Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Sulfur tetrachloride

Sulfur tetrachloride is a chemical substance with the molecular formula Cl4S.

CAS 13451-08-6 Cl4S 173.9 g/mol Danger

01 · Identification

What Sulfur tetrachloride is

Sulfur tetrachloride is a chemical substance with the molecular formula Cl4S. Its molecular formula is Cl4S and its molecular weight is 173.9 g/mol.

Under the GHS it carries the signal word Danger.

02 · Identifiers

Sulfur tetrachloride identifiers and molecular data

Sulfur tetrachloride CAS number and EC number

CAS number13451-08-6
Index number (CLP Annex VI)016-014-00-5

Sulfur tetrachloride molecular formula and molecular weight

Molecular formulaCl4S
Molecular weight173.9 g/mol

Other names for Sulfur tetrachloride

  • sulphur tetrachloride

03 · GHS classification

Sulfur tetrachloride hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Sulfur tetrachloride pictograms and signal word

Signal wordDanger

Sulfur tetrachloride hazard class and category

GHS hazard classes Sulfur tetrachloride falls into
Hazard class Category From code Pictogram
Skin corrosion/irritation GHS chapter 3.2 Category 1A or 1B or 1C H314 GHS05
Hazardous to the aquatic environment - acute GHS chapter 4.1 Category 1 H400 GHS09

Where two values are shown with “or”, the hazard statement is shared by more than one category or by more than one class, and the code alone does not say which. H272, for example, belongs to oxidising liquids and to oxidising solids — the physical state decides. The binding answer for a specific entry is in the CLP Annex VI table itself.

Sulfur tetrachloride hazard statements (H-codes)

Hazard statements assigned to Sulfur tetrachloride
CodeHazard statement
H314 Causes severe skin burns and eye damage.
H400 Very toxic to aquatic life.

Sulfur tetrachloride supplemental EU statements (EUH)

EU-specific statements assigned to Sulfur tetrachloride. They exist only in CLP and have no counterpart in UN GHS.
CodeStatement
EUH014 Reacts violently with water.

This page lists only the codes assigned to Sulfur tetrachloride. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for Sulfur tetrachloride

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of Sulfur tetrachloride issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

Sulfur tetrachloride precautionary statements

CLP Annex VI assigns 8 precautionary statements to Sulfur tetrachloride. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Disposal

What has to happen to the contents and the empty container.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

Sulfur tetrachloride name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български серен тетрахлорид
Spanish español Tetracloruro de azufre
Czech čeština chlorid siřičitý
Danish dansk svovltetrachlorid
German Deutsch Schwefeltetrachlorid
Estonian eesti vääveltetrakloriid
Greek ελληνικά τετραχλωριούχο θείο
English English sulphur tetrachloride
French français tétrachlorure de soufre
Croatian hrvatski sumporov tetraklorid
Italian italiano tetracloruro di zolfo
Latvian latviešu sēra tetrahlorīds
Lithuanian lietuvių sieros tetrachloridas
Hungarian magyar kén-tetraklorid
Maltese Malti tetraklorur tal-kubrit
Dutch Nederlands zwaveltetrachloride
Polish polski tetrachlorek siarki
Portuguese português tetracloreto de enxofre
Romanian română tetraclorură de sulf
Slovak slovenčina chlorid siričitý
Slovenian slovenščina žveplov tetraklorid
Finnish suomi rikkitetrakloridi
Swedish svenska svaveltetraklorid

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

Sulfur tetrachloride GHS label elements

Everything CLP Annex VI fixes for Sulfur tetrachloride, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS05 Corrosion pictogramGHS09 Environment pictogram

Danger

Sulfur tetrachloride

  • Causes severe skin burns and eye damage.
  • Very toxic to aquatic life.
  • Reacts violently with water.
  • Do not breathe dust/fume/gas/mist/vapours/spray.
  • Avoid release to the environment.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • IF SWALLOWED:
  • Immediately call a POISON CENTER/doctor/
  • Do NOT induce vomiting.
  • Collect spillage.
  • Dispose of contents/container to

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open Sulfur tetrachloride in the GHS label constructor →

07 · Questions

Sulfur tetrachloride — frequently asked questions

What is the CAS number of Sulfur tetrachloride?

The CAS number of Sulfur tetrachloride is 13451-08-6.

What is the chemical formula of Sulfur tetrachloride?

The molecular formula of Sulfur tetrachloride is Cl4S and its molecular weight is 173.9 g/mol.

What does a Sulfur tetrachloride label have to show?

Under CLP Annex VI the label for Sulfur tetrachloride carries the pictograms Corrosion and Environment and the signal word is Danger.

Is Sulfur tetrachloride flammable?

CLP Annex VI assigns Sulfur tetrachloride no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it.

Is Sulfur tetrachloride a carcinogen?

CLP Annex VI records no harmonised carcinogenicity classification for Sulfur tetrachloride. Annex VI is a list of agreed classifications, not a list of substances found safe, so this is an absence of a classification rather than a clean bill of health.

Nearby

Substances next to Sulfur tetrachloride

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