracts (petroleum)… falls into
Hazard class Category From code Pictogram
Germ cell mutagenicity GHS chapter 3.5 Category 1A or 1B H340 GHS08
Carcinogenicity GHS chapter 3.6 Category 1A or 1B H350 GHS08
Aspiration hazard GHS chapter 3.10 Category 1 H304 GHS08

Where two values are shown with “or”, the hazard statement is shared by more than one category or by more than one class, and the code alone does not say which. H272, for example, belongs to oxidising liquids and to oxidising solids — the physical state decides. The binding answer for a specific entry is in the CLP Annex VI table itself.

Extracts (petroleum)… hazard statements (H-codes)

Hazard statements assigned to Extracts (petroleum)…
CodeHazard statement
H350 May cause cancer <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
H340 May cause genetic defects <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
H304 May be fatal if swallowed and enters airways.

This page lists only the codes assigned to Extracts (petroleum)…. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for Extracts (petroleum)…

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of Extracts (petroleum)… issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

Extracts (petroleum)… precautionary statements

CLP Annex VI assigns 4 precautionary statements to Extracts (petroleum)…. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Response

What to do once exposure, spillage or fire has already happened.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

Extracts (petroleum)… name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български Екстракти (нефтени), нискотемпературна киселинна екстракция, C 4-6 Нафта с ниска температура на кипене — неспецифицирана
Spanish español Extractos (petróleo), ácido en frío, C 4-6 nafta de bajo punto de ebullición, sin especificar
Czech čeština extrakty (ropné), z extrakce studenou kyselinou, C 4-6 nízkovoroucí benzínová frakce – nespecifikovaná
Danish dansk ekstrakter (råolie), koldsyre-, C 4-6 lavtkogende uspecificeret naphtha
German Deutsch Extrakte (Erdöl), Kalt-Säure, C 4-6 Naphtha, niedrigsiedend, nicht spezifiziert
Estonian eesti ekstraktid (nafta), külm hape, C 4–6 -fraktsioon kergkeev toorbensiin – määratlemata
Greek ελληνικά Εκχυλίσματα (πετρελαίου), από εκχύλιση εν ψυχρώ με οξύ, C 4-6 Νάφθα χαμηλού σημείου ζέσεως — μη προσδιοριζόμενη
English English Extracts (petroleum), cold-acid, C 4-6 Low boiling point naphtha — unspecified
French français Extraits en C 4-6 , extraction à froid à l'acide naphta à bas point d'ébullition — non spécifié
Croatian hrvatski ekstrakti (nafta), hladna kis., C 4-6 niskovrijući benzin – nespecificiran
Italian italiano estratti (petrolio), estrazione acida a freddo, C 4-6 nafta con basso punto di ebollizione — non specificata
Latvian latviešu Ekstrakti (naftas), apstrādāti ar aukstu skābi, C 4-6 Jēlbenzīns ar zemu viršanas punktu – nav precizēts
Lithuanian lietuvių Ekstraktai (nafta), šalta rūgštimi, C 4-6 Žematemperatūris pirminis benzinas – neapibrėžtas.
Hungarian magyar Extraktumok (nyersolaj), hideg savas, C 4-6 Alacsony forráspontú benzin – nem meghatározott
Maltese Malti Estratti (żejt mhux maħdum), aċidu kiesaħ, C 4-6 Nafta b'punt ta' togħlija baxx – mhux speċifikat
Dutch Nederlands extracten (aardolie), koud zuur, C 4-6 nafta met laag kookpunt — niet gespecifieerd
Polish polski Ekstrakty węglowodorów C 4-6 otrzymane w wyniku rafinacji zimnym kwasem (ropa naftowa) Niskowrząca benzyna – niespecyfikowana
Portuguese português extratos (petróleo), de extração a frio com ácido, C 4-6 nafta de baixo ponto de ebulição — não-especificada
Romanian română Extracție cu acid la rece (petrol), fracția C 4-6 Benzină nafta cu temperaturi de fierbere scăzute – fără specificații
Slovak slovenčina extrakty (ropné), z extrakcie kyselinou za studena, C 4-6 ťažký benzín s nízkou teplotou varu – nešpecifikovanýKomplexná zmes organických zlúčenín získavaná extrakciou kyselinou za studena zo zmesi nasýtených a nenasýtených alifatických uhľovodíkov s počtom atómov uhlíka v rozmedzí zvyčajne od C 3 do C 6 , predovšetkým C 5 -alkánov a C 5 -alkénov Pozostáva predovšetkým z nasýtených a nenasýtených uhľovodíkov s počtom atómov uhlíka prevažne v rozmedzí od C 4 do C 6 , predovšetkým C 5 .]
Slovenian slovenščina ekstrakti (nafta), hladno kislinski, C 4–6 nafta z nizkim vreliščem – nespecificirana
Finnish suomi Uutteet (maaöljy), kylmä happo, C 4 –6 Matalalla kiehuva teollisuusbensiini – täsmentämätön
Swedish svenska Extrakt (petroleum), kall syra-, C 4-6 Lågkokande nafta – ospecificerad

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

Extracts (petroleum)… GHS label elements

Everything CLP Annex VI fixes for Extracts (petroleum)…, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS08 Health hazard pictogram

Danger

Extracts (petroleum)…

  • May cause cancer <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
  • May cause genetic defects <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
  • May be fatal if swallowed and enters airways.
  • Obtain special instructions before use.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • IF exposed or concerned:
  • Get medical advice/attention.

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open Extracts (petroleum)… in the GHS label constructor →

07 · Transport

Extracts (petroleum)… UN number and transport classification

Transport classification is a separate system from the GHS classification above. It decides how a package is marked and how a load may be carried; it does not follow from the workplace label, and the workplace label does not follow from it. The entries below are linked by CAS number, never by name.

Extracts (petroleum)… under UN 1197 — shipping name, class and packing group

Europe · ADR 2025, Table A

Proper shipping name (3.1.2) Class Classification code PG Labels (column 5)
EXTRACTS, LIQUID, for flavour or aroma (vapour pressure at 50 °C more than 110 kPa) 3 F1 II
  • ADR label model 3 — Flammable liquid
3
EXTRACTS, LIQUID, for flavour or aroma (vapour pressure at 50 °C not more than 110 kPa) 3 F1 II
  • ADR label model 3 — Flammable liquid
3
EXTRACTS, LIQUID, for flavour or aroma 3 F1 III
  • ADR label model 3 — Flammable liquid
3
EXTRACTS, LIQUID, for flavour or aroma (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C more than 110 kPa) 3 F1 III
  • ADR label model 3 — Flammable liquid
3
EXTRACTS, LIQUID, for flavour or aroma (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C not more than 110 kPa) 3 F1 III
  • ADR label model 3 — Flammable liquid
3

Source: ADR 2025, Table A of Chapter 3.2 · ECE/TRANS/352 Vol. I (UNECE). Class 3 is “Flammable liquids” (ADR 2.1.1.1).

Proper shipping name (column 2) Class or division PG Labels (column 6)
Extracts, liquid, for flavor or aroma 3 II
  • US DOT FLAMMABLE LIQUID label (§172.419)
3
Extracts, liquid, for flavor or aroma 3 III
  • US DOT FLAMMABLE LIQUID label (§172.419)
3

Source: 49 CFR 172.101 Hazardous Materials Table · eCFR, revision 2026-08-03. Class 3 is “Flammable and combustible liquid” (49 CFR 173.2).

Full UN 1197 entry — special provisions, packing instructions, quantity limits and the orange plate →

08 · Questions

Extracts (petroleum)… — frequently asked questions

What is the CAS number of Extracts (petroleum)…?

The CAS number of Extracts (petroleum)… is 68477-61-2. Its EC number is 270-741-4.

What does a Extracts (petroleum)… label have to show?

Under CLP Annex VI the label for Extracts (petroleum)… carries the pictogram Health hazard and the signal word is Danger.

Is Extracts (petroleum)… flammable?

CLP Annex VI assigns Extracts (petroleum)… no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it.

Is Extracts (petroleum)… a carcinogen?

Yes. CLP Annex VI classifies Extracts (petroleum)… as a category 1A or 1B carcinogen and assigns it H350: may cause cancer.

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