Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Tetrahydro-2-furylmethanol

Tetrahydro-2-furylmethanol is a colorless liquid with a mild odor.

CAS 97-99-4 Danger

01 · Identification

What Tetrahydro-2-furylmethanol is

Tetrahydro-2-furylmethanol is a colorless liquid with a mild odor. It boils at 178 °C, melts at -80 °C.

Under the GHS it carries the signal word Danger.

02 · Identifiers

Tetrahydro-2-furylmethanol identifiers and molecular data

Tetrahydro-2-furylmethanol CAS number and EC number

CAS number97-99-4
EC number202-625-6
Index number (CLP Annex VI)603-061-00-7

Other names for Tetrahydro-2-furylmethanol

  • tetrahydrofurfuryl alcohol

03 · GHS classification

Tetrahydro-2-furylmethanol hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Tetrahydro-2-furylmethanol pictograms and signal word

Signal wordDanger

Tetrahydro-2-furylmethanol hazard class and category

GHS hazard classes Tetrahydro-2-furylmethanol falls into
Hazard class Category From code Pictogram
Serious eye damage/eye irritation GHS chapter 3.3 Category 2A H319 GHS07

Tetrahydro-2-furylmethanol hazard statements (H-codes)

Hazard statements assigned to Tetrahydro-2-furylmethanol
CodeHazard statement
H360Df May damage the unborn child. Suspected of damaging fertility.
H319 Causes serious eye irritation.

This page lists only the codes assigned to Tetrahydro-2-furylmethanol. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for Tetrahydro-2-furylmethanol

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of Tetrahydro-2-furylmeth… issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

Tetrahydro-2-furylmethanol precautionary statements

CLP Annex VI assigns 6 precautionary statements to Tetrahydro-2-furylmethanol. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

Tetrahydro-2-furylmethanol name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български тетрахидро-2-фурилметанол тетрахидрофурфурилов алкохол
Spanish español Tetrahidro-2-furilmetanol alcohol tetrahidrofurfurílico
Czech čeština tetrahydro-2-furyl-methanol tetrahydrofurfurylalkohol
Danish dansk tetrahydro-2-furylmethanol tetrahydrofurfurylalkohol
German Deutsch Tetrahydro-2-furyl-methanol Tetrahydrofurfurylalkohol
Estonian eesti tetrahüdro-2-furüülmetanool tetrahüdrofurfurüülalkohol
Greek ελληνικά τετραϋδρο-2-φoυρυλομεθανόλη τετραϋδροφoυρφoυρυλική αλκοόλη
English English tetrahydro-2-furyl-methanol tetrahydrofurfuryl alcohol
French français tétrahydro-2-furyl-méthanol alcool tétrahydrofurfurylique
Croatian hrvatski tetrahidro-2-furil-metanol tetrahidrofurfuril-alkohol
Italian italiano tetraidro-2-furilmetanolo alcool tetraidrofurfurilico
Latvian latviešu tetrahidro-2-furilmetanols tetrahidrofurfurilspirts
Lithuanian lietuvių tetrahidro-2-furilmetanolis tetrahidrofurfurilo alkoholis
Hungarian magyar tetrahidro-2-furilmetanol tetrahidrofurfuril-alkohol
Maltese Malti tetraidro-2-furil-metanol alkoħol tat-tetraidrofurfuril
Dutch Nederlands tetrahydro-2-furylmethanol tetrahydrofurfurylalcohol
Polish polski tetrahydro-2-furylometanol alkohol tetrahydrofurfurylowy2-(hydroksymetylo)oksolan
Portuguese português tetra-hidro-2-furilmetanol álcool tetra-hidrofurfurílico
Romanian română tetrahidro-2-furil-metanol alcool tetrahidrofurfurilic
Slovak slovenčina tetrahydrofurán-2-metanol tetrahydrofurfurylalkohol
Slovenian slovenščina tetrahidro-2-furil-metanol tetrahidrofurfuril alkohol
Finnish suomi tetrahydro-2-furyylimetanoli tetrahydrofurfuryylialkoholi
Swedish svenska tetrahydro-2-furylmetanol tetrahydrofurfurylalkohol

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

Tetrahydro-2-furylmethanol GHS label elements

Everything CLP Annex VI fixes for Tetrahydro-2-furylmethanol, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS08 Health hazard pictogramGHS07 Exclamation mark pictogram

Danger

Tetrahydro-2-furylmethanol

  • May damage the unborn child. Suspected of damaging fertility.
  • Causes serious eye irritation.
  • Wash thoroughly after handling.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • IF IN EYES:
  • Get medical advice/attention.
  • If eye irritation persists:
  • Remove contact lenses, if present and easy to do. Continue rinsing.

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open Tetrahydro-2-furylmethanol in the GHS label constructor →

07 · Health hazards

Tetrahydro-2-furylmethanol health hazards and exposure limits

Tetrahydro-2-furylmethanol hazard summary

A skin, eye, and respiratory tract irritant; Inhalation of high concentrations may cause CNS effects; [ICSC] After exposure for 4 hours to 4700 ppm, narcosis but no deaths among 4 rats were observed. [AIHA] An irritant; Effects in high-dose animal studies include convulsions and general anesthesia; [MSDSonline]

Source: Haz-Map, Information on Hazardous Chemicals and Occupational Diseases

08 · Physical and chemical properties

Tetrahydro-2-furylmethanol properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

Tetrahydro-2-furylmethanol boiling point

Property Value Conditions Source
Boiling point 178 °C (352.4 °F) at 760 mmHg HSDB
178 °C (352.4 °F) ICSC
178.5 °C (353.3 °F) range, midpoint shown JECFA

Tetrahydro-2-furylmethanol melting point

Property Value Conditions Source
Melting point -80 °C (-112 °F) below this value HSDB

Tetrahydro-2-furylmethanol density

Property Value Conditions Source
Density 1.05 g/cm³ ICSC
1.0544 g/cm³ at 20 °C HSDB
1.051 g/cm³ range, midpoint shown JECFA

Tetrahydro-2-furylmethanol solubility

Property Value Conditions Source
Solubility Miscible with water, alcohol, ether, acetone, chloroform, benzene HSDB
Solubility in water: miscible ICSC
Soluble in water, fats JECFA

Tetrahydro-2-furylmethanol vapor pressure

Property Value Conditions Source
Vapor pressure 0.8 mmHg at 25 °C HSDB
1.3951 mmHg at 25 °C ICSC
0.8 mmHg Haz-Map

Tetrahydro-2-furylmethanol flash point

Property Value Conditions Source
Flash point 75 °C (167 °F) OPEN CUP HSDB
75 °C (167 °F) CAMEO
74 °C (165.2 °F) ICSC

Tetrahydro-2-furylmethanol autoignition temperature

Property Value Conditions Source
Autoignition temperature 282.22 °C (540 °F) HSDB
280 °C (536 °F) ICSC

Tetrahydro-2-furylmethanol lower explosive limit (LEL)

Property Value Conditions Source
Lower explosive limit (LEL) 1.5 % by volume HSDB

Tetrahydro-2-furylmethanol upper explosive limit (UEL)

Property Value Conditions Source
Upper explosive limit (UEL) 9.7 % by volume HSDB

Tetrahydro-2-furylmethanol vapor density

Property Value Conditions Source
Vapor density 3.522 (air = 1) HSDB
3.5 (air = 1) ICSC

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

09 · Fire and explosion

Tetrahydro-2-furylmethanol fire and explosion behaviour

These are descriptions rather than measured values, so they are kept out of the table above and quoted here with the source that reported them.

Tetrahydro-2-furylmethanol fire potential

Combustible when exposed to heat or flame.

Source: Hazardous Substances Data Bank (HSDB)

10 · Handling and storage

Tetrahydro-2-furylmethanol storage and handling

Tetrahydro-2-furylmethanol safe storage

Separated from strong oxidants. Dry. Well closed. Ventilation along the floor.

Source: ILO-WHO International Chemical Safety Cards (ICSCs)

Tetrahydro-2-furylmethanol storage conditions

FURFURAL & ITS DERIVATIVES SHOULD BE STORED IN WELL-VENTILATED AREAS, SHELTERED FROM DIRECT SUNLIGHT & AWAY FROM HEAT & OTHER SOURCES OF IGNITION. /FURFURAL & IT DERIVATIVES/

Source: Hazardous Substances Data Bank (HSDB)

Tetrahydro-2-furylmethanol incompatible materials

Violent or explosive reaction with 3-nitro-N-bromophthalimide. ... Can react with oxidizing materials.

Source: Hazardous Substances Data Bank (HSDB)

Planning storage for a mix of chemicals? Check Tetrahydro-2-furylmethano… in the storage compatibility matrix →

11 · Questions

Tetrahydro-2-furylmethanol — frequently asked questions

What is the CAS number of Tetrahydro-2-furylmethanol?

The CAS number of Tetrahydro-2-furylmethanol is 97-99-4. Its EC number is 202-625-6.

What does a Tetrahydro-2-furylmethanol label have to show?

Under CLP Annex VI the label for Tetrahydro-2-furylmethanol carries the pictograms Health hazard and Exclamation mark and the signal word is Danger.

Is Tetrahydro-2-furylmethanol flammable?

CLP Annex VI assigns Tetrahydro-2-furylmethanol no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it. The flash point reported for it is 75 °C (167 °F), OPEN CUP (HSDB).

Is Tetrahydro-2-furylmethanol a carcinogen?

CLP Annex VI records no harmonised carcinogenicity classification for Tetrahydro-2-furylmethanol. Annex VI is a list of agreed classifications, not a list of substances found safe, so this is an absence of a classification rather than a clean bill of health.

What is the boiling point of Tetrahydro-2-furylmethanol?

The boiling point reported for Tetrahydro-2-furylmethanol is 178 °C (352.4 °F), at 760 mmHg (HSDB).

What is the melting point of Tetrahydro-2-furylmethanol?

The melting point reported for Tetrahydro-2-furylmethanol is -80 °C (-112 °F), below this value (HSDB).

How should Tetrahydro-2-furylmethanol be stored?

FURFURAL & ITS DERIVATIVES SHOULD BE STORED IN WELL-VENTILATED AREAS, SHELTERED FROM DIRECT SUNLIGHT & AWAY FROM HEAT & OTHER SOURCES OF IGNITION. /FURFURAL & IT DERIVATIVES/ (Hazardous Substances Data Bank (HSDB))

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