Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

(S)-(-)-2-Chloropropionic acid

(S)-(-)-2-Chloropropionic acid is a chemical substance with the molecular formula C3H5ClO2.

CAS 29617-66-1 C3H5ClO2 108.52 g/mol Danger

01 · Identification

What (S)-(-)-2-Chloropropionic acid is

(S)-(-)-2-Chloropropionic acid is a chemical substance with the molecular formula C3H5ClO2. Its molecular formula is C3H5ClO2 and its molecular weight is 108.52 g/mol.

Under the GHS it carries the signal word Danger.

02 · Identifiers

(S)-(-)-2-Chloropropionic acid identifiers and molecular data

(S)-(-)-2-Chloropropionic acid CAS number and EC number

CAS number29617-66-1
EC number411-150-5
Index number (CLP Annex VI)607-325-00-2

(S)-(-)-2-Chloropropionic acid molecular formula and molecular weight

Molecular formulaC3H5ClO2
Molecular weight108.52 g/mol

Other names for (S)-(-)-2-Chloropropionic acid

  • (S)-2-chloropropionic acid

03 · GHS classification

(S)-(-)-2-Chloropropionic acid hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

(S)-(-)-2-Chloropropionic acid pictograms and signal word

Signal wordDanger

(S)-(-)-2-Chloropropionic acid hazard class and category

GHS hazard classes (S)-(-)-2-Chloropropionic… falls into
Hazard class Category From code Pictogram
Acute toxicity - oral GHS chapter 3.1 Category 4 H302 GHS07
Acute toxicity - dermal GHS chapter 3.1 Category 4 H312 GHS07
Skin corrosion/irritation GHS chapter 3.2 Category 1A or 1B or 1C H314 GHS05

Where two values are shown with “or”, the hazard statement is shared by more than one category or by more than one class, and the code alone does not say which. H272, for example, belongs to oxidising liquids and to oxidising solids — the physical state decides. The binding answer for a specific entry is in the CLP Annex VI table itself.

(S)-(-)-2-Chloropropionic acid hazard statements (H-codes)

Hazard statements assigned to (S)-(-)-2-Chloropropionic…
CodeHazard statement
H312 Harmful in contact with skin.
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.

This page lists only the codes assigned to (S)-(-)-2-Chloropropionic…. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for (S)-(-)-2-Chloropropionic…

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of (S)-(-)-2-Chloropropio… issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

(S)-(-)-2-Chloropropionic acid precautionary statements

CLP Annex VI assigns 10 precautionary statements to (S)-(-)-2-Chloropropionic…. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

(S)-(-)-2-Chloropropionic acid name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български ( S )-2-хлоропропионова киселина
Spanish español Ácido ( S )-2-cloropropiónico
Czech čeština ( S )-2-chlorpropanová kyselina
Danish dansk ( S )-2-chlorpropionsyre
German Deutsch ( S )-2-Chlorpropionsäure
Estonian eesti ( S )-2-kloropropioonhape
Greek ελληνικά (S)-2-χλωροπροπιονικό οξύ
English English ( S )-2-chloropropionic acid
French français acide ( S )-2-chloropropionique
Croatian hrvatski ( S )-2-klorpropionska kiselina
Italian italiano (acido ( S )-2-cloropropionico
Latvian latviešu ( S )-2-hlorpropionskābe
Lithuanian lietuvių ( S )-2-chlorpropano rūgštis
Hungarian magyar ( S )-2-klórpropionsav
Maltese Malti aċidu ( S )-2-kloropropjoniku
Dutch Nederlands ( S )-2-chloorpropionzuur
Polish polski kwas (S)-2-chloropropanowy
Portuguese português ácido ( S )-2-cloropropiónico
Romanian română ( S )-acid 2-cloropropionic
Slovak slovenčina kyselina ( S )-2-chlórpropánová
Slovenian slovenščina ( S )-2-kloropropionska kislina
Finnish suomi ( S )-2-klooripropionihappo
Swedish svenska ( S )-2-klorpropionsyra

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

(S)-(-)-2-Chloropropionic acid GHS label elements

Everything CLP Annex VI fixes for (S)-(-)-2-Chloropropionic…, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS05 Corrosion pictogramGHS07 Exclamation mark pictogram

Danger

(S)-(-)-2-Chloropropionic acid

  • Harmful in contact with skin.
  • Harmful if swallowed.
  • Causes severe skin burns and eye damage.
  • Do not breathe dust/fume/gas/mist/vapours/spray.
  • Do not eat, drink or smoke when using this product.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • IF SWALLOWED:
  • IF ON SKIN:
  • Immediately call a POISON CENTER/doctor/
  • Call a POISON CENTER/doctor/ if you feel unwell.
  • Rinse mouth.
  • Do NOT induce vomiting.
  • Wash with plenty of water/

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open (S)-(-)-2-Chloropropionic… in the GHS label constructor →

07 · Transport

(S)-(-)-2-Chloropropionic acid UN number and transport classification

Transport classification is a separate system from the GHS classification above. It decides how a package is marked and how a load may be carried; it does not follow from the workplace label, and the workplace label does not follow from it. The entries below are linked by CAS number, never by name.

(S)-(-)-2-Chloropropionic acid under UN 2511 — shipping name, class and packing group

Europe · ADR 2025, Table A

Proper shipping name (3.1.2) Class Classification code PG Labels (column 5)
2-CHLOROPROPIONIC ACID 8 C3 III
  • ADR label model 8 — Corrosive substance
8

Source: ADR 2025, Table A of Chapter 3.2 · ECE/TRANS/352 Vol. I (UNECE). Class 8 is “Corrosive substances” (ADR 2.1.1.1).

Proper shipping name (column 2) Class or division PG Labels (column 6)
2-Chloropropionic acid 8 III
  • US DOT CORROSIVE label (§172.442)
8

Source: 49 CFR 172.101 Hazardous Materials Table · eCFR, revision 2026-08-03. Class 8 is “Corrosive material” (49 CFR 173.2).

Full UN 2511 entry — special provisions, packing instructions, quantity limits and the orange plate →

08 · Questions

(S)-(-)-2-Chloropropionic acid — frequently asked questions

What is the CAS number of (S)-(-)-2-Chloropropionic acid?

The CAS number of (S)-(-)-2-Chloropropionic acid is 29617-66-1. Its EC number is 411-150-5.

What is the chemical formula of (S)-(-)-2-Chloropropionic acid?

The molecular formula of (S)-(-)-2-Chloropropionic acid is C3H5ClO2 and its molecular weight is 108.52 g/mol.

What does a (S)-(-)-2-Chloropropionic acid label have to show?

Under CLP Annex VI the label for (S)-(-)-2-Chloropropionic acid carries the pictograms Corrosion and Exclamation mark and the signal word is Danger.

Is (S)-(-)-2-Chloropropionic acid flammable?

CLP Annex VI assigns (S)-(-)-2-Chloropropionic acid no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it.

Is (S)-(-)-2-Chloropropionic acid a carcinogen?

CLP Annex VI records no harmonised carcinogenicity classification for (S)-(-)-2-Chloropropionic acid. Annex VI is a list of agreed classifications, not a list of substances found safe, so this is an absence of a classification rather than a clean bill of health.

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