Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Mercaptodimethur (ISO)

Mercaptodimethur (ISO) is colorless crystals with a phenol-like odor.

CAS 2032-65-7 Danger

01 · Identification

What Mercaptodimethur (ISO) is

Mercaptodimethur (ISO) is colorless crystals with a phenol-like odor. It boils at 325 °C, melts at 119 °C.

Under the GHS it carries the signal word Danger.

02 · Identifiers

Mercaptodimethur (ISO) identifiers and molecular data

Mercaptodimethur (ISO) CAS number and EC number

CAS number2032-65-7
EC number217-991-2
Index number (CLP Annex VI)006-023-00-2

Other names for Mercaptodimethur (ISO)

  • methiocarb (ISO)
  • 3,5-dimethyl-4-methylthiophenyl N-methylcarbamate

03 · GHS classification

Mercaptodimethur (ISO) hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Mercaptodimethur (ISO) pictograms and signal word

Signal wordDanger

Mercaptodimethur (ISO) hazard class and category

GHS hazard classes Mercaptodimethur (ISO) falls into
Hazard class Category From code Pictogram
Acute toxicity - oral GHS chapter 3.1 Category 3 H301 GHS06
Hazardous to the aquatic environment - acute GHS chapter 4.1 Category 1 H400 GHS09
Hazardous to the aquatic environment - chronic GHS chapter 4.1 Category 1 H410 GHS09

Mercaptodimethur (ISO) hazard statements (H-codes)

Hazard statements assigned to Mercaptodimethur (ISO)
CodeHazard statement
H301 Toxic if swallowed.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.

This page lists only the codes assigned to Mercaptodimethur (ISO). The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for Mercaptodimethur (ISO)

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of Mercaptodimethur (ISO) issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

Mercaptodimethur (ISO) precautionary statements

CLP Annex VI assigns 7 precautionary statements to Mercaptodimethur (ISO). They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Prevention

What to do before and during handling so the hazard never happens.

Disposal

What has to happen to the contents and the empty container.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

Mercaptodimethur (ISO) name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български меркаптодиметур (ISO) метиокарб (ISO)3,5-диметил-4-метилтиофенилов N -метилкарбамат
Spanish español Mercaptodimetur (ISO) metiocarb (ISO)N -metilcarbamato de 3,5-dimetil-4-metiltiofenilo
Czech čeština merkaptodimethur (ISO) methiokarb (ISO)3,5-dimethyl-4-(methylsulfanyl)fenyl- N -methylkarbamát
Danish dansk mercaptodimethur (ISO) methiocarb (ISO)4-methylthio-3,5-xylylmethylcarbamat methiocarb
German Deutsch Mercaptodimethur (ISO) Methiocarb (ISO)xylylmethylcarbamat3,5-Dimethyl-4- methylthiophenyl- N -methylcarbamat
Estonian eesti merkaptodimetuur (ISO) metiokarb (ISO)3,5-dimetüül-4-metüültiofenüül- N -metüülkarbamaat
Greek ελληνικά mercaptodimethur (μερκαπτοδιμεθούρη) (ISO) methiocarb (μεθειοκάρβη) (ISO)Ν -μεθυλοκαρβαμιδικός 3,5-διμεθυλο-4-μεθυλοθειοφαινυλεστέρας
English English mercaptodimethur (ISO) methiocarb (ISO)3,5-dimethyl-4-methylthiophenyl N -methylcarbamate
French français mercaptodiméthur (ISO) méthiocarbe (ISO)N -méthylcarbamate de 3,5-diméthyl-4-méthylthiophenyle
Croatian hrvatski merkaptodimetur (ISO) metiokarb (ISO)3,5-dimetil-4-metiltiofenil- N -metil-karbamat
Italian italiano mercaptodimetur (ISO) methiocarb metilcarbammato di 4-metiltio-3,5-xilile
Latvian latviešu merkaptodimetūrs (ISO) metiokars (ISO)3,5-dimetil-4-metiltiofenil- N -metilkarbamāts
Lithuanian lietuvių merkaptodimeturas (ISO) metiokarbas (ISO)3,5-dimetil-4-metiltiofenil N -metilkarbamatas
Hungarian magyar merkaptodimetur (ISO) metiokarb (ISO)3,5-dimetil-4-metiltiofenil- N -metilkarbamát
Maltese Malti merkattodimetur (ISO) metijokarb (ISO)N-metilkarbamat ta’ 3,5-dimetil-4-metiltijofenil
Dutch Nederlands mercaptodimethur (ISO) methiocarb (ISO)3,5-dimethyl-4-methylthiofenyl- N -methylcarbamaat
Polish polski merkaptodimetur (ISO) metiokarb (ISO)metylokarbaminian 3,5-dimetylo-4-(metylotio)fenylu
Portuguese português mercaptodimetur (ISO) metiocarbe (ISO)N -metilcarbamato de 3,5-dimetil-4-metiltiofenilo
Romanian română mercaptodimetur (ISO) metiocarb (ISO)N -metilcarbamat de 3,5-dimetil-4-metiltiofenil
Slovak slovenčina merkaptodimetur (ISO) metiokarb (ISO)O -[3,5-dimetyl-4-(metylsulfanyl)fenyl]- N -metylkarbamát
Slovenian slovenščina merkaptodimetur (ISO) metiokarb (ISO)3,5-dimetil-4-metiltiofenil N -metilkarbamat
Finnish suomi merkaptodimetuuri (ISO) metiokarbi (ISO)3,5-dimetyyli-4-(metyylitio)fenyyli- N -metyylikarbamaatti
Swedish svenska merkaptodimetur (ISO) metiokarb (ISO)3,5-dimetyl-4-metyltiofenyl- N -metylkarbamat

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

Mercaptodimethur (ISO) GHS label elements

Everything CLP Annex VI fixes for Mercaptodimethur (ISO), laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS06 Skull and crossbones pictogramGHS09 Environment pictogram

Danger

Mercaptodimethur (ISO)

  • Toxic if swallowed.
  • Very toxic to aquatic life.
  • Very toxic to aquatic life with long lasting effects.
  • Do not eat, drink or smoke when using this product.
  • Avoid release to the environment.
  • IF SWALLOWED:
  • Immediately call a POISON CENTER/doctor/
  • Rinse mouth.
  • Collect spillage.
  • Dispose of contents/container to

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open Mercaptodimethur (ISO) in the GHS label constructor →

07 · Health hazards

Mercaptodimethur (ISO) health hazards and exposure limits

Mercaptodimethur (ISO) hazard summary

May cause skin and mucous membrane irritation; [HSDB] No malformations in rats or rabbits at 10 mg/kg/day, but caused malformations in chickens and ducks; [REPROTOX] A reversible cholinesterase inhibitor; [CAMEO] May cause irritation; A cholinesterase inhibitor; Can be absorbed through skin; A lachrymator; Effects in high-dose animal studies include convulsions; [MSDSonline] Contact dermatitis reported in a carnation grower; [Kanerva, p. 1812; PMID 9197969 ] See CARBAMATE INSECTICIDES.

Source: Haz-Map, Information on Hazardous Chemicals and Occupational Diseases

Mercaptodimethur (ISO) carcinogenicity classification

Cancer Classification: Group D Not Classifiable as to Human Carcinogenicity

Source: Hazardous Substances Data Bank (HSDB)

An IARC group and a CLP classification answer different questions. IARC judges whether the evidence for cancer in humans is strong enough; CLP Annex VI is the legally binding EU classification. A substance can carry one and not the other.

08 · Physical and chemical properties

Mercaptodimethur (ISO) properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

Mercaptodimethur (ISO) boiling point

Property Value Conditions Source
Boiling point 325 °C (617 °F) at 760 mmHg DOE PAC
Very high. (USCG, 1999) CAMEO

Mercaptodimethur (ISO) melting point

Property Value Conditions Source
Melting point 119 °C (246.2 °F) HSDB
117.22 °C (243 °F) CAMEO

Mercaptodimethur (ISO) density

Property Value Conditions Source
Density 1 g/cm³ CAMEO

Mercaptodimethur (ISO) solubility

Property Value Conditions Source
Solubility 200 g/l in dichloromethane; 53 g/l in isopropanol; 33 g/l in toluene; 1.3 g/l in hexane HSDB
Soluble in organic solvents. HSDB
In water, 27 mg/l @ 20 °C at 20 °C HSDB

Mercaptodimethur (ISO) vapor pressure

Property Value Conditions Source
Vapor pressure 0.0001 mmHg CAMEO
1.125e-7 mmHg at 20 °C ICSC
2.7e-7 mmHg at 25 °C HSDB

Mercaptodimethur (ISO) lower explosive limit (LEL)

Property Value Conditions Source
Lower explosive limit (LEL) Dust may be explosive. HSDB

Mercaptodimethur (ISO) corrosivity

Property Value Conditions Source
Corrosivity Non-corrosive HSDB

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

09 · Fire and explosion

Mercaptodimethur (ISO) fire and explosion behaviour

These are descriptions rather than measured values, so they are kept out of the table above and quoted here with the source that reported them.

Mercaptodimethur (ISO) fire potential

Nonflammable.

Source: Hazardous Substances Data Bank (HSDB)

10 · Handling and storage

Mercaptodimethur (ISO) storage and handling

Mercaptodimethur (ISO) safe storage

Separated from food and feedstuffs. Store in an area without drain or sewer access. Provision to contain effluent from fire extinguishing.

Source: ILO-WHO International Chemical Safety Cards (ICSCs)

Mercaptodimethur (ISO) incompatible materials

Unstable in highly alkaline media.

Source: Hazardous Substances Data Bank (HSDB)

Mercaptodimethur (ISO) reactivity

MERCAPTODIMETHUR is a carbamate ester. Carbamates are chemically similar to, but more reactive than amides. Like amides they form polymers such as polyurethane resins. Carbamates are incompatible with strong acids and bases, and especially incompatible with strong reducing agents such as hydrides. Flammable gaseous hydrogen is produced by the combination of active metals or nitrides with carbamates. Strongly oxidizing acids, peroxides, and hydroperoxides are incompatible with carbamates.

Source: CAMEO Chemicals

Planning storage for a mix of chemicals? Check Mercaptodimethur (ISO) in the storage compatibility matrix →

11 · Questions

Mercaptodimethur (ISO) — frequently asked questions

What is the CAS number of Mercaptodimethur (ISO)?

The CAS number of Mercaptodimethur (ISO) is 2032-65-7. Its EC number is 217-991-2.

What does a Mercaptodimethur (ISO) label have to show?

Under CLP Annex VI the label for Mercaptodimethur (ISO) carries the pictograms Skull and crossbones and Environment and the signal word is Danger.

Is Mercaptodimethur (ISO) flammable?

CLP Annex VI assigns Mercaptodimethur (ISO) no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it.

Is Mercaptodimethur (ISO) a carcinogen?

CLP Annex VI records no harmonised carcinogenicity classification for Mercaptodimethur (ISO). Annex VI is a list of agreed classifications, not a list of substances found safe, so this is an absence of a classification rather than a clean bill of health.

What is the boiling point of Mercaptodimethur (ISO)?

The boiling point reported for Mercaptodimethur (ISO) is 325 °C (617 °F), at 760 mmHg (DOE PAC).

What is the melting point of Mercaptodimethur (ISO)?

The melting point reported for Mercaptodimethur (ISO) is 119 °C (246.2 °F) (HSDB).

Nearby

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