Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Guanidine Hydrochloride

Guanidine Hydrochloride: large Crystals; Dry Powder; Liquid.

CAS 50-01-1 Warning

01 · Identification

What Guanidine Hydrochloride is

Guanidine Hydrochloride: large Crystals; Dry Powder; Liquid. It melts at 183 °C.

Under the GHS it carries the signal word Warning.

02 · Identifiers

Guanidine Hydrochloride identifiers and molecular data

Guanidine Hydrochloride CAS number and EC number

CAS number50-01-1
EC number200-002-3
Index number (CLP Annex VI)607-148-00-0

Other names for Guanidine Hydrochloride

  • guanidinium chloride
  • guanadine hydrochloride

03 · GHS classification

Guanidine Hydrochloride hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Guanidine Hydrochloride pictograms and signal word

Signal wordWarning

Guanidine Hydrochloride hazard class and category

GHS hazard classes Guanidine Hydrochloride falls into
Hazard class Category From code Pictogram
Acute toxicity - oral GHS chapter 3.1 Category 4 H302 GHS07
Skin corrosion/irritation GHS chapter 3.2 Category 2 H315 GHS07
Serious eye damage/eye irritation GHS chapter 3.3 Category 2A H319 GHS07

Guanidine Hydrochloride hazard statements (H-codes)

Hazard statements assigned to Guanidine Hydrochloride
CodeHazard statement
H302 Harmful if swallowed.
H315 Causes skin irritation.
H319 Causes serious eye irritation.

This page lists only the codes assigned to Guanidine Hydrochloride. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for Guanidine Hydrochloride

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of Guanidine Hydrochlorid… issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

Guanidine Hydrochloride precautionary statements

CLP Annex VI assigns 13 precautionary statements to Guanidine Hydrochloride. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

Guanidine Hydrochloride name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български гуанидиниев хлорид гуанидинхидрохлорид
Spanish español Cloruro de guanidinio clorhidrato de guanidina
Czech čeština guanidin-chlorid guanidin-hydrochlorid
Danish dansk guanidinhydrochlorid guanidiniumchlorid
German Deutsch Guanidiniumchlorid Guanadinhydrochlorid
Estonian eesti guanidiiniumkloriid guanidiinvesinikkloriid
Greek ελληνικά χλωριούχο γουανιδίνιο υδροχλωρική γουαναδίνη
English English guanidinium chloride guanadine hydrochloride
French français chlorure de guanidinium chlorhydrate de guanidine
Croatian hrvatski gvanidin-klorid gvanadin-hidroklorid
Italian italiano guanidinio cloruro
Latvian latviešu guanidīnija hlorīds guanidīna hidrohlorīds
Lithuanian lietuvių guanidinio chloridas guanidino rūgštusis chloridas
Hungarian magyar guanidínium-klorid guanidin-hidroklorid
Maltese Malti klorur tal-gwanidju idroklorur tal-gwanadin
Dutch Nederlands guanidiniumchloride guanadinehydrochloride
Polish polski chlorek guanidynium chlorowodorek guanidynychlorek guanidyny
Portuguese português cloreto de guanidínio cloridrato de guanidina
Romanian română clorură de guanidiniu clorhidrat de guanidină
Slovak slovenčina guanidínium-chlorid hydrochlorid guanidínu
Slovenian slovenščina gvanidinijev klorid gvanidin hidroklorid
Finnish suomi guanidiniumkloridi guanidiinihydrokloridi
Swedish svenska guanidiniumklorid guanidinhydroklorid

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

Guanidine Hydrochloride GHS label elements

Everything CLP Annex VI fixes for Guanidine Hydrochloride, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS07 Exclamation mark pictogram

Warning

Guanidine Hydrochloride

  • Harmful if swallowed.
  • Causes skin irritation.
  • Causes serious eye irritation.
  • Wash thoroughly after handling.
  • Do not eat, drink or smoke when using this product.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • IF SWALLOWED:
  • IF ON SKIN:
  • IF IN EYES:
  • Call a POISON CENTER/doctor/ if you feel unwell.
  • Get medical advice/attention.
  • Rinse mouth.
  • If skin irritation occurs:
  • If eye irritation persists:
  • Remove contact lenses, if present and easy to do. Continue rinsing.
  • Wash with plenty of water/

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open Guanidine Hydrochloride in the GHS label constructor →

07 · Physical and chemical properties

Guanidine Hydrochloride properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

Guanidine Hydrochloride melting point

Property Value Conditions Source
Melting point 183 °C (361.4 °F) DOE PAC
181.5 °C (358.7 °F) range, midpoint shown ICSC

Guanidine Hydrochloride density

Property Value Conditions Source
Density 1.3 g/cm³ ICSC

Guanidine Hydrochloride solubility

Property Value Conditions Source
Solubility Solubility in water, g/100ml at 20 °C: 215 at 20 °C ICSC

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

08 · Handling and storage

Guanidine Hydrochloride storage and handling

Guanidine Hydrochloride safe storage

Well closed. Dry.

Source: ILO-WHO International Chemical Safety Cards (ICSCs)

Planning storage for a mix of chemicals? Check Guanidine Hydrochloride in the storage compatibility matrix →

09 · Questions

Guanidine Hydrochloride — frequently asked questions

What is the CAS number of Guanidine Hydrochloride?

The CAS number of Guanidine Hydrochloride is 50-01-1. Its EC number is 200-002-3.

What does a Guanidine Hydrochloride label have to show?

Under CLP Annex VI the label for Guanidine Hydrochloride carries the pictogram Exclamation mark and the signal word is Warning.

Is Guanidine Hydrochloride flammable?

CLP Annex VI assigns Guanidine Hydrochloride no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it.

Is Guanidine Hydrochloride a carcinogen?

CLP Annex VI records no harmonised carcinogenicity classification for Guanidine Hydrochloride. Annex VI is a list of agreed classifications, not a list of substances found safe, so this is an absence of a classification rather than a clean bill of health.

What is the melting point of Guanidine Hydrochloride?

The melting point reported for Guanidine Hydrochloride is 183 °C (361.4 °F) (DOE PAC).

Nearby

Substances next to Guanidine Hydrochloride

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