Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Methylenebisacrylamide

Methylenebisacrylamide: n,n'-methylenebisacrylamide is a white crystalline powder with a neutral odor.

CAS 110-26-9 C7H10N2O2 154.17 g/mol Danger

01 · Identification

What Methylenebisacrylamide is

Methylenebisacrylamide: n,n'-methylenebisacrylamide is a white crystalline powder with a neutral odor. Its molecular formula is C7H10N2O2 and its molecular weight is 154.17 g/mol. It melts at 185 °C.

Under the GHS it carries the signal word Danger.

02 · Identifiers

Methylenebisacrylamide identifiers and molecular data

Methylenebisacrylamide CAS number and EC number

CAS number110-26-9
EC number203-750-9
Index number (CLP Annex VI)616-243-00-6

Methylenebisacrylamide molecular formula and molecular weight

Molecular formulaC7H10N2O2
Molecular weight154.17 g/mol

Other names for Methylenebisacrylamide

  • N,N'-methylenediacrylamide

03 · GHS classification

Methylenebisacrylamide hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Methylenebisacrylamide pictograms and signal word

Signal wordDanger

Methylenebisacrylamide hazard class and category

GHS hazard classes Methylenebisacrylamide falls into
Hazard class Category From code Pictogram
Germ cell mutagenicity GHS chapter 3.5 Category 1A or 1B H340 GHS08

Where two values are shown with “or”, the hazard statement is shared by more than one category or by more than one class, and the code alone does not say which. H272, for example, belongs to oxidising liquids and to oxidising solids — the physical state decides. The binding answer for a specific entry is in the CLP Annex VI table itself.

Methylenebisacrylamide hazard statements (H-codes)

Hazard statements assigned to Methylenebisacrylamide
CodeHazard statement
H340 May cause genetic defects <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.

This page lists only the codes assigned to Methylenebisacrylamide. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for Methylenebisacrylamide

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of Methylenebisacrylamide issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

Methylenebisacrylamide precautionary statements

CLP Annex VI assigns 4 precautionary statements to Methylenebisacrylamide. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Response

What to do once exposure, spillage or fire has already happened.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

Methylenebisacrylamide name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български N, N’ -метилендиакриламид
Spanish español N,N’ -Metilenodiacrilamida
Czech čeština N,N’ -methylendiakrylamid
Danish dansk N,N' -methylendiacrylamid
German Deutsch N,N’ -Methylendiacrylamid
Estonian eesti N,N’ -metüleendiakrüülamiid
Greek ελληνικά N,N’ -μεθυλενοδιακρυλαμίδιο
English English N,N' -methylenediacrylamide
French français N,N’ -méthylènediacrylamide
Croatian hrvatski N,N’ -metilendiakrilamid
Italian italiano N,N’ -metilendiacrilammide
Latvian latviešu N,N’ -metilēndiakrilamīds
Lithuanian lietuvių N,N' -metilendiakrilamidas
Hungarian magyar N,N’ -metiléndiakrilamid
Maltese Malti N,N’ -metilendiakrilammid
Dutch Nederlands N,N' -methyleendiacrylamide
Polish polski N,N’ -metylenodiakrylamid
Portuguese português N,N’ -metilenodiacrilamida
Romanian română N, N’ -metilendiacrilamidă
Slovak slovenčina N,N’ -metyléndiakrylamid
Slovenian slovenščina N,N’ -metilendiakrilamid
Finnish suomi N,N’-metyleenidiakryyliamidi
Swedish svenska N,N’ -metylendiakrylamid

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

Methylenebisacrylamide GHS label elements

Everything CLP Annex VI fixes for Methylenebisacrylamide, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS08 Health hazard pictogram

Danger

Methylenebisacrylamide

  • May cause genetic defects <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
  • Obtain special instructions before use.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • IF exposed or concerned:
  • Get medical advice/attention.

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open Methylenebisacrylamide in the GHS label constructor →

07 · Health hazards

Methylenebisacrylamide health hazards and exposure limits

Methylenebisacrylamide hazard summary

May cause skin and eye irritation and symptoms indicative of nervous system effects; [NTP] May cause irritation; Harmful by ingestion and inhalation; May cause reproductive disorders, based on animal studies; [Sigma-Aldrich MSDS] See Acrylamide.

Source: Haz-Map, Information on Hazardous Chemicals and Occupational Diseases

08 · Physical and chemical properties

Methylenebisacrylamide properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

Methylenebisacrylamide melting point

Property Value Conditions Source
Melting point 185 °C (365 °F) decomposes CAMEO

Methylenebisacrylamide density

Property Value Conditions Source
Density 1.235 g/cm³ at 30 °C CAMEO

Methylenebisacrylamide solubility

Property Value Conditions Source
Solubility 0.1 to 1 mg/mL at 64 °F (NTP, 1992) at 17.78 °C CAMEO

Methylenebisacrylamide vapor density

Property Value Conditions Source
Vapor density 5.31 (air = 1) CAMEO

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

09 · Handling and storage

Methylenebisacrylamide storage and handling

Methylenebisacrylamide reactivity

N,N'-METHYLENEBISACRYLAMIDE is incompatible with strong oxidizers, strong acids and strong bases. (NTP, 1992)

Source: CAMEO Chemicals

Planning storage for a mix of chemicals? Check Methylenebisacrylamide in the storage compatibility matrix →

10 · Questions

Methylenebisacrylamide — frequently asked questions

What is the CAS number of Methylenebisacrylamide?

The CAS number of Methylenebisacrylamide is 110-26-9. Its EC number is 203-750-9.

What is the chemical formula of Methylenebisacrylamide?

The molecular formula of Methylenebisacrylamide is C7H10N2O2 and its molecular weight is 154.17 g/mol.

What does a Methylenebisacrylamide label have to show?

Under CLP Annex VI the label for Methylenebisacrylamide carries the pictogram Health hazard and the signal word is Danger.

Is Methylenebisacrylamide flammable?

CLP Annex VI assigns Methylenebisacrylamide no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it.

Is Methylenebisacrylamide a carcinogen?

CLP Annex VI records no harmonised carcinogenicity classification for Methylenebisacrylamide. Annex VI is a list of agreed classifications, not a list of substances found safe, so this is an absence of a classification rather than a clean bill of health.

What is the melting point of Methylenebisacrylamide?

The melting point reported for Methylenebisacrylamide is 185 °C (365 °F), decomposes (CAMEO).

Nearby

Substances next to Methylenebisacrylamide

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