Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

tert-butyl (5S,6R,7R)-3-bromomethyl-5,8-dioxo-7-(2-(2-phenylacetamido)-5-thia-1-azabicyclo[4.2.0] oct-2-ene-2-carboxylate

tert-butyl (5S,6R,7R)-3-bromomethyl-5,8-dioxo-7-(2-(2-phenylacetamido)-5-thia-1-azabicyclo[4.2.0] oct-2-ene-2-carboxylate is a substance with a harmonised classification under EU CLP.

CAS 33610-13-8 Danger

01 · Identification

What tert-butyl (5S,6R,7R)-3-bromom… is

tert-butyl (5S,6R,7R)-3-bromomethyl-5,8-dioxo-7-(2-(2-phenylacetamido)-5-thia-1-azabicyclo[4.2.0] oct-2-ene-2-carboxylate is a substance with a harmonised classification under EU CLP.

Under the GHS it carries the signal word Danger.

02 · Identifiers

tert-butyl (5S,6R,7R)-3-bromom… identifiers and molecular data

tert-butyl (5S,6R,7R)-3-bromom… CAS number and EC number

CAS number33610-13-8
EC number407-620-4
Index number (CLP Annex VI)607-267-00-8

03 · GHS classification

tert-butyl (5S,6R,7R)-3-bromom… hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

tert-butyl (5S,6R,7R)-3-bromom… pictograms and signal word

Signal wordDanger

tert-butyl (5S,6R,7R)-3-bromom… hazard class and category

GHS hazard classes tert-butyl (5S,6R,7R)-3-br… falls into
Hazard class Category From code Pictogram
Respiratory sensitisation GHS chapter 3.4 Category 1 or 1A or 1B H334 GHS08
Skin sensitisation GHS chapter 3.4 Category 1 or 1A or 1B H317 GHS07
Hazardous to the aquatic environment - chronic GHS chapter 4.1 Category 3 H412

Where two values are shown with “or”, the hazard statement is shared by more than one category or by more than one class, and the code alone does not say which. H272, for example, belongs to oxidising liquids and to oxidising solids — the physical state decides. The binding answer for a specific entry is in the CLP Annex VI table itself.

tert-butyl (5S,6R,7R)-3-bromom… hazard statements (H-codes)

Hazard statements assigned to tert-butyl (5S,6R,7R)-3-br…
CodeHazard statement
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H317 May cause an allergic skin reaction.
H412 Harmful to aquatic life with long lasting effects.

This page lists only the codes assigned to tert-butyl (5S,6R,7R)-3-br…. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for tert-butyl (5S,6R,7R)-3-br…

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of tert-butyl (5S,6R,7R)… issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

tert-butyl (5S,6R,7R)-3-bromom… precautionary statements

CLP Annex VI assigns 7 precautionary statements to tert-butyl (5S,6R,7R)-3-br…. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Response

What to do once exposure, spillage or fire has already happened.

Disposal

What has to happen to the contents and the empty container.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

tert-butyl (5S,6R,7R)-3-bromom… name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български трет -бутилов (5 S ,6 R ,7 R )-3-бромометил-5,8-диоксо-7-(2-(2-фенилацетамидо)-5-тиа-1-азабицикло[4.2.0]окт-2-ен-2-карбоксилат
Spanish español (5 S ,6 R ,7R)-3-Bromometil-5,8-dioxo-7-(2-(2-fenilacetamido)-5-tia-1-azabiciclo[4.2.0]oct-2-eno-2-carboxilato de terc -butilo
Czech čeština terc -butyl-(1 S ,7 R ,7a R )-3-(brommethyl)-7-(fenylacetamido)-1,6(7 H )-dioxo-2 H -azeto[2,1- b ][1,3]thiazin-4-karboxylát
Danish dansk tert -butyl-(5 S ,6 R ,7 R )-3-brommethyl-5,8-dioxo-7-(2-phenylacetamido)-5-thia-1-azabicyclo[4.2.0] oct-2-en-2-carboxylat
German Deutsch tert -Butyl-(5 S ,6 R ,7 R )-3-brommethyl-5,8-dioxo-7-(2-(2-phenylacetamido)-5-thia-1-azabicyclo[4.2.0]-oct-2-en-2-carboxylat
Estonian eesti tert -butüül-(5 S ,6 R ,7 R )-3-bromometüül-5,8-diokso-7-(2-(2-fenüülatseetamido)-5-tia-1-asabitsüklo[4.2.0]okt-2-een-2-karboksülaat
Greek ελληνικά (5 S ,6 R ,7 R )-3-βρωμομεθυλο-5,8-διοξο-7-(2-(2-φαινυλακεταμιδο)-5-θεια-1-αζαδικυκλο[4.2.0]οκτ-2-ενο-2-καρβοξυλικός tert -βουτυλεστέρας
English English tert -butyl (5 S ,6 R ,7 R )-3-bromomethyl-5,8-dioxo-7-(2-(2-phenylacetamido)-5-thia-1-azabicyclo[4.2.0] oct-2-ene-2-carboxylate
French français (5 S ,6 R ,7 R )-3-bromométhyl-5,8-dioxo-7-(2-(2-phénylacétamido)-5-thia-1-azabicyclo[4.2.0]oct-2-ène-2-carboxylate de tert -butyle
Croatian hrvatski tert -butil(5 S ,6 R ,7 R )-3-brommetil-5,8-diokso-7-(2-(2-fenilacetamido)-5-tia-1-azabiciklo[4.2.0]okt-2-en-2-karboksilat
Italian italiano (5 S ,6 R ,7 R )-3-bromometil-5,8-diosso-7-(2-fenilacetammido)-5-tia-1-azabiciclo[4.2.0] ott-2-en-2-carbossilato di terz -butile
Latvian latviešu terc -butil-(5 S ,6 R ,7 R )-3-brommetil-5,8-diokso-7-(2-(2-fenilacetamido)-5-tia-1-azabiciklo[4.2.0]okt-2-ēn-2-karboksilāts
Lithuanian lietuvių tret -butil-(5 S 6 R7 R )-3-brommetil-5,8-diokso-7-(2-(2-fenilacetamido)-5-tia-1-azabiciklo[4.2.0]okt-2-en-2-karboksilatas
Hungarian magyar terc -butil-(5 S ,6 R ,7 R )-3-brómmetil-5,8-dioxo-7-(2-(2-fenilacetamido)-5-tia-1-azabiciklo[4.2.0]okt-2-én-2-karboxilát
Maltese Malti tert -butyl (5 S ,6 R ,7 R )-3-bromometil-5,8-diosso-7-(2-(2-fenilaċetammido)-5-tija-1-ażabiċiklo[4.2.0] ott-2-en-2-karbossilat
Dutch Nederlands tert -butyl-(5 S ,6 R ,7 R )-3-broommethyl-5,8-dioxo-7-(2-fenylaceetamido)-5-thia-1-azabicyclo[4.2.0]oct-2-een-2-carboxylaat
Polish polski (5S,6R,7R)-3-bromometylo-5,8-diokso-7-(2-fenyloacetamido)-5-tia-1-azabicyklo[4.2.0]okt-2-eno-2-karboksylan tert-butylu
Portuguese português (5 S ,6 R ,7 R )-3-bromometil-5,8-dioxo-7-(2-fenilacetamido)-5-tia-1-azabiciclo[4.2.0]-2-octeno-2-carboxilato de terc -butilo
Romanian română (5 S ,6 R ,7 R )-3-brommetil-5,8-dioxo-7-(2-(2-fenilacetamidă)-5-tia-1-azabiciclo [4.2.0]oct-2-enă-2-carboxilat de terț -butil
Slovak slovenčina O-terc-butyl-(5S,6R,7R)-3-(brómmetyl)-7-(2-fenylacetamido)-5,8-dioxo-5-tia-1-azabicyklo[4.2.0]okt-2-én-2-karboxylát
Slovenian slovenščina terc -butil (5 S ,6 R ,7 R )-3-bromometil-5,8-diokso-7-(2-(2-fenilacetamido)-5-tia-1-azabiciklo[4.2.0] okt-2-en-2-karboksilat
Finnish suomi tert -butyyli (5 S ,6 R ,7 R )-3-bromimetyyli-5,8-diokso-7-(2-(2-fenyyliasetamido)-5-tia-1-atsabisyklo[4.2.0]okt-2-eeni-2-karboksylaatti
Swedish svenska tert -butyl(5 S ,6 R ,7 R )-3-brommetyl-5,8-dioxo-7-(2-(2-fenylacetamido)-5-tia-1-azabicyklo[4.2.0]okt-2-en-2-karboxylat

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

tert-butyl (5S,6R,7R)-3-bromom… GHS label elements

Everything CLP Annex VI fixes for tert-butyl (5S,6R,7R)-3-br…, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS08 Health hazard pictogram

Danger

tert-butyl (5S,6R,7R)-3-bromom…

  • May cause allergy or asthma symptoms or breathing difficulties if inhaled.
  • May cause an allergic skin reaction.
  • Harmful to aquatic life with long lasting effects.
  • Avoid breathing dust/fume/gas/mist/vapours/spray.
  • Contaminated work clothing should not be allowed out of the workplace.
  • Avoid release to the environment.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • Get medical advice/attention.
  • If skin irritation or rash occurs:
  • Dispose of contents/container to

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open tert-butyl (5S,6R,7R)-3-br… in the GHS label constructor →

07 · Questions

tert-butyl (5S,6R,7R)-3-bromom… — frequently asked questions

What is the CAS number of tert-butyl (5S,6R,7R)-3-bromom…?

The CAS number of tert-butyl (5S,6R,7R)-3-bromom… is 33610-13-8. Its EC number is 407-620-4.

What does a tert-butyl (5S,6R,7R)-3-bromom… label have to show?

Under CLP Annex VI the label for tert-butyl (5S,6R,7R)-3-bromom… carries the pictogram Health hazard and the signal word is Danger.

Is tert-butyl (5S,6R,7R)-3-bromom… flammable?

CLP Annex VI assigns tert-butyl (5S,6R,7R)-3-bromom… no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it.

Is tert-butyl (5S,6R,7R)-3-bromom… a carcinogen?

CLP Annex VI records no harmonised carcinogenicity classification for tert-butyl (5S,6R,7R)-3-bromom…. Annex VI is a list of agreed classifications, not a list of substances found safe, so this is an absence of a classification rather than a clean bill of health.

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