Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Monobenzone

Monobenzone is lustrous leaflets from water and is odorless.

CAS 103-16-2 C13H12O2 200.23 g/mol Warning

01 · Identification

What Monobenzone is

Monobenzone is lustrous leaflets from water and is odorless. Its molecular formula is C13H12O2 and its molecular weight is 200.23 g/mol. It melts at 123 °C.

Under the GHS it carries the signal word Warning.

02 · Identifiers

Monobenzone identifiers and molecular data

Monobenzone CAS number and EC number

CAS number103-16-2
EC number203-083-3
Index number (CLP Annex VI)604-043-00-1

Monobenzone molecular formula and molecular weight

Molecular formulaC13H12O2
Molecular weight200.23 g/mol

Other names for Monobenzone

  • 4-hydroxyphenyl benzyl ether
  • hydroquinone monobenzyl ether

03 · GHS classification

Monobenzone hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Monobenzone pictograms and signal word

Signal wordWarning

Monobenzone hazard class and category

GHS hazard classes Monobenzone falls into
Hazard class Category From code Pictogram
Serious eye damage/eye irritation GHS chapter 3.3 Category 2A H319 GHS07
Skin sensitisation GHS chapter 3.4 Category 1 or 1A or 1B H317 GHS07

Where two values are shown with “or”, the hazard statement is shared by more than one category or by more than one class, and the code alone does not say which. H272, for example, belongs to oxidising liquids and to oxidising solids — the physical state decides. The binding answer for a specific entry is in the CLP Annex VI table itself.

Monobenzone hazard statements (H-codes)

Hazard statements assigned to Monobenzone
CodeHazard statement
H319 Causes serious eye irritation.
H317 May cause an allergic skin reaction.

This page lists only the codes assigned to Monobenzone. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for Monobenzone

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of Monobenzone issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

Monobenzone precautionary statements

CLP Annex VI assigns 9 precautionary statements to Monobenzone. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

Monobenzone name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български монобензон бензил-4-хидроксифенилов етермонобензилов етер на хидрохинона
Spanish español Monobenzona éter de 4-hidroxifenilo y benciloéter monobencílico de hidroquinona
Czech čeština monobenzon 4-(benzyloxy)fenolhydrochinonmonobenzylether
Danish dansk monobenzon 4-hydroxyphenyl benzyletherhydroquinon monobenzylether
German Deutsch Monobenzon 4-HydroxyphenylbenzyletherHydrochinonmonobenzylether
Estonian eesti monobensoon 4-hüdroksüfenüülbensüüleeterhüdrokinooni monobensüüleeter
Greek ελληνικά μονοβενζόνη 4-υδροξυφαινυλο-βενζυλαιθέραςμονοβενζυλαιθέρας υδροκινόνης
English English monobenzone 4-hydroxyphenyl benzyl etherhydroquinone monobenzyl ether
French français monobenzone oxyde de 4-hydroxyphényle et de benzyleéther monobenzylique de l'hydroquinone
Croatian hrvatski monobenzon 4-hidroksifenil-benzil-eterhidrokinon-monobenzil-eter
Italian italiano monobenzone 4-idrossifenil benzil eteremonobenzil etere dell'idrochinone
Latvian latviešu monobenzons 4-hidroksifenilbenzilēterishidrohinona monobenzilēteris
Lithuanian lietuvių monobenzonas 4-hidroksifenilbenzilo eterishidrochinono monobenzileteris
Hungarian magyar monobenzon 4-hidroxifenil-benzil-éterhidrokinon-monobenzil-éter
Maltese Malti monobenżon eter tal-benżil ta’ 4-idrossifenileter tal-monobenżil tal-idrokinon
Dutch Nederlands monobenzon 4-hydroxyfenylbenzyletherhydrochinonmonobenzylether
Polish polski monobenzon eter benzylowo-4-hydroksyfenylowyeter monobenzylowy hydrochinonu4-benzyloksyfenol
Portuguese português monobenzona éter benzílico e 4-hidroxifenílicoéter monobenzílico de hidroquinona
Romanian română monobenzonă 4-hidroxifenil-benzil-etereterul monobenzilic al hidrochinonei
Slovak slovenčina monobenzón benzyl(4-hydroxyfenyl)éter4-(benzyloxy)fenol
Slovenian slovenščina monobenzon 4-hidroksifenil benzil eterhidrokinon monobenzil eter
Finnish suomi monobentsoni 4-hydroksifenyylibentsyylieetterihydrokinonimonobentsyylieetteri
Swedish svenska monobenson 4-hydroxifenylbensyleterhydrokinonmonobensyleter

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

Monobenzone GHS label elements

Everything CLP Annex VI fixes for Monobenzone, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS07 Exclamation mark pictogram

Warning

Monobenzone

  • Causes serious eye irritation.
  • May cause an allergic skin reaction.
  • Avoid breathing dust/fume/gas/mist/vapours/spray.
  • Wash thoroughly after handling.
  • Contaminated work clothing should not be allowed out of the workplace.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • IF IN EYES:
  • Get medical advice/attention.
  • If skin irritation or rash occurs:
  • If eye irritation persists:
  • Remove contact lenses, if present and easy to do. Continue rinsing.

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open Monobenzone in the GHS label constructor →

07 · Physical and chemical properties

Monobenzone properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

Monobenzone melting point

Property Value Conditions Source
Melting point 122.5 °C (252.5 °F) HSDB
122 °C (251.6 °F) DrugBank
114 °C (237.2 °F) range, midpoint shown HMDB

Monobenzone density

Property Value Conditions Source
Density 1.26 g/cm³ HSDB

Monobenzone solubility

Property Value Conditions Source
Solubility SOLUBILITY IN BOILNG WATER ABOUT 1.0 G/100 ML; SOL IN ALC, ETHER, BENZENE HSDB
INSOL IN WATER HSDB
FREELY SOL IN ACETONE HSDB

Monobenzone vapor pressure

Property Value Conditions Source
Vapor pressure 0.0000225 mmHg Haz-Map

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

08 · Questions

Monobenzone — frequently asked questions

What is the CAS number of Monobenzone?

The CAS number of Monobenzone is 103-16-2. Its EC number is 203-083-3.

What is the chemical formula of Monobenzone?

The molecular formula of Monobenzone is C13H12O2 and its molecular weight is 200.23 g/mol.

What does a Monobenzone label have to show?

Under CLP Annex VI the label for Monobenzone carries the pictogram Exclamation mark and the signal word is Warning.

Is Monobenzone flammable?

CLP Annex VI assigns Monobenzone no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it.

Is Monobenzone a carcinogen?

CLP Annex VI records no harmonised carcinogenicity classification for Monobenzone. Annex VI is a list of agreed classifications, not a list of substances found safe, so this is an absence of a classification rather than a clean bill of health.

What is the melting point of Monobenzone?

The melting point reported for Monobenzone is 122.5 °C (252.5 °F) (HSDB).

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