Provenance

Reference data from EU CLP Annex VI and published regulations — verify against your supplier's SDS before use.

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Substance profile

Thiometon

Thiometon is a colorless oil with a characteristic odor.

CAS 640-15-3 C6H15O2PS3 246.4 g/mol Danger

01 · Identification

What Thiometon is

Thiometon is a colorless oil with a characteristic odor. Its molecular formula is C6H15O2PS3 and its molecular weight is 246.4 g/mol.

Under the GHS it carries the signal word Danger.

02 · Identifiers

Thiometon identifiers and molecular data

Thiometon CAS number and EC number

CAS number640-15-3
EC number211-362-6
Index number (CLP Annex VI)015-050-00-9

Thiometon molecular formula and molecular weight

Molecular formulaC6H15O2PS3
Molecular weight246.4 g/mol

Other names for Thiometon

  • thiometon (ISO)
  • S-2-ethylthioethyl O,O-dimethyl phosphorodithioate

03 · GHS classification

Thiometon hazard classification

Harmonised classification under CLP Annex VI. This is the legally binding classification in the EU; other jurisdictions may differ.

Thiometon pictograms and signal word

Signal wordDanger

Thiometon hazard class and category

GHS hazard classes Thiometon falls into
Hazard class Category From code Pictogram
Acute toxicity - oral GHS chapter 3.1 Category 3 H301 GHS06
Acute toxicity - dermal GHS chapter 3.1 Category 4 H312 GHS07

Thiometon hazard statements (H-codes)

Hazard statements assigned to Thiometon
CodeHazard statement
H301 Toxic if swallowed.
H312 Harmful in contact with skin.

This page lists only the codes assigned to Thiometon. The full reference lives on the hazard statements hub, the precautionary statements hub and the GHS pictograms hub.

Safety Data Sheet

Getting an SDS for Thiometon

A Safety Data Sheet is written for a product, not for a substance: the supplier of the grade you actually buy issues it, so two suppliers of Thiometon issue two different sheets. That is why there is no single authoritative SDS for a substance to download — what there is, is the job of collecting the sheets for the products you hold and keeping them current as suppliers revise them.

04 · Precautionary statements

Thiometon precautionary statements

CLP Annex VI assigns 8 precautionary statements to Thiometon. They are grouped the way a label groups them: what to do before handling, what to do when something has already happened, how to store it and how to dispose of it.

Reading the notation. is a blank the supplier fills in — not a truncated sentence.· [square brackets] mark a part printed only when it applies.

05 · Names in the regulation

Thiometon name in 23 EU languages

CLP Annex VI Part 3 is published in every language edition of the regulation, and the identification column is written out in each of them. Nothing below is translated by us: each line is the name as that edition prints it. Under Art. 18(2) the substance name from Annex VI is a lawful product identifier, so this is the wording to put on a label going to that market — and where the cell lists several designations, any one of them qualifies.

Language Name in CLP Annex VI Part 3
Bulgarian български тиометон (ISO) S -2-етилтиоетилов О , О -диметилов фосфородитиоат
Spanish español Tiometón (ISO) fosforoditioato de S -2-etiltioetilo y O , O -dimetilo
Czech čeština thiometon (ISO) S -[2-(ethylsulfanyl)ethyl]- O, O -dimethyl-fosforodithioát
Danish dansk thiometon (ISO) S -2-ethylthioethyl- O, O- dimethyldithiophosphat
German Deutsch Thiometon (ISO) S -2-Ethylthioethyl- O , O -dimethylphosphorodithioat
Estonian eesti tiometoon (ISO) S -2-etüültioetüül- O , O -dimetüülfosforoditioaat
Greek ελληνικά thiometon (θειομετόνη) (ISO) διθειοφωσφορικό S -2-αιθυλοθειαιθύλιο O , O -διμεθύλιο
English English thiometon (ISO) S -2-ethylthioethyl O , O -dimethyl phosphorodithioate
French français thiométon (ISO) phosphorodithioate de S -2-éthylthioéthyle et de O, O -diméthyle
Croatian hrvatski tiometon (ISO) S -2-etil-tioetil- O , O -dimetil-fosforoditioat
Italian italiano tiometon (ISO) ditiofosfato di S-2-etiltioetile e O, O-dimetile
Latvian latviešu tiometons (ISO) S -2-etiltioetil- O , O -dimetilfosforditioāts
Lithuanian lietuvių tiometonas (ISO) S -2-etiltioetil- O , O -dimetilditiofosfatas
Hungarian magyar tiometon (ISO) S -2-etiltioetil- O, O -dimetil-ditiofoszfát
Maltese Malti tijometon (ISO) fosforoditijoat ta’ S -2-etiltijoetil O , O -dimetil
Dutch Nederlands thiometon (ISO) S -2-ethylthioëthyl- O , O -dimethyldithiofosfaat
Polish polski tiometon (ISO) ditiofosforan S -2-(etylosulfanylo)etylu- O , O -dimetylu
Portuguese português tiometão (ISO) ditiofosfato de O , O -dimetilo e de S -2-etiltioetilo
Romanian română tiometon (ISO) ditiofosfat de S -2-etiltioetil și de O, O -dimetil
Slovak slovenčina tiometón (ISO) S -[2-(etylsulfanyl)etyl]- O, O -dimetylfosforoditioát
Slovenian slovenščina tiometon (ISO) S -2-etiltioetil O , O -dimetil fosforoditioat
Finnish suomi tiometoni (ISO) S -2-etyylitioetyyli- O , O -dimetyylifosforoditioaatti
Swedish svenska tiometon (ISO) S -2-etyltioetyl- O , O -dimetylfosforditioat

All 23 language editions of Annex VI carry this entry. Irish is the twenty-fourth official EU language and has no line here for a different reason: no consolidated CLP text has ever been published in Irish, so there is no Irish edition of Annex VI to quote a name from. Source: consolidated CLP, CELEX 02008R1272, language editions. © European Union, https://eur-lex.europa.eu — only the electronic Official Journal of the European Union is authentic.

06 · Label elements

Thiometon GHS label elements

Everything CLP Annex VI fixes for Thiometon, laid out the way it appears on a label. The greyed lines are the parts only the supplier can fill in.

GHS06 Skull and crossbones pictogram

Danger

Thiometon

  • Toxic if swallowed.
  • Harmful in contact with skin.
  • Do not eat, drink or smoke when using this product.
  • Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/
  • IF SWALLOWED:
  • IF ON SKIN:
  • Immediately call a POISON CENTER/doctor/
  • Call a POISON CENTER/doctor/ if you feel unwell.
  • Rinse mouth.
  • Wash with plenty of water/

Supplier name, address and telephone number· Product identifier·Nominal quantity

Need this as an actual label? Open Thiometon in the GHS label constructor →

07 · Health hazards

Thiometon health hazards and exposure limits

Thiometon hazard summary

A cholinesterase inhibitor that may cause nervous system effects; Can be absorbed through skin; [ICSC] A weak mutagen; [HSDB] Cholinesterase inhibition observed in short term animal studies, but no adverse histopathological or other changes; No evidence of delayed neurotoxicity, significant reproductive toxicity, or teratogenicity in animal studies; [INCHEM PDS: Thiometon - 1988] The average of two baseline respective cholinesterase activity determinations three days apart, with no exposures to enzyme inhibiting pesticides for at least 30 days, is recommended for each worker prior to exposure to cholinesterase inhibitors because of large inter-individual differences in published baseline values. To be established at least once a year. Removal from workplace exposures is recommended until the cholinesterase activity returns to within 20% of baseline. [TLVs and BEIs]

Source: Haz-Map, Information on Hazardous Chemicals and Occupational Diseases

08 · Physical and chemical properties

Thiometon properties

Every value is shown with the conditions it was measured under and the source it came from. Where sources disagree, all values are listed rather than one being picked — the difference is usually a different form of the substance, not an error.

Thiometon boiling point

Property Value Conditions Source
Boiling point 110 °C (230 °F) at 0.1 mmHg (reduced pressure) HSDB
110 °C (230 °F) at 97.508 mmHg (reduced pressure) ICSC

Thiometon density

Property Value Conditions Source
Density 1.2 g/cm³ ICSC
1.209 g/cm³ at 20 °C HSDB

Thiometon solubility

Property Value Conditions Source
Solubility It is slightly soluble in light petroleum; soluble in most organic solvents. HSDB
Readily soluble in common organic solvents. Slightly soluble in petroleum ether and mineral oils. HSDB
200 mg/l in water @ 25 °C at 25 °C HSDB

Thiometon vapor pressure

Property Value Conditions Source
Vapor pressure 0.000017 mmHg at 20 °C HSDB
0.00015 mmHg at 20 °C ICSC
0.000017 mmHg Haz-Map

Thiometon vapor density

Property Value Conditions Source
Vapor density 8.5 (air = 1) ICSC

Thiometon corrosivity

Property Value Conditions Source
Corrosivity Non-corrosive HSDB

Values compiled from PubChem Laboratory Chemical Safety Summary. Temperatures converted to Fahrenheit for reference.

09 · Handling and storage

Thiometon storage and handling

Thiometon safe storage

Provision to contain effluent from fire extinguishing. Separated from food and feedstuffs. Keep in a well-ventilated room.

Source: ILO-WHO International Chemical Safety Cards (ICSCs)

Thiometon storage conditions

Formulations are said to be stable for at least 2 yr when stored below 40 °C.

Source: Hazardous Substances Data Bank (HSDB)

Thiometon incompatible materials

Incompatible with alkaline preparations and formulating materials.

Source: Hazardous Substances Data Bank (HSDB)

Planning storage for a mix of chemicals? Check Thiometon in the storage compatibility matrix →

10 · Questions

Thiometon — frequently asked questions

What is the CAS number of Thiometon?

The CAS number of Thiometon is 640-15-3. Its EC number is 211-362-6.

What is the chemical formula of Thiometon?

The molecular formula of Thiometon is C6H15O2PS3 and its molecular weight is 246.4 g/mol.

What does a Thiometon label have to show?

Under CLP Annex VI the label for Thiometon carries the pictogram Skull and crossbones and the signal word is Danger.

Is Thiometon flammable?

CLP Annex VI assigns Thiometon no flammability hazard class. That is not a statement that it cannot burn: the harmonised list only records the hazards that were assessed for it.

Is Thiometon a carcinogen?

CLP Annex VI records no harmonised carcinogenicity classification for Thiometon. Annex VI is a list of agreed classifications, not a list of substances found safe, so this is an absence of a classification rather than a clean bill of health.

What is the boiling point of Thiometon?

The boiling point reported for Thiometon is 110 °C (230 °F), at 0.1 mmHg (reduced pressure) (HSDB).

How should Thiometon be stored?

Formulations are said to be stable for at least 2 yr when stored below 40 °C. (Hazardous Substances Data Bank (HSDB))

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