Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Silver massive: [particle diameter ≥ 1 mm]

Silver massive: [particle diameter ≥ 1 mm] is a white metal, face-centered cubic structure.

CAS 7440-22-4 Ag 107.868 g/mol Warning

01 · Identification

What Silver massive: [particle… is

Silver massive: [particle diameter ≥ 1 mm] is a white metal, face-centered cubic structure. Its molecular formula is Ag and its molecular weight is 107.868 g/mol. It boils at 2000 °C, melts at 961 °C, is practically insoluble in water.

Under the GHS it carries the signal word Warning. It is classed as flammable agents - 3rd degree.

02 · Identifiers

Silver massive: [particle… identifiers and molecular data

Silver massive: [particle… CAS number and EC number

CAS number7440-22-4
EC number231-131-3
Index number (CLP Annex VI)047-004-00-9

Silver massive: [particle… molecular formula and molecular weight

Molecular formulaAg
Molecular weight107.868 g/mol
Chemical class Flammable agents - 3rd degree

03 · GHS classification

Silver massive: [particle… hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Silver massive: [particle… pictograms and signal word

Signal wordWarning

Silver massive: [particle… hazard class and category

GHS hazard classes Silver massive: [particle… falls into
Hazard class Category From code Pictogram
Specific target organ toxicity - repeated exposure GHS chapter 3.9 Category 2 H373 GHS08

Silver massive: [particle… hazard statements (H-codes)

Hazard statements assigned to Silver massive: [particle…
CodeHazard statement
H361f Suspected of damaging fertility.
H373 May cause damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.

This page lists only the codes assigned to Silver massive: [particle…. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for Silver massive: [particle…

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of Silver massive… issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

Silver massive: [particle… precautionary statements

CLP Annex VI assigns 3 precautionary statements to Silver massive: [particle…. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Prevention

What to do before and during handling so the hazard never happens.

Response

What to do once exposure, spillage or fire has already happened.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

Silver massive: [particle… name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български сребро в масивна форма
Spanish español Plata masiva
Czech čeština celistvé stříbro
Danish dansk sølv i massiv form
German Deutsch Silbermasse
Estonian eesti massiivne hõbe
Greek ελληνικά συμπαγής άργυρος
English English silver massive
French français argent massif
Croatian hrvatski srebro u čvrstom stanju
Italian italiano argento massiccio
Latvian latviešu viengabala sudrabs
Lithuanian lietuvių masyvios formos sidabras
Hungarian magyar tömör ezüst
Maltese Malti fidda f’forma massiva
Dutch Nederlands massief zilver
Polish polski srebro w postaci litej
Portuguese português prata maciça
Romanian română argint masiv
Slovak slovenčina celistvé striebro
Slovenian slovenščina masivno srebro
Finnish suomi hopea massiivimuodossa
Swedish svenska massivt silver

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

Silver massive: [particle… GHS label elements

Everything CLP Annex VI fixes for Silver massive: [particle…, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS08 Health hazard pictogram

Warning

Silver massive: [particle…

  • Suspected of damaging fertility.
  • May cause damage to organs <or state all organs affected, if known> through prolonged or repeated exposure <state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard>.
  • Do not breathe dust/fume/gas/mist/vapours/spray.
  • Do not eat, drink or smoke when using this product.
  • Get medical advice/attention if you feel unwell.

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open Silver massive: [particle… in the GHS label constructor →

07 · Health hazards

Silver massive: [particle… health hazards and exposure limits

Silver massive: [particle… hazard summary

Silver is a naturally occurring element. It is found in the environment combined with other elements such as sulfide, chloride, and nitrate. Pure silver is "silver" colored, but silver nitrate and silver chloride are powdery white and silver sulfide and silver oxide are dark-gray to black. Silver is often found as a by-product during the retrieval of copper, lead, zinc, and gold ores. Silver is used to make jewelry, silverware, electronic equipment, and dental fillings. It is also used to make photographs, in brazing alloys and solders, to disinfect drinking water and water in swimming pools, and as an antibacterial agent. Silver has also been used in lozenges and chewing gum to help people stop smoking.

Source: Agency for Toxic Substances and Disease Registry (ATSDR)

Silver massive: [particle… carcinogenicity classification

Cancer Classification: Group D Not Classifiable as to Human Carcinogenicity

Source: Hazardous Substances Data Bank (HSDB)

CLASSIFICATION: D; not classifiable as to human carcinogenicity. BASIS FOR CLASSIFICATION: In animals local sarcomas have been induced after implantation of foils and disks of silver. However, the interpretation of these findings has been questioned due to the phenomenon of solid-state carcinogenesis in which even insoluble solids such as plastic have been shown to result in local fibrosarcomas. ANIMAL CARCINOGENICITY DATA: Inadequate .

Source: Hazardous Substances Data Bank (HSDB)

An IARC group and a CLP classification answer different questions. IARC judges whether the evidence for cancer in humans is strong enough; CLP Annex VI is the legally binding EU classification. A substance can carry one and not the other.

Silver massive: [particle… occupational exposure limits

US occupational exposure limits reported for Silver massive: [particle…. PEL is enforceable (OSHA), REL is a recommendation (NIOSH), IDLH is the concentration at which escape becomes impossible without injury.
Limit Value Source
PEL 0.01 [mg/m3], as Ag Haz-Map, Information on Hazardous Chemicals and Occupational Diseases
PEL 0.01 mg/m³ Occupational Safety and Health Administration (OSHA)
PEL TWA 0.01 mg/m3 The National Institute for Occupational Safety and Health (NIOSH)
REL 0.01 mg/m³ Occupational Safety and Health Administration (OSHA)
REL TWA 0.01 mg/m3 The National Institute for Occupational Safety and Health (NIOSH)
IDLH 10 mg Ag/m3 (NIOSH, 2024) CAMEO Chemicals
IDLH 10.0 [mg/m3], as Ag Haz-Map, Information on Hazardous Chemicals and Occupational Diseases
IDLH 10 mg/cu m (as ag). /Silver (metal dust and soluble compounds, as Ag)/ Hazardous Substances Data Bank (HSDB)

These are United States values. The European Union sets its own indicative and binding limits, and the figure that applies at a given workplace is the one in the local regulation — not the one shown here.

08 · Physical and chemical properties

Silver massive: [particle… properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

Silver massive: [particle… boiling point

Property Value Conditions Source
Boiling point 2000 °C (3632 °F) NIOSH
2212 °C (4014 °F) at 760 mmHg CAMEO
2212 °C (4013.6 °F) ICSC

Silver massive: [particle… melting point

Property Value Conditions Source
Melting point 960.5 °C (1760.9 °F) HSDB
960.56 °C (1761 °F) NIOSH
961.94 °C (1763.5 °F) CAMEO

Silver massive: [particle… density

Property Value Conditions Source
Density 10.49 g/cm³ metal NIOSH
10.5 g/cm³ ICSC
10.5 g/cm³ at 20 °C CAMEO

Silver massive: [particle… solubility

Property Value Conditions Source
Solubility Sol in fused alkali hydroxides in presence of air, fused peroxides, and alkali cyanides in presence of oxygen HSDB
INSOL IN HOT OR COLD WATER, ALKALI; SOL IN NITRIC ACID; HOT SULFURIC ACID, POTASSIUM CYANIDE Aqueous HSDB
Insoluble NIOSH

Silver massive: [particle… vapor pressure

Property Value Conditions Source
Vapor pressure 0 mmHg approx NIOSH
1 mmHg at 1357.22 °C CAMEO

Silver massive: [particle… lower explosive limit (LEL)

Property Value Conditions Source
Lower explosive limit (LEL) Metal: Noncombustible Solid, but flammable in form of dust or powder. NIOSH

Silver massive: [particle… corrosivity

Property Value Conditions Source
Corrosivity Sol silver cmpd will attack some forms of plastics, rubber, and coatings. Silver metal and soluble silver compounds HSDB

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

09 · Fire and explosion

Silver massive: [particle… fire and explosion behaviour

These are descriptions rather than measured values, so they are kept out of the table above and quoted here with the source that reported them.

Silver massive: [particle… fire potential

NONCOMBUSTIBLE, EXCEPT AS POWDER

Source: Hazardous Substances Data Bank (HSDB)

10 · Handling and storage

Silver massive: [particle… storage and handling

Silver massive: [particle… safe storage

Separated from : see Chemical Dangers. Store only in original packaging. Store in an area without drain or sewer access.

Source: ILO-WHO International Chemical Safety Cards (ICSCs)

Silver massive: [particle… incompatible materials

SILVER IS ... INCOMPATIBLE WITH OXALIC ACID & TARTARIC ACID.

Source: Hazardous Substances Data Bank (HSDB)

Planning storage for a mix of chemicals? Check Silver massive: [particle… in the storage compatibility matrix →

11 · Questions

Silver massive: [particle… — frequently asked questions

What is the CAS number of Silver massive: [particle…?

The CAS number of Silver massive: [particle… is 7440-22-4. Its EC number is 231-131-3.

What is the chemical formula of Silver massive: [particle…?

The molecular formula of Silver massive: [particle… is Ag and its molecular weight is 107.868 g/mol.

What does a Silver massive: [particle… label have to show?

Under CLP Annex VI the label for Silver massive: [particle… carries the pictogram Health hazard and the signal word is Warning.

Is Silver massive: [particle… flammable?

CLP Annex VI assigns Silver massive: [particle… no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it.

Is Silver massive: [particle… a carcinogen?

CLP Annex VI records no harmonised carcinogenicity classification for Silver massive: [particle…. Annex VI is a list of agreed classifications, not a list of substances found safe, so this is an absence of a classification rather than a clean bill of health.

What is the exposure limit for Silver massive: [particle…?

The US occupational exposure limit reported for Silver massive: [particle… is 0.01 [mg/m3], as Ag (Haz-Map, Information on Hazardous Chemicals and Occupational Diseases). Limits differ by country: the EU sets its own indicative and binding values, and the figure that applies at a given workplace is the one in the local regulation.

What is the boiling point of Silver massive: [particle…?

The boiling point reported for Silver massive: [particle… is 2000 °C (3632 °F) (NIOSH).

What is the melting point of Silver massive: [particle…?

The melting point reported for Silver massive: [particle… is 960.5 °C (1760.9 °F) (HSDB).

Nearby

Substances next to Silver massive: [particle…

Keep going: substances starting with S, or search the whole database by name, CAS number, pictogram or signal word.

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