Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Sodium chloroacetate

Sodium chloroacetate is a white colored powdered solid.

CAS 3926-62-3 C2H2ClNaO2 116.48 g/mol Danger

01 · Identification

What Sodium chloroacetate is

Sodium chloroacetate is a white colored powdered solid. Its molecular formula is C2H2ClNaO2 and its molecular weight is 116.48 g/mol.

Under the GHS it carries the signal word Danger.

02 · Identifiers

Sodium chloroacetate identifiers and molecular data

Sodium chloroacetate CAS number and EC number

CAS number3926-62-3
EC number223-498-3
Index number (CLP Annex VI)607-158-00-5

Sodium chloroacetate molecular formula and molecular weight

Molecular formulaC2H2ClNaO2
Molecular weight116.48 g/mol

Other names for Sodium chloroacetate

  • sodium salt of chloroacetic acid

03 · GHS classification

Sodium chloroacetate hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Sodium chloroacetate pictograms and signal word

Signal wordDanger

Sodium chloroacetate hazard class and category

GHS hazard classes Sodium chloroacetate falls into
Hazard class Category From code Pictogram
Acute toxicity - oral GHS chapter 3.1 Category 3 H301 GHS06
Skin corrosion/irritation GHS chapter 3.2 Category 2 H315 GHS07
Hazardous to the aquatic environment - acute GHS chapter 4.1 Category 1 H400 GHS09

Sodium chloroacetate hazard statements (H-codes)

Hazard statements assigned to Sodium chloroacetate
CodeHazard statement
H301 Toxic if swallowed.
H315 Causes skin irritation.
H400 Very toxic to aquatic life.

This page lists only the codes assigned to Sodium chloroacetate. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for Sodium chloroacetate

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of Sodium chloroacetate issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

Sodium chloroacetate precautionary statements

CLP Annex VI assigns 13 precautionary statements to Sodium chloroacetate. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Disposal

What has to happen to the contents and the empty container.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

Sodium chloroacetate name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български натриева сол на хлорооцетната киселина натриев хлороацетат
Spanish español Sal sódica del ácido cloroacético cloroacetato de sodio
Czech čeština chloroctan sodný natrium-chloracetát
Danish dansk natrium-salt af chloreddikesyre natriumchloracetat
German Deutsch Natriumsalz der Chloressigsäure, Natriumchloracetat
Estonian eesti kloroäädikhappe naatriumsool naatriumkloroatsetaat
Greek ελληνικά άλας νατρίου του χλωροξικού οξέος χλωροξικό νάτριο
English English sodium salt of chloroacetic acid sodium chloroacetate
French français sel de sodium de l'acide chloroacétique chloroacétate de sodium
Croatian hrvatski natrijeva sol kloroctene kiseline natrijev kloracetat
Italian italiano sale di sodio dell'acido cloroacetico cloroacetato di sodio
Latvian latviešu hloretiķskābes nātrija sāls nātrija hloracetāts
Lithuanian lietuvių chloracto rūgšties natrio druska natrio chloracetatas
Hungarian magyar klórecetsav nátriumsója nátrium-klóracetát
Maltese Malti melħ tas-sodju tal-aċidu kloroaċetiku kloroaċetat tas-sodju
Dutch Nederlands natriumzout van chloorazijnzuur natriumchlooracetaat
Polish polski chlorooctan sodu
Portuguese português sal de sódio do ácido cloroacético cloroacetato de sódio
Romanian română sare de sodiu a acidului cloroacetic cloracetat de sodiu
Slovak slovenčina sodná soľ kyseliny chlóroctovej nátrium-chlóracetátchlóroctan sodný
Slovenian slovenščina natrijeva sol kloroocetne kisline natrijev kloroacetat
Finnish suomi kloorietikkahapon natriumsuola natriumklooriasetaatti
Swedish svenska natriumsalt av klorättiksyra natriumkloracetat

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

Sodium chloroacetate GHS label elements

Everything CLP Annex VI fixes for Sodium chloroacetate, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS06 Skull and crossbones pictogramGHS09 Environment pictogram

Danger

Sodium chloroacetate

  • Toxic if swallowed.
  • Causes skin irritation.
  • Very toxic to aquatic life.
  • Wash thoroughly after handling.
  • Do not eat, drink or smoke when using this product.
  • Avoid release to the environment.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • IF SWALLOWED:
  • IF ON SKIN:
  • Immediately call a POISON CENTER/doctor/
  • Get medical advice/attention.
  • Rinse mouth.
  • If skin irritation occurs:
  • Wash with plenty of water/
  • Collect spillage.
  • Dispose of contents/container to

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open Sodium chloroacetate in the GHS label constructor →

07 · Health hazards

Sodium chloroacetate health hazards and exposure limits

Sodium chloroacetate hazard summary

An eye and respiratory tract irritant; Toxic by ingestion or by inhalation after spraying; The substance may cause effects on the central nervous system and cardiovascular system, resulting in convulsions, cardiac disorders and kidney impairment. [ICSC] Toxic to the liver in high-dose, animal-feeding studies; [AIHA] Highly toxic by inhalation, ingestion, and skin absorption; [CAMEO] An irritant; Effects in high-dose animal studies include convulsions and coma; [MSDSonline]

Source: Haz-Map, Information on Hazardous Chemicals and Occupational Diseases

08 · Physical and chemical properties

Sodium chloroacetate properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

Sodium chloroacetate solubility

Property Value Conditions Source
Solubility Solubility in water, g/100ml at 20 °C: 85 at 20 °C ICSC

Sodium chloroacetate vapor pressure

Property Value Conditions Source
Vapor pressure 0.86 mmHg Haz-Map
Vapor pressure at 25 °C: negligible at 25 °C ICSC

Sodium chloroacetate vapor density

Property Value Conditions Source
Vapor density 3.26 (air = 1) ICSC

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

09 · Handling and storage

Sodium chloroacetate storage and handling

Sodium chloroacetate safe storage

Separated from food and feedstuffs and strong oxidants. Provision to contain effluent from fire extinguishing. Store in an area without drain or sewer access.

Source: ILO-WHO International Chemical Safety Cards (ICSCs)

Sodium chloroacetate reactivity

Salts, basic, such as SODIUM CHLOROACETATE, are generally soluble in water. The resulting solutions contain moderate concentrations of hydroxide ions and have pH's greater than 7.0. They react as bases to neutralize acids. These neutralizations generate heat, but less or far less than is generated by neutralization of the bases in reactivity group 10 (Bases) and the neutralization of amines. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible.

Source: CAMEO Chemicals

Planning storage for a mix of chemicals? Check Sodium chloroacetate in the storage compatibility matrix →

10 · Transport

Sodium chloroacetate UN number and transport classification

Transport classification is a separate system from the GHS classification above. It decides how a package is marked and how a load may be carried; it does not follow from the workplace label, and the workplace label does not follow from it. The entries below are linked by CAS number, never by name.

Sodium chloroacetate under UN 2659 — shipping name, class and packing group

Europe · ADR 2025, Table A

Proper shipping name (3.1.2) Class Classification code PG Labels (column 5)
SODIUM CHLOROACETATE 6.1 T2 III
  • ADR label model 6.1 — Toxic substance
6.1

Source: ADR 2025, Table A of Chapter 3.2 · ECE/TRANS/352 Vol. I (UNECE). Class 6.1 is “Toxic substances” (ADR 2.1.1.1).

Proper shipping name (column 2) Class or division PG Labels (column 6)
Sodium chloroacetate 6.1 III
  • US DOT POISON label (§172.430)
6.1

Source: 49 CFR 172.101 Hazardous Materials Table · eCFR, revision 2026-08-03. Class 6.1 is “Poisonous materials” (49 CFR 173.2).

Full UN 2659 entry — special provisions, packing instructions, quantity limits and the orange plate →

11 · Questions

Sodium chloroacetate — frequently asked questions

What is the CAS number of Sodium chloroacetate?

The CAS number of Sodium chloroacetate is 3926-62-3. Its EC number is 223-498-3.

What is the chemical formula of Sodium chloroacetate?

The molecular formula of Sodium chloroacetate is C2H2ClNaO2 and its molecular weight is 116.48 g/mol.

What does a Sodium chloroacetate label have to show?

Under CLP Annex VI the label for Sodium chloroacetate carries the pictograms Skull and crossbones and Environment and the signal word is Danger.

Is Sodium chloroacetate flammable?

CLP Annex VI assigns Sodium chloroacetate no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it.

Is Sodium chloroacetate a carcinogen?

CLP Annex VI records no harmonised carcinogenicity classification for Sodium chloroacetate. Annex VI is a list of agreed classifications, not a list of substances found safe, so this is an absence of a classification rather than a clean bill of health.

Nearby

Substances next to Sodium chloroacetate

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