Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Pyridine, alkyl derivs.

Pyridine, alkyl derivs. is a substance with a harmonised classification under EU CLP.

CAS 68391-11-7 Danger

01 · Identification

What Pyridine, alkyl derivs. is

Pyridine, alkyl derivs. is a substance with a harmonised classification under EU CLP.

Under the GHS it carries the signal word Danger.

02 · Identifiers

Pyridine, alkyl derivs. identifiers and molecular data

Pyridine, alkyl derivs. CAS number and EC number

CAS number68391-11-7
EC number269-929-9
Index number (CLP Annex VI)648-029-00-3

Other names for Pyridine, alkyl derivs.

  • Crude Tar Bases
  • [The complex combination of polyalkylated pyridines derived from coal tar distillation or as high-boiling distillates approximately above 150°C (302°F) from the reaction of ammonia with acetaldehyde, formaldehyde or paraformaldehyde.]

03 · GHS classification

Pyridine, alkyl derivs. hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Pyridine, alkyl derivs. pictograms and signal word

Signal wordDanger

Pyridine, alkyl derivs. hazard class and category

GHS hazard classes Pyridine, alkyl derivs. falls into
Hazard class Category From code Pictogram
Germ cell mutagenicity GHS chapter 3.5 Category 1A or 1B H340 GHS08
Carcinogenicity GHS chapter 3.6 Category 1A or 1B H350 GHS08

Where two values are shown with “or”, the hazard statement is shared by more than one category or by more than one class, and the code alone does not say which. H272, for example, belongs to oxidising liquids and to oxidising solids — the physical state decides. The binding answer for a specific entry is in the CLP Annex VI table itself.

Pyridine, alkyl derivs. hazard statements (H-codes)

Hazard statements assigned to Pyridine, alkyl derivs.
CodeHazard statement
H350 May cause cancer <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
H340 May cause genetic defects <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.

This page lists only the codes assigned to Pyridine, alkyl derivs.. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for Pyridine, alkyl derivs.

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of Pyridine, alkyl… issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

Pyridine, alkyl derivs. precautionary statements

CLP Annex VI assigns 4 precautionary statements to Pyridine, alkyl derivs.. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Response

What to do once exposure, spillage or fire has already happened.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

Pyridine, alkyl derivs. name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български Пиридин, алкилови производни сурови катранени основи
Spanish español Piridina, derivados alquílicos bases de alquitrán crudo
Czech čeština pyridin, alkylhomology surové dehtové báze
Danish dansk pyridin, alkylderivater råtjærebaser
German Deutsch Pyridin, Alkylderivate Roh-Teerbasen
Estonian eesti püridiin, alküülderivaadid töötlemata tõrvaalused
Greek ελληνικά Αλκυλοπαράγωγα πυριδίνης Ακατέργαστες βάσεις πίσσας
English English Pyridine, alkyl derivs. Crude Tar Bases
French français Pyridine, dérivés alkylés bases de goudron de brut
Croatian hrvatski piridin, alkil-derivati sirove katranske baze
Italian italiano piridina, alchil-derivati basi di catrame grezze
Latvian latviešu Piridīns, alkilatvasinājumi Jēldarvas bāzes
Lithuanian lietuvių Piridinas, alkildariniai Žalios alyvos bazės
Hungarian magyar Piridin, alkilszárm Nyers kátrány bázisok
Maltese Malti Piridina, derivi. tal-alkil Bażijiet tal-Qatran Mhux Raffinat
Dutch Nederlands pyridine, alkylderivaten ruwe teerbasen
Polish polski Pirydyna, pochodne alkilowe Surowe zasady smołowe
Portuguese português piridina, derivados alquílicos bases de alcatrão brutas
Romanian română Piridina, derivați alchilici Gudroane bazice brute
Slovak slovenčina alkyderiváty pyridínu surové dechtové zásady
Slovenian slovenščina piridin, alkilni derivati surove katranske bazeKompleksna mešanica polialkiliranih piridinov, dobljenih iz destilacije premogovega katrana ali kot destilati z visokim vreliščem približno nad 150 o C (302 o F) iz reakcije amonijaka z acetaldehidom, formaldehidom ali paraformaldehidom.]
Finnish suomi Pyridiini, alkyylijohdokset Raakatervaemäkset
Swedish svenska Pyridin, alkylderivat Råtjärbaser

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

Pyridine, alkyl derivs. GHS label elements

Everything CLP Annex VI fixes for Pyridine, alkyl derivs., laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS08 Health hazard pictogram

Danger

Pyridine, alkyl derivs.

  • May cause cancer <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
  • May cause genetic defects <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
  • Obtain special instructions before use.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • IF exposed or concerned:
  • Get medical advice/attention.

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open Pyridine, alkyl derivs. in the GHS label constructor →

07 · Transport

Pyridine, alkyl derivs. UN number and transport classification

Transport classification is a separate system from the GHS classification above. It decides how a package is marked and how a load may be carried; it does not follow from the workplace label, and the workplace label does not follow from it. The entries below are linked by CAS number, never by name.

Pyridine, alkyl derivs. under UN 1282 — shipping name, class and packing group

Europe · ADR 2025, Table A

Proper shipping name (3.1.2) Class Classification code PG Labels (column 5)
PYRIDINE 3 F1 II
  • ADR label model 3 — Flammable liquid
3

Source: ADR 2025, Table A of Chapter 3.2 · ECE/TRANS/352 Vol. I (UNECE). Class 3 is “Flammable liquids” (ADR 2.1.1.1).

Proper shipping name (column 2) Class or division PG Labels (column 6)
Pyridine 3 II
  • US DOT FLAMMABLE LIQUID label (§172.419)
3

Source: 49 CFR 172.101 Hazardous Materials Table · eCFR, revision 2026-08-03. Class 3 is “Flammable and combustible liquid” (49 CFR 173.2).

Full UN 1282 entry — special provisions, packing instructions, quantity limits and the orange plate →

08 · Questions

Pyridine, alkyl derivs. — frequently asked questions

What is the CAS number of Pyridine, alkyl derivs.?

The CAS number of Pyridine, alkyl derivs. is 68391-11-7. Its EC number is 269-929-9.

What does a Pyridine, alkyl derivs. label have to show?

Under CLP Annex VI the label for Pyridine, alkyl derivs. carries the pictogram Health hazard and the signal word is Danger.

Is Pyridine, alkyl derivs. flammable?

CLP Annex VI assigns Pyridine, alkyl derivs. no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it.

Is Pyridine, alkyl derivs. a carcinogen?

Yes. CLP Annex VI classifies Pyridine, alkyl derivs. as a category 1A or 1B carcinogen and assigns it H350: may cause cancer.

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