Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Isobenzan

Isobenzan is a whitish to light brown powder.

CAS 297-78-9 C9H4Cl8O 411.7 g/mol Danger

01 · Identification

What Isobenzan is

Isobenzan is a whitish to light brown powder. Its molecular formula is C9H4Cl8O and its molecular weight is 411.7 g/mol. It melts at 121 °C.

Under the GHS it carries the signal word Danger.

02 · Identifiers

Isobenzan identifiers and molecular data

Isobenzan CAS number and EC number

CAS number297-78-9
EC number206-045-4
Index number (CLP Annex VI)602-053-00-0

Isobenzan molecular formula and molecular weight

Molecular formulaC9H4Cl8O
Molecular weight411.7 g/mol

Other names for Isobenzan

  • isobenzan (ISO)
  • 1,3,4,5,6,7,8,8-octachloro-1,3,3a,4,7,7a-hexahydro-4,7-methanoisobenzofuran

03 · GHS classification

Isobenzan hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Isobenzan pictograms and signal word

Signal wordDanger

Isobenzan hazard class and category

GHS hazard classes Isobenzan falls into
Hazard class Category From code Pictogram
Acute toxicity - oral GHS chapter 3.1 Category 1 or 2 H300 GHS06
Acute toxicity - dermal GHS chapter 3.1 Category 1 or 2 H310 GHS06
Hazardous to the aquatic environment - acute GHS chapter 4.1 Category 1 H400 GHS09

Where two values are shown with “or”, the hazard statement is shared by more than one category or by more than one class, and the code alone does not say which. H272, for example, belongs to oxidising liquids and to oxidising solids — the physical state decides. The binding answer for a specific entry is in the CLP Annex VI table itself.

Isobenzan hazard statements (H-codes)

Hazard statements assigned to Isobenzan
CodeHazard statement
H310 Fatal in contact with skin.
H300 Fatal if swallowed.
H400 Very toxic to aquatic life.

This page lists only the codes assigned to Isobenzan. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for Isobenzan

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of Isobenzan issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

Isobenzan precautionary statements

CLP Annex VI assigns 10 precautionary statements to Isobenzan. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Disposal

What has to happen to the contents and the empty container.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

Isobenzan name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български изобензан (ISO) 1,3,4,5,6,7,8,8-октахлоро-1,3,3a,4,7,7a-хексахидро-4,7-метаноизобензофуран
Spanish español Isobenzán (ISO) 1,3,4,5,6,7,8,8-octacloro-1,3,3a,4,7,7a-hexahidro-4,7-metanoisobenzofurano
Czech čeština isobenzan (ISO) 1,3,4,5,6,7,8,8-oktachlor-3a,4,7,7a-hexahydro-4,7-methano-1 H ,3 H -isobenzofuran
Danish dansk isobenzan (ISO) 1,3,4,5,6,7,8,8-octachlor- 1,3,3a,4,7,7a-hexahydro-4,7- methanoisobenzofuran
German Deutsch Isobenzan (ISO) 1,3,4,5,6,7,8,8-Octachlor-1,3,3a,4,7,7a-hexahydro-4,7-methanoisobenzofuran
Estonian eesti isobensaan (ISO) 1,3,4,5,6,7,8,8-oktakloro-1,3,3a,4,7,7a-heksahüdro-4,7-metanoisobensofuraan
Greek ελληνικά isobenzan (ισοβενζάνη) (ISO) 1,3,4,5,6,7,8,8-οκταχλωρο-1,3,3a,4,7,7a-εξαϋδρο-4,7-μεθανοϊσοβενζοφουράνιο
English English isobenzan (ISO) 1,3,4,5,6,7,8,8-octachloro-1,3,3a,4,7,7a-hexahydro-4,7-methanoisobenzofuran
French français isobenzan (ISO) 1,3,4,5,6,7,8,8-octachloro-1,3,3a,4,7,7a-hexahydro-4,7-méthanoisobenzofurane
Croatian hrvatski izobenzan (ISO) 1,3,4,5,6,7,8,8-oktaklor-1,3,3a,4,7,7a-hekshidro-4,7-metanoizobenzofuran
Italian italiano isobenzan (ISO) 1,3,4,5,6,7,8,8-ottacloro-1,3,3a,4,7,7a-esaidro-4,7-metanoisobenzofurano
Latvian latviešu izobenzāns (ISO) 1,3,4,5,6,7,8,8-oktahlor-1,3,3a,4,7,7a-heksahidro-4,7-metanoizobenzfurāns
Lithuanian lietuvių izobenzanas (ISO) 1,3,4,5,6,7,8,8-oktachlor-1,3,3a,4,7,7a-heksahidro-4,7-metanoizobenzofuranas
Hungarian magyar izobenzán (ISO) 1,3,4,5,6,7,8,8-oktaklór-1,3,3a,4,7,7a-hexahidro-4,7-metanoizobenzofurán
Maltese Malti isobenżan (ISO) 1,3,4,5,6,7,8,8-ottakloro-1,3,3a,4,7,7a-eżaidro-4,7-metanoisobenżofuran
Dutch Nederlands isobenzan (ISO) 1,3,4,5,6,7,8,8-octachloor-1,3,3a,4,7,7a-hexahydro-4,7-methanoïsobenzofuran
Polish polski izobenzan (ISO) 1,3,4,5,6,7,8,8-oktachloro-1,3,3a,4,7,7a-heksahydro-4,7-metanoizobenzofuran
Portuguese português isobenzão (ISO) 1,3,4,5,6,7,8,8-octacloro-1,3,3a,4,7,7a-hexa-hidro-4,7-metanoisobenzofurano
Romanian română izobenzan (ISO) 1,3,4,5,6,7,8,8-octacloro-1,3,3a,4,7,7a-hexahidro- 4,7-metanoisobenzofuran
Slovak slovenčina izobenzán (ISO) 1,3,4,5,6,7,8,8-oktachlór-1,3,3a,4,7,7a-hexahydro-4,7-metanoizobenzofurán
Slovenian slovenščina izobenzan (ISO) 1,3,4,5,6,7,8,8-oktakloro-1,3,3a,4,7,7a-heksahidro-4,7-metanoizobenzofuran
Finnish suomi isobentsaani (ISO) 1,3,4,5,6,7,8,8-oktakloori-1,3,3a,4,7,7a-heksahydro-4,7-metaani-isobentsofuraani
Swedish svenska isobenzan (ISO) 1,3,4,5,6,7,8,8-oktaklor-1,3,3a,4,7,7a-hexahydro-4,7-metanoisobensofuran

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

Isobenzan GHS label elements

Everything CLP Annex VI fixes for Isobenzan, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS06 Skull and crossbones pictogramGHS09 Environment pictogram

Danger

Isobenzan

  • Fatal in contact with skin.
  • Fatal if swallowed.
  • Very toxic to aquatic life.
  • Do not eat, drink or smoke when using this product.
  • Avoid release to the environment.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • IF SWALLOWED:
  • IF ON SKIN:
  • Immediately call a POISON CENTER/doctor/
  • Rinse mouth.
  • Wash with plenty of water/
  • Collect spillage.
  • Dispose of contents/container to

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open Isobenzan in the GHS label constructor →

07 · Health hazards

Isobenzan health hazards and exposure limits

Isobenzan hazard summary

Highly toxic by skin absorption, inhalation, and ingestion; Very slowly eliminated by the human body, with a blood half-life of 2.77 years; May cause convulsions and seizures; [CAMEO] Over stimulates the CNS causing convulsions; Slowly eliminated by the body; [INCHEM] May cause irritation; [MSDSonline]

Source: Haz-Map, Information on Hazardous Chemicals and Occupational Diseases

08 · Physical and chemical properties

Isobenzan properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

Isobenzan melting point

Property Value Conditions Source
Melting point 121 °C (249.8 °F) range, midpoint shown HSDB
121.11 °C (250 °F) range, midpoint shown CAMEO

Isobenzan density

Property Value Conditions Source
Density 1.87 g/cm³ HSDB
1.87 g/cm³ at 25 °C DOE PAC

Isobenzan solubility

Property Value Conditions Source
Solubility Sol in ether, acetone, benzene, xylene, heavy aromatic naphtha HSDB
Greater than 1% in ethanol & kerosene HSDB

Isobenzan vapor pressure

Property Value Conditions Source
Vapor pressure 0.000003 mmHg at 20 °C HSDB
0.00000292 mmHg at 20 °C HSDB
0.00001 mmHg at 25 °C CAMEO

Isobenzan lower explosive limit (LEL)

Property Value Conditions Source
Lower explosive limit (LEL) Non-flammable and non-explosive. (EPA, 1998) CAMEO

Isobenzan upper explosive limit (UEL)

Property Value Conditions Source
Upper explosive limit (UEL) Non-flammable and non-explosive. (EPA, 1998) CAMEO

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

09 · Source notes

Further notes on Isobenzan

These are descriptions rather than measured values, so they are kept out of the table above and quoted here with the source that reported them.

Solubility

25 g/100 ml acetone at 25 °C, 38 g/100 ml benzene at 25 °C, 34 g/100 ml carbon tetrachloride at 25 °C, 2 g/100 ml fuel oil at 25 °C, 34 g/100 ml toluene at 25 °C, 29 g/100 ml xylene at 25 °C.

Source: HSDB

10 · Handling and storage

Isobenzan storage and handling

Isobenzan reactivity

Chlorine is evolved when ISOBENZAN is heated above 410F. Avoid acids, certain metal salts, and catalytically active carriers. [EPA, 1998].

Source: CAMEO Chemicals

Planning storage for a mix of chemicals? Check Isobenzan in the storage compatibility matrix →

11 · Questions

Isobenzan — frequently asked questions

What is the CAS number of Isobenzan?

The CAS number of Isobenzan is 297-78-9. Its EC number is 206-045-4.

What is the chemical formula of Isobenzan?

The molecular formula of Isobenzan is C9H4Cl8O and its molecular weight is 411.7 g/mol.

What does a Isobenzan label have to show?

Under CLP Annex VI the label for Isobenzan carries the pictograms Skull and crossbones and Environment and the signal word is Danger.

Is Isobenzan flammable?

CLP Annex VI assigns Isobenzan no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it.

Is Isobenzan a carcinogen?

CLP Annex VI records no harmonised carcinogenicity classification for Isobenzan. Annex VI is a list of agreed classifications, not a list of substances found safe, so this is an absence of a classification rather than a clean bill of health.

What is the melting point of Isobenzan?

The melting point reported for Isobenzan is 121 °C (249.8 °F), range, midpoint shown (HSDB).

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